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Sulfonated poly(ether sulfone) for universal polymer electrolyte fuel cell operations
Affiliation:1. Institute for Problems of Chemical Physics, Russian Academy of Sciences, Semenov Prospect 1, Chernogolovka 142432, Russian Federation;2. Skolkovo Institute of Science and Technology, Center for Electrochemical Energy Storage, Skolkovo Innovation Center, Nobel St. 3, Moscow 143026, Russian Federation;1. Department of Nanostructured Materials, Leibniz Institute of Polymer Research Dresden, Hohe Str. 6, D-01069 Dresden, Germany;2. Technische Universität Dresden, Department of Chemistry, Dresden 01069, Germany;1. Department of Crystallography, Faculty of Chemistry, Maria Curie-Skłodowska University, 3 Maria Curie-Skłodowska Square, 20-031 Lublin, Poland;2. Laboratory of Bioorganic Synthesis and Analysis, Chair and Department of Medical Chemistry, Medical University, 4A Chodźki Street, 20-093 Lublin, Poland
Abstract:The performances of the proton exchange membrane fuel cell (PEMFC), direct formic acid fuel cell (DFAFC) and direct methanol fuel cell (DMFC) with sulfonated poly(ether sulfone) membrane are reported. Pt/C was coated on the membrane directly to fabricate a MEA for PEMFC operation. A single cell test was carried out using H2/air as the fuel and oxidant. A current density of 730 mA cm−2 at 0.60 V was obtained at 70 °C. Pt–Ru (anode) and Pt (cathode) were coated on the membrane for DMFC operations. It produced 83 mW cm−2 maximum power density. The sulfonated poly(ether sulfone) membrane was also used for DFAFC operation under several different conditions. It showed good cell performances for several different kinds of polymer electrolyte fuel cell applications.
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