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含砷金铜矿熔炼电尘灰酸性氧化浸出研究
引用本文:张俊峰. 含砷金铜矿熔炼电尘灰酸性氧化浸出研究[J]. 有色金属(冶炼部分), 2021, 0(2)
作者姓名:张俊峰
作者单位:中南大学;山东恒邦冶炼股份有限公司
基金项目:国家重点研发计划项目(2018YFC1900306);山东省重大科技创新工程项目(2019TSLH0119)。
摘    要:含砷金铜精矿火法熔炼电尘灰是铜冶炼熔炼车间产出的中间产物,成分复杂,较难处理,属于典型危废。以山东某冶炼公司含砷金铜矿熔炼产出的中间产物电尘灰为原料,采用双氧水为氧化剂进行酸性氧化浸出,最佳浸出工艺条件为:双氧水用量120kg/t、酸性氧化浸出时间2h、浸出温度80℃、酸度60g/L,铜和砷的浸出率分别达到92.30%、87.50%以上。为铜冶炼企业湿法处理电尘灰提供了一条新途径。

关 键 词:铜冶炼  电尘灰  氧化剂    

Study on Oxidation Acidity Leaching of Dust of Electrostatic Precipitator of Arsenic-bearing Auricupride Smelting
ZHANG Jun-feng. Study on Oxidation Acidity Leaching of Dust of Electrostatic Precipitator of Arsenic-bearing Auricupride Smelting[J]. Nonferrous Metals(Extractive Metallurgy), 2021, 0(2)
Authors:ZHANG Jun-feng
Affiliation:(Central South University,Changsha 410083,China;Shandong Humon Smelting Co.,Ltd.,Yantai 264109,Shandong,China)
Abstract:Dust of electrostatic precipitator of arsenic-bearing auricupride smelting is an intermediate product produced by copper smelting workshop.It is a typical hazardous waste due to its complex composition and difficult to treat.Dust of electrostatic precipitator from a smelting company in Shandong province was oxidation acidity leached with hydrogen peroxide as oxidant.The results show that leaching rate of copper and arsenic is 92.30%and 87.50%above respectively under the optimum conditions including dosage of hydrogen peroxide of 120 kg/t,leaching time of 2 h,leaching temperature of 80℃,and acidity of 60 g/L.It provides a new approach for copper smelting companies to deal with dust of electrostatic precipitator by hydrometallurgical process.
Keywords:copper smelting  dust of electrostatic precipitator  oxidant  copper  arsenic
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