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| 含硅有机锡化合物在缩醛反应中的催化性能 | |
| 引用本文： | 何小立,林森,郭璇,邓瑞红,杨绪杰,汪信,陆路德.含硅有机锡化合物在缩醛反应中的催化性能[J].精细石油化工,2007,24(4):26-29. |
| 作者姓名： | 何小立 林森 郭璇 邓瑞红 杨绪杰 汪信 陆路德 |
| 作者单位： | 1. 南京理工大学化工学院,江苏,南京,210094;南昌大学化学系,江西,南昌,330047 2. 南昌大学化学系,江西,南昌,330047 3. 南京理工大学化工学院,江苏,南京,210094 |
| 基金项目： | 江西省自然科学基金(0520064) |
| 摘 要： | 通过催化合成苯甲醛缩乙二醇和丁醛缩乙二醇的反应,考察了3种含硅三烃基锡化合物和2种含硅二烃基锡化合物在缩醛反应中的催化活性,并以丁醛与乙二醇的反应为例,讨论了催化剂用量、反应时间和溶剂等因素对反应的影响。实验结果表明,5种含硅有机锡化合物在缩醛反应中均表现出一定的催化活性;在丁醛与乙二醇的反应中,当n(丁醛):n(乙二醇)=1:1,三(三甲基硅基)亚甲基]氯化锡用量为反应物料质量分数的1.8%,环己烷为带水剂,反应时间5 h时,丁醛缩乙二醇的收率可以达到88.6%。 |
| 关 键 词： | 含硅有机锡化合物 催化 缩醛反应 |
| 收稿时间： | 2006-11-14 |
| 修稿时间： | 2006-11-142007-05-12 |
CATALYTIC PROPERTIES OF SILICON-CONTAINING ORGANOTINCOMPOUNDS IN ACETALIZATION |
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| He Xiaoli,Lin Sen,Guo Xuan,Deng Ruihong,Yang Xujie,Wang Xin,Lu Lude.CATALYTIC PROPERTIES OF SILICON-CONTAINING ORGANOTINCOMPOUNDS IN ACETALIZATION[J].Speciality Petrochemicals,2007,24(4):26-29. | |
| Authors: | He Xiaoli Lin Sen Guo Xuan Deng Ruihong Yang Xujie Wang Xin Lu Lude |
| Affiliation: | 1. School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, Jiangsu, China;2. Department of Chemistry, Nanchang University, Nanchang 330047, Jiangxi, China |
| Abstract: | The catalytic properties of silicon-containing trihydroxyltin and dihydroxyltin compounds were studied in the syntheses of benzaldehyde glycol acetal and butyraldehyde glycol acetal.The fac- tors influencing the reaction,such as catalyst dosage,reaction time and types of solvents,were inves- tigated based on the reaction of butyraldehyde and glycol.The results showed that all the five organo- tin compounds possessed certain catalytic activities.In the reaction of butyraldehyde and glycol,when n(butyraldehyde):n(glycol)=1:1,the amount of tri(trimethylsilyl)methyl]tinchloride as cat- alyst was 1.8% based on the mass of the reactants,cyclohexane as water carrying agent,and reaction time 5 h,the yield of butyraldehyde glycol acetal reached 88.6%. |
| Keywords: | silicon-containing organotin compounds catalysis acetalization |
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