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稀酸预处理对玉米秸秆纤维组分及结构的影响
引用本文:陈尚钘,勇强,徐勇,朱均均,余世袁.稀酸预处理对玉米秸秆纤维组分及结构的影响[J].中国粮油学报,2011,26(6):13-19.
作者姓名:陈尚钘  勇强  徐勇  朱均均  余世袁
作者单位:1. 江西农业大学林学院,南昌,330045
2. 林木遗传与生物技术省部共建教育部重点实验室,南京林业大学,南京210037
基金项目:863计划,国家自然科学基金
摘    要:研究了稀硫酸预处理对玉米秸秆化学组成变化及纤维素酶水解得率的影响,并采用扫描电镜(SEM)、X射线衍射仪(XRD)、红外光谱(IR)和热重分析(TG)对玉米秸秆纤维结构特性进行了分析。结果表明随着硫酸浓度的增大、温度的升高和时间的延长,纤维素和木质素含量有所增加,而半纤维素含量大幅度降低,且预处理后纤维素酶水解得率也逐渐增大。当处理条件为硫酸质量分数0.75%、温度150℃、时间80 min时,半纤维素降解率为98.02%,所得固体渣纤维素酶水解得率为66.95%(纤维素酶用量20 FPUI/g纤维素)。稀酸预处理后玉米秸秆纤维表面和细胞壁受到不同程度的破坏,表面积增大,孔洞增加,纤维素的结晶度降低,有利于纤维素酶水解作用的进行。

关 键 词:玉米秸秆  稀酸预处理  纤维素酶水解  化学组成  纤维结构

Effects of Dilute Acid Pretreatment on Fibre Components and Structure of Corn Stover
Chen Shangxing,Yong Qiang,Xu Yong,Zhu Junjun,Yu Shiyuan.Effects of Dilute Acid Pretreatment on Fibre Components and Structure of Corn Stover[J].Journal of the Chinese Cereals and Oils Association,2011,26(6):13-19.
Authors:Chen Shangxing  Yong Qiang  Xu Yong  Zhu Junjun  Yu Shiyuan
Affiliation:Chen Shangxing1 Yong Qiang2 Xu Yong2 Zhu Junjun2 Yu Shiyuan2(College of Forestry,Jiangxi Agricultural University1,Nanchang 330045)(Key Laboratory of Forest Genetics & Biotechnology,Ministry of Education,Nanjing Forestry University2,Nanjing 210037)
Abstract:The effects of dilute sulfuric acid pretreatment on the composition and enzymatic hydrolysis rate of solid residues for corn stover were investigated,and the fiber structure property of the pretreated residues were studied with scanning electron microscope,infrared,X-rays diffraction and thermal gravity.Results: With the increase of sulfuric concentration,temperature and retention time,the contents of cellulose and lignin increase slightly,the hemicellulose content largely declines,and the yield of enzymati...
Keywords:corn stover  dilute sulfuric acid pretreatment  enzymatic hydrolysis  chemical composition  cellulose structure  
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