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The calculation of the heat release rate by oxygen consumption in a controlled‐atmosphere cone calorimeter
Authors:Martin Werrel  Jan H. Deubel  Simone Krüger  Anja Hofmann  Ulrich Krause
Affiliation:1. BAM Federal Institute for Materials Research and Testing, Berlin, Germany;2. Currently with BASF SE, Ludwigshafen am Rhein, Germany;3. Otto‐von‐Guericke‐University Magdeburg, Magdeburg, Germany
Abstract:The standard cone calorimeter according to ASTM E 1354 and ISO 5660 enables reaction‐to‐fire tests to be performed in ambient atmospheric conditions. A controlled‐atmosphere chamber modifies the standard apparatus in a way that allows tests to be performed in nonambient conditions as well. The enclosed chamber is placed underneath the standard exhaust hood and does not have a closed connection to the hood. With this open arrangement, the exhaust gases are diluted by excess air drawn in from the laboratory surroundings. Heat‐induced changes in the consequential dilution ratio affect the calculation of fire quantities and, when neglected, lead to deviations of up to 30% in heat release rate. The paper introduces a test protocol and equations to calculate the heat release rate taking dilution effects into account. A mathematical correction is shown that compensates for the dilution effects while avoiding extensive mechanical changes in the equipment. Copyright © 2013 John Wiley & Sons, Ltd.
Keywords:controlled‐atmosphere cone calorimeter  heat release rate  oxygen consumption  cone calorimeter  vitiation and ventilation control  excess air
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