Revealing local variations in nanoparticle size distributions in supported catalysts: a generic TEM specimen preparation method |
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| Authors: | TORBEN PINGEL MAGNUS SKOGLUNDH HENRIK GRÖNBECK EVA OLSSON |
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| Affiliation: | 1. Competence Centre for Catalysis (KCK), Department of Applied Physics, Chalmers University of Technology, Gothenburg, Sweden;2. Competence Centre for Catalysis (KCK), Department of Chemical and Biological Engineering, Chalmers University of Technology, Gothenburg, Sweden |
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| Abstract: | The specimen preparation method is crucial for how much information can be gained from transmission electron microscopy (TEM) studies of supported nanoparticle catalysts. The aim of this work is to develop a method that allows for observation of size and location of nanoparticles deposited on a porous oxide support material. A bimetallic Pt‐Pd/Al2O3 catalyst in powder form was embedded in acrylic resin and lift‐out specimens were extracted using combined focused ion beam/scanning electron microscopy (FIB/SEM). These specimens allow for a cross‐section view across individual oxide support particles, including the unaltered near surface region of these particles. A site‐dependent size distribution of Pt‐Pd nanoparticles was revealed along the radial direction of the support particles by scanning transmission electron microscopy (STEM) imaging. The developed specimen preparation method enables obtaining information about the spatial distribution of nanoparticles in complex support structures which commonly is a challenge in heterogeneous catalysis. |
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| Keywords: | FIB/SEM palladium platinum specimen preparation supported nanoparticle catalyst TEM |
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