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电渗析-超滤耦合技术研究进展
引用本文:苏慧超,张田明,吴云奇,徐国荣. 电渗析-超滤耦合技术研究进展[J]. 化工进展, 2020, 39(z2): 1-7. DOI: 10.16085/j.issn.1000-6613.2020-1316
作者姓名:苏慧超  张田明  吴云奇  徐国荣
作者单位:1.自然资源部天津海水淡化与综合利用研究所,天津 300074;2.江苏中鼎环境工程股份有限公司,江苏 宜兴 214221
基金项目:国家重点研发计划;对发展中国家科技援助项目;中央级公益性科研院所基本科研业务费专项
摘    要:电渗析-超滤耦合技术(EDUF)是一项用于分离带电有机物的新型技术,用超滤膜替换一部分离子交换膜,或将超滤膜嵌入到传统电渗析器中,从而形成一种超滤与电渗析内部结合的新型分离技术。该技术一方面利用超滤膜的孔径差异性分离不同分子量的带电有机物,另一方面利用电驱动原理克服压力驱动式超滤膜的膜污染问题,在营养食品、生物制药等领域用于分离提纯活性有机物组分,展示出了良好的应用优势。本文聚焦于电渗析-超滤耦合技术的产生和发展,详细介绍了该技术的技术原理及应用优势,重点阐述了影响其分离效率的主要因素,包括pH、超滤膜切割分子量(MWCO)、电场强度、膜对结构等。最后,从提高分离效率、降低系统能耗、超滤膜材质、水解液预处理、系统泄漏等角度提出了未来的研究方向,为该技术的研究和应用提供指导。

关 键 词:电渗析  超滤  耦合  有机物  分离  
收稿时间:2020-07-10

Development of electrodialysis with ultrafiltration membrane technology
SU Huichao,ZHANG Tianming,WU Yunqi,XU Guorong. Development of electrodialysis with ultrafiltration membrane technology[J]. Chemical Industry and Engineering Progress, 2020, 39(z2): 1-7. DOI: 10.16085/j.issn.1000-6613.2020-1316
Authors:SU Huichao  ZHANG Tianming  WU Yunqi  XU Guorong
Affiliation:1.The Institute of Seawater Desalination and Multipurpose Utilization, Ministry of Natural Resources, Tianjin 300192, China
2.Jiangsu Zhongding Environment Engineering Share Co. , Ltd. , Yixing 214221, Jiangsu, China
Abstract:Electrodialysis with ultrafiltration membrane(EDUF) is a innovative technology for separation of organic charged molecules. It is an internal combination of electrodialysis (ED) and UF processes, with UF membranes are stacked or replaced partial ion-exchange membranes in a conventional ED stack. The ultrafiltration membrane is stacked as a different molecular barrier according to the different molecular weight cut-off of the UF membrane. And the driving force of the process is an external electric field, contrary to pressure-driven processes, no significant fouling at membrane interface was detected. It has been found effective in numerous potential applications in the food and bio-pharmaceutical industry for the separation and the recovery of bioactive compounds. In this process, it is the focus of the emergence and development of EDUF. The main factors affecting the separation efficiency are discussed, inclouding pH, the molecular weight cut-off of the UF membrane(MWCO), the appropriate electric field, stack configuration and so on. Finally, the future research direction is proposed for improving separation efficiency, reducing system energy consumption, ultrafiltration membrane material, hydrolysate pretreatment, system leakage. It will provide guidance for the research and application of this technology.
Keywords:electrodialysis  ultrafiltration  coupling  organic matter  separation  
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