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Performance assessment of concentrated solar power plants based on carbon and hydrogen fuel cells
Authors:Elena Díaz  Michael Epstein  Manuel Romero  José González-Aguilar
Affiliation:1. IMDEA Energy Institute, Avda. Ramón de La Sagra 3, 28935, Móstoles, Spain;2. Department of Chemical and Energy Technology, ESCET, Rey Juan Carlos University, 28933 Móstoles, Spain
Abstract:In spite of the recent success on the implementation of Concentrating Solar Power (CSP), still this technology needs a substantial enhancement to achieve competitiveness. This paper provides thorough insight after previous analyses on an alternative concept for higher efficiency CSP systems based on the replacement of the power block by an electrochemical conversion system. Concentrating solar energy is herewith used to decompose methane into hydrogen and carbon, which are used in hydrogen and carbon fuel cells for electricity generation. This approach envisages modular, efficient and flexible generation plants. Dispatchability can be achieved by storing the solid carbon. Solar-to-electricity efficiency was calculated assuming thermodynamic equilibrium composition and experimental data available from literature, and compared with those of conventional power generation systems and commercial CSP plants. It is concluded that this new-generation CSP concept is potentially able to produce power more efficiently than the current state-of-the art solar thermal power plants.
Keywords:Solar thermal electricity  Methane decomposition  Direct carbon fuel cells  Hydrogen fuel cells  AFC  Alkaline fuel cell  CSP  Concentrated solar power  DCFC  Direct carbon fuel cell  FC  Fuel cell  HFC  Hydrogen fuel cell  MCFC  Molten carbonates fuel cell  PAFC  Phosphoric acid fuel cell  PEMFC  Proton exchange membrane fuel cell  PSA  Pressure swing adsorption  SOFC  Solid oxide fuel cell  SOFCIR  Solid oxide fuel cell with internal reforming  MSR  Methane steam reforming
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