| 用于90Sr萃取分离的冠醚试剂的辐射化学研究进展 |
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| 引用本文： | 彭静,俞初红,崔振鹏,翟茂林.用于90Sr萃取分离的冠醚试剂的辐射化学研究进展[J].同位素,2011,24(Z1):29-35. |
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| 作者姓名： | 彭静 俞初红 崔振鹏 翟茂林 |
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| 作者单位： | 北京大学化学与分子工程学院 放射化学与辐射化学重点实验室，北京100871 |
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| 摘 要： | 长寿命裂变产物的分离不仅可有效提高乏燃料后处理与高放废物处置安全性,而且可降低高放废物对人类和环境的危害.鉴于用于分离长寿命裂变产物的萃取剂在分离过程中通常处在较高的辐射场中,因此为了设计合适的萃取分离体系,有必要开展对裂变产物具有良好萃取性能的萃取剂的辐射稳定性的研究.本文通过对比辐照前后萃取剂的化学结构和萃取性能的...
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| 关 键 词： | 90Sr 萃取分离 辐射化学 进展 |
Progress in Radiation Chemistry of Crown Ether Extractants Used for the Solvent Extraction of 90Sr |
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| PENG Jing,YU Chu-hong,CUI Zhen-peng,ZHAI Mao-lin.Progress in Radiation Chemistry of Crown Ether Extractants Used for the Solvent Extraction of 90Sr[J].Isotopes,2011,24(Z1):29-35. |
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| Authors: | PENG Jing YU Chu-hong CUI Zhen-peng ZHAI Mao-lin |
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| Affiliation: | the Key Laboratory of Radiochemistry and Radiation Chemistry，College of Chemistry and Molecular Engineering， Peking University， Beijing 100871， China |
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| Abstract: | The separation of the long-lived fission products from dissolved nuclear fuel could improve the safe disposal of high-level nuclear wastes and reduce their threaten to human being and environment. Since the extractant system will be exposed to high radiation environment during the solvent extraction of long-lived fission products. The understanding of radiation chemistry of extractants is very important for practical design of extractant system. The radiation chemistry of crown ether systems proposed for use in the solvent extraction of one of fission products 90Sr were reviewed based on the study on the radiation stability and radiolysis mechanism of crown ether system. Finally some challenges were suggested. |
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| Keywords: | 90Sr extractants radiation chemistry progress |
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