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模拟非α低中放废液水合陶瓷固化体的水化产物和力学性能
引用本文:王进,洪明,王军霞,李玉香,滕元成,吴秀玲.模拟非α低中放废液水合陶瓷固化体的水化产物和力学性能[J].辐射防护,2011,31(5).
作者姓名:王进  洪明  王军霞  李玉香  滕元成  吴秀玲
作者单位:1. 中国地质大学材料科学与化学工程学院,教育部纳米矿物材料及应用工程研究中心,武汉430074/西南科技大学材料科学与工程学院,四川绵阳621010
2. 西南科技大学材料科学与工程学院,四川绵阳,621010
3. 中国地质大学材料科学与化学工程学院,教育部纳米矿物材料及应用工程研究中心,武汉430074
基金项目:国防基础科研项目(A3120080126); 国家自然科学基金资助项目(Nos.10775113); 西南科技大学“核废物与环境安全”国防重点学科实验室培育基金资助项目(08zxnp03)
摘    要:以模拟非α低中放废液为固化处理对象,用水热法合成了非α低中放废液中和处理后沉淀的"碱-矿渣-粉煤灰-偏高岭土"水合陶瓷固化体。采用X射线衍射仪分析了固化体的水化产物,确定了水化产物的组成,并测试了固化体的抗压强度。研究结果表明:温度为150~180℃、废液沉淀与固化原材料的质量比值(即盐灰比)为0.10~0.30时,固化体水化产物的主要物相为方沸石,随着温度升高和反应时间延长,水化产物中方沸石的衍射峰不断增加。固化体抗压强度测试结果表明,该固化体具有较高的抗压强度,但盐灰比由0.10增加至0.30时,固化体抗压强度由26.33 MPa下降到8.46 MPa。

关 键 词:水合陶瓷固化体  非α低中放废液  水化产物  抗压强度

Hydration Products and Mechanical Properties of Hydroceramics Solidified Waste for Simulated Non-alpha Low and Intermediate Level Radioactive Wastes
Wang Jin,Hong Ming,Wang Junxia,Li Yuxiang,Teng Yuancheng,Wu Xiuling.Hydration Products and Mechanical Properties of Hydroceramics Solidified Waste for Simulated Non-alpha Low and Intermediate Level Radioactive Wastes[J].Radiation Protection,2011,31(5).
Authors:Wang Jin    Hong Ming  Wang Junxia  Li Yuxiang  Teng Yuancheng  Wu Xiuling
Affiliation:Wang Jin1,2,Hong Ming2,Wang Junxia2,Li Yuxiang2,Teng Yuancheng2,Wu Xiuling1(1.Faculty of Materials Science and Chemical Engineering,Engineering Research Center of Nano-Geomaterials of Ministry of Education,China University of Geosciences,Wuhan 430074,2.School of Materials Science and Engineering,Southwest University of Science and Technology,Sichuan Mianyang 621010)
Abstract:In this paper,simulated non-alpha low and intermediate level radioactive wastes was handled as curing object and that of alkali-slag-coal fly ash-metakaolin hydroceramics waste forms were prepared by hydrothermal synthesis method.The hydration products were analyzed by X ray diffraction.The composition of hydrates and the compressive strength of waste forms were determined and measured.The results indicate that the main crystalline phase of hydration products were analcite when the temperature was 150 to 18...
Keywords:Hydroceramics Solidified Waste  Non-alpha Low and Intermediate Level Radioactive Waste  Hydration Products  Compressive Strength  
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