2D thermal modeling of a solid oxide electrolyzer cell (SOEC) for syngas production by H2O/CO2 co-electrolysis |
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| Authors: | Meng Ni |
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| Affiliation: | Building Energy Research Group, Department of Building and Real Estate, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong, China |
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| Abstract: | Solid oxide fuel cells (SOFCs) can be operated in a reversed mode as electrolyzer cells for electrolysis of H2O and CO2. In this paper, a 2D thermal model is developed to study the heat/mass transfer and chemical/electrochemical reactions in a solid oxide electrolyzer cell (SOEC) for H2O/CO2 co-electrolysis. The model is based on 3 sub-models: a computational fluid dynamics (CFD) model describing the fluid flow and heat/mass transfer; an electrochemical model relating the current density and operating potential; and a chemical model describing the reversible water gas shift reaction (WGSR) and reversible methanation reaction. It is found that reversible methanation and reforming reactions are not favored in H2O/CO2 co-electrolysis. For comparison, the reversible WGSR can significantly influence the co-electrolysis behavior. The effects of inlet temperature and inlet gas composition on H2O/CO2 co-electrolysis are simulated and discussed. |
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| Keywords: | Solid oxide fuel cell Heat transfer Synthetic fuel Co-electrolysis Thermo-electrochemical model |
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