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聚丙烯腈废胶块水解物作为水泥密封剂的实验研究
引用本文:周晶晶,陈启明,于果,陈金芳,赵芬.聚丙烯腈废胶块水解物作为水泥密封剂的实验研究[J].精细石油化工进展,2009,10(7):28-32.
作者姓名:周晶晶  陈启明  于果  陈金芳  赵芬
作者单位:1. 武汉工程大学化工与制药学院,武汉,430074
2. 武汉软件工程职业学院,武汉,430205
摘    要:以聚丙烯腈(PAN)废胶块为原料,在碱性条件下完全水解,经筛选确定最佳的硬化添加剂,将具有一定粘度的水溶性胶液作为水泥密封剂。PAN废胶块完全水解的最佳温度是95℃,最佳水解比例是m(PAN):m(NaOH):m(H2O)=1:0.3:5.5。与水泥混合使用时最佳的硬化添加剂是泡花碱,其与PAN废胶块在最佳条件下完全水解的水解液质量配比是PAN水解液:添加剂:水泥=100:1:300。

关 键 词:废胶块  水解  密封  水泥添加剂

Study on the Hydrolyzate of Waste Polyacrylonitrile Pastern as a Sealant of Cement
Zhou Jingjing,Chen Qiming,Yu Guo,Chen Jinfang,Zhao Fen.Study on the Hydrolyzate of Waste Polyacrylonitrile Pastern as a Sealant of Cement[J].Advances in Fine Petrochemicals,2009,10(7):28-32.
Authors:Zhou Jingjing  Chen Qiming  Yu Guo  Chen Jinfang  Zhao Fen
Affiliation:1. School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Wuhan 430074 ; 2. Wuhan Vocational College of Software and Engneering, Wuhan 430205)
Abstract:Waste polyacrylonitrile(PAN) pastern was hydrolyzed completely under alkali condition. The optimal hardening agent was determined by screening. The water-soluble glue with a certain viscosity was used as a sealant of cement. The optimal temperature of waste PAN pastern hydrolysis was 95 ℃, the best mass ratio of PAN,NaOH,H2O for hydrolysis was 1: 0.3: 5.5. Sodium silicate was the best hardening agent, and the mixed mass ratio of hydrolysate, additive, cement was 100:1 : 300.
Keywords:waste pastern  hydrolysis  seal  cement additive
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