| 活性碳纤维负载钴酞菁对取代酚的催化氧化 |
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| 引用本文： | 徐敏虹,陈文兴,曹枫,潘国祥,唐培松,陈海锋,吕汪洋.活性碳纤维负载钴酞菁对取代酚的催化氧化[J].纺织学报,2011,32(10):26-0. |
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| 作者姓名： | 徐敏虹 陈文兴 曹枫 潘国祥 唐培松 陈海锋 吕汪洋 |
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| 作者单位： | 1. 湖州师范学院化学系,浙江湖州,313000
2. 浙江理工大学先进纺织材料与制备技术教育部重点实验室,浙江杭州,310018 |
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| 基金项目： | 浙江省自然科学基金资助项目(Y4100471,Y4110641); 浙江省教育厅项目(Y200903866); 湖州市自然科学基金资助项目(2010YZ01) |
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| 摘 要： | 为去除难降解的酚类物质,以活性碳纤维负载钴酞菁(CoPc-ACF)为催化剂、以H2O2为氧化剂组成新型催化氧化体系(CoPc-ACF/H2O2).该体系能充分发挥CoPc-ACF中活性碳纤维的吸附特性和钴酞菁的催化性能.以对硝基苯酚、对甲氧基苯酚和取代氯酚为对象,研究该体系对其的吸附催化氧化性能.采用UPLC检测酚类物...
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| 关 键 词： | 活性碳纤维 钴酞菁 取代酚 催化氧化 |
Catalytic oxidation of phenols by cobalt phthalocyanine supported activated carbon fibers |
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| XU Minhong,CHEN Wenxing,CAO Feng,PAN Guoxiang,TANG Peisong,CHEN Haifeng,L Wangyang.Catalytic oxidation of phenols by cobalt phthalocyanine supported activated carbon fibers[J].Journal of Textile Research,2011,32(10):26-0. |
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| Authors: | XU Minhong CHEN Wenxing CAO Feng PAN Guoxiang TANG Peisong CHEN Haifeng L Wangyang |
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| Affiliation: | XU Minhong1,CHEN Wenxing2,CAO Feng1,PAN Guoxiang1,TANG Peisong1,CHEN Haifeng1,Lü Wangyang2(1.Chemistry Department,Huzhou Normal College,Huzhou,Zhejiang 313000,China,2.Key Laboratory of Advanced Textile Materials and Manufacturing Technology,Ministry of Education,Zhejiang Sci-Tech University,Hangzhou,Zhejiang 310018,China) |
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| Abstract: | In order to remove refractory phenols,a novel catalytic oxidation system,consisting of activated carbon fibers supported with cobalt phthalocyanine(CoPc-ACF) and H2O2 as oxidant,has been developed,which gives full play to the adsorption of ACF and the catalysis of cobalt phthalocyanine.The oxidative removal of p-nitrophenol,p-methoxyphenol,and chlorophenol were investigated in this catalytic oxidation system.The results showed that more than 97% of these phenols were removed in 5 h under the condition of Co... |
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| Keywords: | activated carbon fiber cobalt phthalocyanine substituted phenol catalytic oxidation |
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