Effect of amphiphilic compatibilizers on the filler dispersion and properties of polyethylene—thermally reduced graphene nanocomposites |
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| Authors: | Vikas Mittal Ali U. Chaudhry |
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| Affiliation: | Department of Chemical Engineering, The Petroleum Institute, Abu Dhabi, UAE |
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| Abstract: | Compatibilizers of different chemical structures and specifications were used to enhance the filler exfoliation in nanocomposites of polyethylene and thermally reduced graphene prepared by melt mixing route. The mechanical performance of the compatibilized nanocomposites was observed to be better than PE/G nanocomposites due to enhanced extent of filler exfoliation and distribution. Highest increase of 45% in tensile modulus and 13% in peak stress was observed in the composites. Overall, from the mechanical, rheological, thermal, and calorimetric properties, the compatibilizers with best performance were ethylene acrylic acid (EAA) copolymer and chlorinated polyethylene (CPE25). Furthermore, the extent of filler exfoliation was observed to increase with increasing EAA content thus confirming positive interactions between EAA and thermally reduced graphene, though no specific chemical interactions could be detected. The composite properties were observed to reach maximum around 7.5 wt % EAA content, followed by reduced performance due to extensive matrix plasticization. The observed behaviors were a result of interplay of opposing factors like filler exfoliation due to compatibilizer addition and matrix plasticization due to its lower molecular weight, thus the observed optimum comaptibilizer amount was specific to the compatibilizer. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42484. |
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| Keywords: | composites morphology properties and characterization |
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