| 四官能度过氧化物引发制备高抗冲聚苯乙烯 |
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| 引用本文： | 曹锐鑫,单国荣,黄志明. 四官能度过氧化物引发制备高抗冲聚苯乙烯[J]. 化工学报, 2011, 62(9): 2663-2667. DOI: 10.3969/j.issn.0438-1157.2011.09.041 |
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| 作者姓名： | 曹锐鑫 单国荣 黄志明 |
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| 作者单位： | 化学工程联合国家重点实验室（浙江大学），浙江大学化工系，浙江 杭州 310027 |
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| 摘 要： | 引言高抗冲聚苯乙烯(HIPS)可通过顺丁橡胶(PB)接枝苯乙烯共聚制备,相比通用聚苯乙烯(GPPS),其抗冲性能高、拉伸形变大,但这些性能受HIPS分子量及分布、接枝效率、橡胶粒子形态及大小的影响很大。制备时可改变剪切速率、橡胶类型及用量、引发剂用量来调节产物分子量及分布、接枝效率、橡胶粒子形态及大小,进而控制
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| 关 键 词： | 高抗冲聚苯乙烯 四官能度过氧化物 接枝效率 相反转 |
Preparation of high impact polystyrene initiated with a tetrafunctional peroxide |
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| CAO Ruixin,SHAN Guorong,HUANG Zhiming. Preparation of high impact polystyrene initiated with a tetrafunctional peroxide[J]. Journal of Chemical Industry and Engineering(China), 2011, 62(9): 2663-2667. DOI: 10.3969/j.issn.0438-1157.2011.09.041 |
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| Authors: | CAO Ruixin SHAN Guorong HUANG Zhiming |
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| Affiliation: | CAO Ruixin,SHAN Guorong,HUANG Zhiming(State Key Laboratory of Chemical Engineering,Department of Chemical Engineering,Zhejiang University,Hangzhou 310027,Zhejiang,China) |
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| Abstract: | The synthesis of high impact polystyrene(HIPS)with the usage of a tetrafunctional peroxide initiator was investigated.The polymerization performance of a commercial initiator polyether poly-t-butylperoxy carbonate(JWEB50)was compared with that of its monofunctional counterpart,tert-butyl(2-ethylhexyl)monoperoxycarbonate(TBEC).It was shown that the polymerization kinetic curves completely overlapped at the same polymerization temperature when the molar concentrations of were equal for these two initiators.An... |
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| Keywords: | high impact polystyrene tetrafunctional peroxide graft efficiency phase inversion |
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