| 液液萃取-气相色谱-质谱联用快速检测葡萄酒中14种农药残留 |
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| 引用本文： | 王春利,李天宝,刘炜,郭盈希,冯志洪.液液萃取-气相色谱-质谱联用快速检测葡萄酒中14种农药残留[J].酿酒科技,2012(8):112-115. |
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| 作者姓名： | 王春利 李天宝 刘炜 郭盈希 冯志洪 |
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| 作者单位： | 江门出入境检验检疫局,广东江门,529000 |
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| 基金项目： | 江门市科技项目，广东出入境检验检疫局科技项目(2010GDK31)经费资助 |
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| 摘 要： | 建立了葡萄酒中14种农药残留的气相色谱-质谱联用选择离子模式进行监测的检测方法,样品采用正己烷∶乙酸乙酯（1∶1）萃取,无需净化。该方法在0.01～10 mg/L范围内线性关系良好,相关系数大于0.998;在0.01～1.0 mg/L添加水平范围内,平均加标回收率在90.32～108.13之间;最低检出限（LOD）在0.01～0.10 mg/kg之间,定量检出限（LOQ）为0.001～0.05 mg/kg,相对标准偏差均小于10%。
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| 关 键 词： | 液液萃取 气相色谱-质谱联用 葡萄酒 农药残留 |
Rapid Determination of 14 Kinds of Pesticides Residue in Grape Wine by Gas Chromatography-Mass Spectrometry with Liquid-liquid Extraction |
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| WANG Chunli,LI Tianbao,LIU Wei,GUO Yingxi and FENG Zhihong.Rapid Determination of 14 Kinds of Pesticides Residue in Grape Wine by Gas Chromatography-Mass Spectrometry with Liquid-liquid Extraction[J].Liquor-making Science & Technology,2012(8):112-115. |
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| Authors: | WANG Chunli LI Tianbao LIU Wei GUO Yingxi and FENG Zhihong |
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| Affiliation: | (Jiangmen Entry-Exit Inspection and Quarantine Bureau,Jiangmen,Guangdong 529000,China) |
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| Abstract: | A method(GC-MS coupled with liquid-liquid extraction)for rapid determination of 14 kinds of pesticides residue in grape wine has been developed.Grape wine samples were extracted by n-hexane and ethyl acetate(1∶1) without purification.The results suggested that such method displayed good linear relationships within 0.01～10 mg/L and the relative coefficient was above 0.998,the average recoveries were in the range of 90.32～108.13 with RSD s<10 % as the addition level was between 0.01～1.0 mg/L,LOD ranged from 0.01～0.10 mg/kg,and LOQ ranged from 0.001～0.05 mg/kg. |
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| Keywords: | liquid-liquid extraction gas chromatography-electron ionization mass spectrometry grape wine pesticides residue |
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