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核壳型表面施胶剂的制备及应用
引用本文:李建文,詹怀宇,李亮.核壳型表面施胶剂的制备及应用[J].中国造纸,2006,25(3):11-14.
作者姓名:李建文  詹怀宇  李亮
作者单位:1. 华南理工大学制浆造纸工程国家重点实验室,广州,510640
2. 山东亚太森博浆纸有限公司,山东日照,276826
摘    要:以苯乙烯、丙烯酸酯、丙烯酸等为原料,采用功能单体引入法无皂聚合工艺制备了性能稳定的核壳型共聚物表面施胶剂(PSS)。IR、DSC、TEM分析表明,PSS有预期的共聚结构和微粒形态。PSS与表面施胶淀粉共用于纸厂铜版原纸的生产表明,与单用表面施胶淀粉相比,原纸正、反面Cobb值分别降低28.6%、40.8%;增加碳酸钙用量1.5%后,原纸表面强度、抗张指数、耐折度仍可提高14.2%、7.4%、16.7%,吨浆生产原纸成本降低19.02元。

关 键 词:核壳型共聚物  无皂聚合  表面施胶剂  铜版原纸  表面施胶淀粉
文章编号:0254-508X(2006)03-0011-04
修稿时间:2006年8月11日

Preparation and Application of the Core-Shell Type Surface Sizing Agent
LI Jian-wen,ZHAN Huai-yu,LI Liang.Preparation and Application of the Core-Shell Type Surface Sizing Agent[J].China Pulp & Paper,2006,25(3):11-14.
Authors:LI Jian-wen  ZHAN Huai-yu  LI Liang
Abstract:The core-shell type surface sizing agent PSS synthesized by introducing a functional monomer in the soap-free polymerization technology was prepared using acrylate, styrene, acrylic acid as raw materials. The designed copolymer molecular structure of PSS product was identified by the analysis of IR and DSC. The result of surface sizing of the base paper for art paper with PSS plus starch indicted that the Cobb values of the top side and back side of the base paper decreased 28.6% and 40.8% respectively compared with the application of starch alone. The paper surface strength, tensile index, folding endurance and brightness were respectively increased by 14.2%, 7.4%, 16.7%, and 0.7% ISO when the increment of calcium carbonate was 1.5%, meanwhile, the saving of 19.02 RMB per ton of base paper could be achieved.
Keywords:core-shell type  soap-free polymerization  surface sizing agent  coated art base paper  surface sizing starch
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