| 顺-1-环己基-1,2-环己二醇的合成 |
| |
| 引用本文： | 张颂培,祝钧,陈娟.顺-1-环己基-1,2-环己二醇的合成[J].精细石油化工,2006,23(1):20-22. |
| |
| 作者姓名： | 张颂培 祝钧 陈娟 |
| |
| 作者单位： | 北京工商大学,化工学院,北京,100037 |
| |
| 摘 要： | 研究了顺-1-环己基-1,2-环己二醇的合成新工艺。先用格氏试剂1-环己基溴化镁和环己酮反应制得环己醇,醇脱水后生成α-位取代的环己烯,最后用甲酸-过氧化氢氧化制得顺-1-环己基-1,2-环己二醇。产物用元素分析、红外光谱与1H NMR进行了表征。产物熔点90~91℃,收率为29%。
|
| 关 键 词： | 顺-1-环己基-1 2-环己二醇 合成 表征 |
| 收稿时间： | 2005-04-11 |
| 修稿时间： | 2005-12-14 |
SYNTHESIS AND SPECTRAL ANALYSIS OF cis-1-CYCLOHEXYL-1, 2-CYCLOHEXANEDIOL |
| |
| Zhang Songpei,Zhu Jun,Chen Juan.SYNTHESIS AND SPECTRAL ANALYSIS OF cis-1-CYCLOHEXYL-1, 2-CYCLOHEXANEDIOL[J].Speciality Petrochemicals,2006,23(1):20-22. |
| |
| Authors: | Zhang Songpei Zhu Jun Chen Juan |
| |
| Affiliation: | College of Chemical and Beijing Technology and Business Environmental Engineering, University, Beijing 100037, China |
| |
| Abstract: | 1-cyclohexyl-cyclohexanol was prepared by the reaction of grignard reagent and cyclohexanone and the product was then dehydrated to give 1-cyclohexyl-1,2-cyclohexene.cis-1-cyclohexyl-1,2-cyclohexandiol was obtained by the oxidization of 1-cyclohexyl-cyclohexene with hydrogen peroxide.The melting point(9091 ℃) of the product was the same as the reported value.The elemental analysis,IR and ~1H NMR data all indicated that the target compound was prepared. |
| |
| Keywords: | cis-1-cyclohexyl-1 2-cyclohexanediol synthesis characteristic |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
