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杨木CTMP碱性H2O2漂白中糖醛酸溶出的研究
引用本文:霍 丹,秦梦华,傅英娟,徐清华,刘 娜.杨木CTMP碱性H2O2漂白中糖醛酸溶出的研究[J].中国造纸,2011,30(6):6-10.
作者姓名:霍 丹  秦梦华  傅英娟  徐清华  刘 娜
作者单位:山东轻工业学院制浆造纸科学与技术省部共建教育部重点实验室,山东济南,250353
基金项目:国家自然科学基金(30972327);国家教育部新世纪人才支持计划(NCET-08-0882)项目。
摘    要:研究了杨木CTMP碱性H2O2漂白过程中漂白工艺对糖醛酸溶出的影响。结果表明,糖醛酸的溶出主要受体系碱度的影响。高碱度下,H2O2的加入会在一定程度上阻碍糖醛酸的溶出;高温(如高于80℃)会加剧糖醛酸的溶出;一定温度下,糖醛酸的溶出主要在反应初期阶段较快速。正交实验结果表明,影响糖醛酸溶出的漂白工艺条件依次为NaOH用量、温度、H2O2用量、浆浓、反应时间。

关 键 词:杨木CTMP  糖醛酸  碱性H2O2漂白

Releasing of Uronic Acids in Alkaline Peroxide Bleaching of Aspen CTMP
HUO Dan,QIN Meng hua,FU Ying juan,XU Qing hua,LIU Na.Releasing of Uronic Acids in Alkaline Peroxide Bleaching of Aspen CTMP[J].China Pulp & Paper,2011,30(6):6-10.
Authors:HUO Dan  QIN Meng hua  FU Ying juan  XU Qing hua  LIU Na
Affiliation:HUO Dan QIN Meng-hua FU Ying-juan XU Qing-hua LIU Na(Key Lab of Paper Science and Technology of Ministry of Education,Shandong Polytechnic University,Ji'nan,Shandong Province,250353)
Abstract:Some dissolved and colloidal substances(DCS) tend to release during the alkline hydrogen peroxide bleaching of mechanical pulp,and the anionic groups(AGs) in DCS are mainly uronic acids.In this paper,the aspen CTMP were bleached with alkaline hydrogen peroxide under different conditions,and the content of uronic acids in the resultant DCS was determined by spectrophotometric method.The results showed that the amount of uronic acids dissolved was mainly affected by the alkalinity of the system;Peroxide could...
Keywords:aspen CTMP  uronic acids  alkaline peroxide bleaching  
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