| 金刚烷单季铵盐阳离子表面活性剂的合成 |
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| 引用本文： | 蔡璐,郭建维,刘卅,关念云,朱乐杰,崔英德,孙保兴. 金刚烷单季铵盐阳离子表面活性剂的合成[J]. 化工学报, 2011, 62(11): 3295-3300. DOI: 10.3969/j.issn.0438-1157.2011.11.046 |
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| 作者姓名： | 蔡璐 郭建维 刘卅 关念云 朱乐杰 崔英德 孙保兴 |
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| 作者单位： | 广东工业大学轻工化工学院；华南理工大学材料学院；广州市瑞洋表面活性剂有限公司 |
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| 基金项目： | 广东工业大学重大项目培育专项(405095220)~~ |
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| 摘 要： | 引言金刚烷(Adamantane)化学名为三环[3,3,1,13,7]癸烷,分子式为C10H16,是一种高度对称的笼状烃,整个环系具有周正对称、高度稳定的结构特征[1]。金刚烷分子中1,3,5,7位上四个桥头
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| 关 键 词： | 金刚烷 季铵盐 阳离子表面活性剂 合成 |
Synthesis of adamantane-containing cationic surfactants |
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| CAI Lu,GUO Jianwei,LIU Sa,GUAN Nianyun,ZHU Lejie,CUI Yingde,SUN Baoxing. Synthesis of adamantane-containing cationic surfactants[J]. Journal of Chemical Industry and Engineering(China), 2011, 62(11): 3295-3300. DOI: 10.3969/j.issn.0438-1157.2011.11.046 |
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| Authors: | CAI Lu GUO Jianwei LIU Sa GUAN Nianyun ZHU Lejie CUI Yingde SUN Baoxing |
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| Affiliation: | CAI Lu 1,GUO Jianwei1,LIU Sa2,GUAN Nianyun1,ZHU Lejie1,CUI Yingde1,SUN Baoxing3 (1Faculty of Chemical Engineering & Light Industry,Guangdong University of Technology,Guangzhou 510006,Guangdong,China,2College of Material Science & Engineering,South China University of Technology,Guangzhou 510640,3Guangzhou Rui Yang Surfactant Ltd.,Guangzhou 511400,China) |
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| Abstract: | Eight halogen quaternary ammonium cationic surfactants containing adamantane structure were successfully synthesized through quaterisation of the intermediate compound-N,N-dimethyl tertiary amine using halogen quaternary ammonium reagents.N-(1-adamantyl)-N,N-dimethylamine was synthesized through the Eschweiler-Clarke methylation reaction in which 1-adamantine and formaldehyde with excess formic acid were used as raw materials.The yields of the eight products were 90%,85%,75%,61%,44%,54%,87%,45% respectively... |
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| Keywords: | adamantane quaternary ammonium salt cationic surfactant synthesis |
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