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Thermal cycling and ageing of a glass-ceramic sealant for planar SOFCs
Authors:F Smeacetto  A ChrysanthouM Salvo  T MoskalewiczF D'Herin Bytner  LC AjitdossM Ferraris
Affiliation:a Department of Materials Science and Chemical Engineering, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino, Italy
b School of Aerospace, Automotive and Design Engineering, University of Hertfordshire, College Lane, Hatfield, Herts AL10 9AB, UK
c Faculty of Metals Engineering and Industrial Computer Science, AGH University of Science and Technology, Al. Mickiewicza 30, 30-059 Kraków, Poland
d Saint-Gobain Isover CRIR, France
Abstract:Thermal cycling and thermal ageing tests were performed on Crofer22APU/glass-ceramic/Anode-Supported-Electrolyte (ASE) joined samples in air at the SOFC operating temperature of 800 °C. The Crofer22APU had been polished and preoxidised at 900 °C for 2 h. The diffusion behaviour at the two interfaces was examined and revealed slight diffusion of chromium and manganese from Crofer22APU into the glass-ceramic. No interactions, failure or crack formation were observed at the Crofer22APU/glass-ceramic interface and between the glass-ceramic and YSZ.
Keywords:Glass-ceramic sealant  Solid oxide fuel cell  Trasmission electron microscopy  Microstructure  Crofer22APU
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