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酞菁镍与Fe_3O_4纳米粒子的复合机理及复合粒子的结构模型
引用本文:黄俊,姜德生,官建国,袁润章. 酞菁镍与Fe_3O_4纳米粒子的复合机理及复合粒子的结构模型[J]. 复合材料学报, 2001, 18(2)
作者姓名:黄俊  姜德生  官建国  袁润章
作者单位:1. 武汉工业大学光纤中心,
2. 武汉工业大学材料复合新技术国家实验室,
基金项目:国家自然科学基金资助项目!(2 96 740 2 1)
摘    要:分析了酞菁镍 (Ni Pc)与 Fe3O4纳米粒子的复合过程 ,提出了其复合机理。研究并建立了 Ni Pc- Fe3O4纳米复合粒子的结构模型

关 键 词:NiPc-Fe3O4纳米复合粒子  复合机理  结构模型

COMPLEX MECHANISM OF PHTHALOCYANINE NICKEL WITH Fe_3O_4 NANOPARTICLES AND THE STRUCTURE MODEL OF THE NANOPARTICLES COMPOSITE
HUANG Jun,JIANG Desheng,GUAN Jianguo,YUAN Runzhang. COMPLEX MECHANISM OF PHTHALOCYANINE NICKEL WITH Fe_3O_4 NANOPARTICLES AND THE STRUCTURE MODEL OF THE NANOPARTICLES COMPOSITE[J]. Acta Materiae Compositae Sinica, 2001, 18(2)
Authors:HUANG Jun  JIANG Desheng  GUAN Jianguo  YUAN Runzhang
Affiliation:HUANG Jun 1,JIANG De sheng 1,GUAN Jian guo 2,YUAN Run zhang 2
Abstract:In this article, the complex process of phthalocyanine nickel with Fe 3O 4 nanoparticles has been analyzed, the complex mechanism and the structure model for NiPc Fe 3O 4 nanoparticles composite have been studied. For the complexes mechanism of NiPc with Fe 3O 4 nanoparticles, first, there are complex between NiPc and all Fe 3O 4 nanoparticles. Then, Fe 3O 4 nanoparticles accumulate together to form the accumulators; NiPc have the function of cohering Fe 3O 4 nanoparticles. A considerable number of NiPc combine with Fe 3O 4 nanoparticles and on the surface of the accumulators to form NiPc Fe 3O 4 nanoparticles composite. All the processes above take place spontaneously. Inside the NiPc Fe 3O 4 nanoparticles complex, Fe 3O 4 nanoparticles accumulate together without order, on the surface of composite, NiPc form a molecular dispersion layer. The threshold of the molecular dispersion layer is 0.06 g/g(Fe 3O 4).
Keywords:NiPc Fe 3O 4 nanoparticles composite  complex mechanism  structure model
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