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快硬硫铝酸盐水泥基封堵材料早期性能研究
引用本文:范成文,白银,李平. 快硬硫铝酸盐水泥基封堵材料早期性能研究[J]. 水利水运工程学报, 2020, 0(2): 30-35. DOI: 10.12170/20190321001
作者姓名:范成文  白银  李平
作者单位:河海大学岩土力学与堤坝工程教育部重点实验室,江苏南京 210098;河海大学土木与交通学院,江苏南京 210098;南京水利科学研究院水文水资源与水利工程科学国家重点试验室,江苏南京 210029
基金项目:国家重点研发计划资助项目(2016YFC0401609);国家自然科学基金重点项目(51739008);国家自然科学基金面上项目(41977240)
摘    要:为了开发适用于有压作用下混凝土结构渗漏缺陷快速封堵的材料,采用可再分散乳胶粉(VAE)改性快硬硫铝酸盐水泥(R·SAC)。使用流变仪测试R·SAC黏度时变规律,揭示其流变学性能;通过抗折抗压试验以及“8”字模粘结试验测试R·SAC的力学性能,并结合扫描电镜(SEM)分析,从而得到R·SAC基封堵材料较为完整的早期性能。结果表明:R·SAC初始黏度维持时间约为40 min,随后黏度呈“指数型”急剧增长;加入VAE后R·SAC的初始黏度增加、突变点提前且突变后黏度增长速率显著加快,提高了封堵材料抵抗渗漏水压的能力,掺量在4%时此现象最为明显;掺量为3%~4%时可将R·SAC的早期抗折强度提高15%~21%,抗压强度则随掺量提高而降低,折压比上升表明改性R·SAC柔韧性提高;1 d粘结强度在VAE掺量为4%时达到最大值,粘结强度较对照组提高121%; SEM分析表明改性R·SAC内部颗粒之间形成了致密的搭接结构,封堵渗漏缺陷的能力得到明显改善。

关 键 词:混凝土渗漏  快硬硫铝酸盐水泥  可再分散乳胶粉  早期性能  掺量
收稿时间:2019-03-21

Study on early performance of rapid hardening sulphoaluminate cement-based sealing material
Affiliation:1.Key Laboratory of Ministry of Education for Geomechanics and Embankment Engineering, Hohai University, Nanjing 210098, China2.College of Civil and Transportation Engineering, Hohai University, Nanjing 210098, China3.State Key Laboratory of Hydrology-Water Resources and Hydraulic Engineering, Nanjing Hydraulic Research Institute, Nanjing 210029, China
Abstract:In order to develop materials suitable for rapid plugging of concrete leakage defects under pressure, we use vinyl acetate-ethylene copolymer (VAE) to modify rapid hardening sulphoaluminate cement (R·SAC). Employing rheometer, R·SAC’s rheologic property was revealed by testing its viscosity law which varies with time. The early performance of R·SAC-based materials was unveiled by combining the testing results of R·SAC’s mechanical property by means of anti-flexural and anti-pressure test and adhesion test on “8”-shaped model with analysis of scanning electron microscope (SEM). The study shows that maintainable time of initial viscosity of R·SAC is about 40 minutes, whose viscosity surges with exponential rate later. With an addition of VAE, plugging material’s ability to resist leaking water pressure improved accompanied by an increase of R·SAC’s initial viscosity, an acceleration of mutational site and an remarkable leap of viscosity’s growing rate. The most obvious phenomenon above occurs by adding 4% VAE into the material. When the content of VAE ranges from 3% to 4%, the increase of R·SAC’s early anti-flexural strength varies from 15% to 21% and anti-pressure strength decreases accordingly. The increase of flexural-press ratio demonstrates that the flexibility of the modified R·SAC achieves improvement. When the content of VAE reaches 4%, 1 d bonding strength hits its maximum with a 121% bonding strength growth compared with the control group. Analysis from SEM illustrates that dense lap structures are formed among interior granules of R·SAC and thus the material’s ability to plug leakage defects gets substantive progress.
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