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改性煤变压吸附分离煤层气中甲烷的研究
引用本文:张福凯,徐龙君,鲜学福.改性煤变压吸附分离煤层气中甲烷的研究[J].天然气化工,2008,33(4).
作者姓名:张福凯  徐龙君  鲜学福
作者单位:1. 重庆大学,西南资源开发及环境灾害控制工程教育部重点实验室,重庆,400044;重庆市地质矿产勘查开发局安全处,重庆,400039
2. 重庆大学,西南资源开发及环境灾害控制工程教育部重点实验室,重庆,400044
基金项目:国家重点基础研究发展计划(973计划),重庆市院士基金 
摘    要:通过对中梁山改性煤样在不同流速下的穿透实验,得到了该煤样的吸附柱穿透曲线,建立了等温条件下的非线性柱动力学穿透模型,并通过MATLAB求解软件对该模型进行了数值求解。采用中梁山改性前后煤样、松藻改性煤和活性炭作为吸附剂对模拟煤层气进行变压吸附浓缩分离研究表明,对于低浓度的煤层气而言,采用中梁山酸碱改性煤样在提纯低浓度煤层气实验中优于活性炭。

关 键 词:煤层气  甲烷  分离  改性煤  吸附剂  变压吸附  动力学数学模型

Separation of methane from coal-bed gas by pressure swing adsorption using modified coals as adsorbents
ZHANG Fu-kai,XU Long-jun,XIAN Xue-fu.Separation of methane from coal-bed gas by pressure swing adsorption using modified coals as adsorbents[J].Natural Gas Chemical Industry,2008,33(4).
Authors:ZHANG Fu-kai  XU Long-jun  XIAN Xue-fu
Abstract:The breakthrough curve of the modified coal has been gotten by breakthrough experiment in different current velocity.The nonlinear kinetic model has been set up under the isothermal condition,and its numerical value keys are obtained by MATLAB7.0 software.The reconstructive coal can be used for separating methane from the simulate coal-seam gas methane by using PSA enrichment method.The result is shown that the effective ability of separating low concentration coal-bed gas by acid-alkali modification Zhongliangshan coal sample is prior than that by activated carbon.
Keywords:the modified coal  adsorbent  pressure swing adsorption  the columniation of kinetic model
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