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Analysis of Cs-adsorption behavior using a column filled with microcapsule beads of potassium copper hexacyanoferrate
Authors:Gentoku Kido  Mikihiro Takasaki  Kimitaka Minami  Hisashi Tanaka  Hiroshi Ogawa  Tohru Kawamoto
Affiliation:1. Kanto Chemical Company Incorporated, Saitama, Japan;2. National Instiute of Advanced Industrial Science and Technology (AIST), Ibaraki, Japan
Abstract:Ash-washing technology is a crucially important technology for removing radioactive Cs from contaminated ash. For that technology, Cs+ removal from the ash-washing solution by the adsorbent is necessary. This study was conducted to establish rapid preparation of appropriate adsorption columns for Cs+ uptake. A one-site model was not used for analysis because the model cannot accommodate sites with different adsorption speed. Results demonstrated that the adsorption behavior of the column filled with the granules of potassium copper hexacyanoferrate was well reproduced by a two-site adsorption model with parameters chosen through analysis of batch adsorption test results.
Keywords:Potassium copper hexacyanoferrate  cesium removal  micro-beads  fly ash  Langmuir adsorption isotherm  simulation  radioactive cesium
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