| 气相色谱-质谱联用检测进出口水产品中氟乐灵残留 |
| |
| 引用本文： | 李晓玉,付建,隋涛,曹鹏,池连学,娄喜山. 气相色谱-质谱联用检测进出口水产品中氟乐灵残留[J]. 食品科学, 2011, 32(16): 315-317. DOI: 10.7506/spkx1002-6630-201116068 |
| |
| 作者姓名： | 李晓玉 付建 隋涛 曹鹏 池连学 娄喜山 |
| |
| 作者单位： | 1. 烟台出入境检验检疫局2.烟台杰科检测服务有限公司3.山东农业大学食品科学与工程学院 |
| |
| 摘 要： | 采用液液萃取的前处理方式，以气相色谱-质谱联用仪(gas chromatography- mass spectrometry，GC-MS)检测水产品中氟乐灵的残留量。水产品经过匀质，丙酮提取，正己烷进行液液分配，弗罗里硅土柱净化后，用气相色谱-质谱联用仪进行测定和确认，外标法定量。该方法在5～100μg/L质量浓度范围内，相关系数R2为0.99996，具有良好的线性关系，检测限均为1.0μg/kg。分别在鳗鱼、梭子蟹、黄花鱼、印度虾和蛤蜊5种水产品中添加1～4μg/L氟乐灵，回收率在82.0%～93.6%之间。该方法操作简单、灵敏度高，可以满足水产品中氟乐灵的定性定量检测要求。
|
| 关 键 词： | 气相色谱-质谱法(GC-MS) 水产品 氟乐灵 |
| 收稿时间： | 2018-05-21 |
Determination of Trifluralin Residues in Imported and Exported Aquatic Products by Gas Chromatography-Mass Spectrometry |
| |
| LI Xiao-yu,FU Jian,SUI Tao,CAO Peng,,CHI Lian-xue,LOU Xi-shan. Determination of Trifluralin Residues in Imported and Exported Aquatic Products by Gas Chromatography-Mass Spectrometry[J]. Food Science, 2011, 32(16): 315-317. DOI: 10.7506/spkx1002-6630-201116068 |
| |
| Authors: | LI Xiao-yu FU Jian SUI Tao CAO Peng CHI Lian-xue LOU Xi-shan |
| |
| Affiliation: | (1. Yantai Entry-Exit Inspection and Quarantine Bureau, Yantai 264000, China；2. Yantai Jieke Inspection Service Co. Ltd., Yantai 265231, China；3. College of Food Science and Engineering, Shandong Agricultural University, Taian 271018, China) |
| |
| Abstract: | A gas chromatography-mass spectrometry (GC-MS) method is presented for determining trifluralin residues in aquatic products in this paper. In the method, extraction with acetone, partition with n-hexane and cleanup on a Florisil solid-phase extraction column were used for sample preparation, and quantification was performed by the external standard method. Trifluralin concentration exhibited a good linearity over the range of 5－100μg/L, with a correlation coefficient of 0.99996. The detection limit of this method was 1.0μg/kg for trifluralin. The recovery rates of trifluralin in eel, corvine, India shrimp, clams and swimming crab across the spike levels of 1.0, 2.0μg/kg and 4.0μg/kg were 82.0%－93.6%. This simple and sensitive method can be applied for the determination of trifluralin residues in aquatic products. |
| |
| Keywords: | gas chromatography-mass spectrometry(GC-MS) aquatic product trifluralin |
| 本文献已被 CNKI 等数据库收录！ |
| 点击此处可从《食品科学》浏览原始摘要信息 |
|
点击此处可从《食品科学》下载全文 |
|
