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催化裂化重汽油加氢脱硫工艺研究
引用本文:李刚,李建萍,康秀娟,王洛飞,李金阳,张松显.催化裂化重汽油加氢脱硫工艺研究[J].石化技术与应用,2009,27(2):132-134.
作者姓名:李刚  李建萍  康秀娟  王洛飞  李金阳  张松显
作者单位:1. 兰州交通大学化学与生物工程学院,甘肃兰州730070;中国石油兰州化工研究中心,甘肃兰州730060
2. 中国石油兰州石化公司工程公司,甘肃兰州,730060
3. 中国石油兰州化工研究中心,甘肃兰州,730060
摘    要:以馏程大于70℃的催化裂化重汽油为原料,在装填OTC—M型催化剂的30mL微型固定床反应评价装置上,进行加氢脱硫的工艺研究。结果表明,优化的加氢条件为:反应温度260℃、反应压力1.6MPa、氢油体积比300:1、进料空速4h^-1;在此工艺条件下,重汽油的硫含量由272.35μg/g降至124.78μg/g,脱硫率达54.18%。

关 键 词:汽油  催化裂化  重汽油  加氢脱硫  加氢条件  脱硫率

Study on catalytic cracking heavy gasoline hydrodesulfurization process
Li Gang,Li Jianping,Kang Xiujuan,Wang Luofei,Li Jinyang,Zhang Songxian.Study on catalytic cracking heavy gasoline hydrodesulfurization process[J].Petrochemical Technology & Application,2009,27(2):132-134.
Authors:Li Gang  Li Jianping  Kang Xiujuan  Wang Luofei  Li Jinyang  Zhang Songxian
Affiliation:1.Chemical and Biological Engineering Institute of Lanzhou Jiaotong University;Lanzhou 730070;China;2.Lanzhou Petrochemical Research Center;PetroChina;Lanzhou 730060;3.Engineering Company of Lanzhou Petrochemical Company;China
Abstract:The hydrodesulfurization process were investigated in an evaluation unit with a 30 mL mieroreaetor fixed - bed, using catalytic cracking heavy gasoline (70 ℃ plus) as feedstock and OTC -M as hydrogenation catalyst. The results showed that the optimum conditions were: reaction temperature 260 ℃ ,reaction pressure 1.6 MPa, volumn ratio of hydrogen to oil 300: 1, feeding airspeed 4 h^-1. At this condition the sulfur content in heavy gasoline reduced from 272.35 μg/g to 124.78 μg/g,and the desulfurization percent reached 54.18%.
Keywords:gasoline  catalytic cracking  heavy gasoline  hydrodesulfurization  hydrogenation conditions  desulfurization percent  
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