| 低共熔溶剂对煤焦油柴油馏分中氮化物的脱除 |
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| 引用本文： | 赵宁,刘东,李志恒,郭中山,娄斌,于冉,王峰. 低共熔溶剂对煤焦油柴油馏分中氮化物的脱除[J]. 石油学报(石油加工), 2020, 36(2): 410-419. DOI: 10.3969/j.issn.1001-8719.2020.02.023 |
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| 作者姓名： | 赵宁 刘东 李志恒 郭中山 娄斌 于冉 王峰 |
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| 作者单位： | 1中国石油大学(华东) 化学工程学院 重质油国家重点实验室，山东 青岛 266580；2神华宁夏煤业集团有限责任公司 煤制油分公司，宁夏 银川 751410 |
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| 基金项目： | 基金项目： 国家重点研发计划基金项目（2017YFB0602500）资助 |
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| 摘 要： | 以氯化胆碱(ChCl)为氢键受体(HBA)，分别与不同类型氢键供体(HBD)反应合成一系列氯化胆碱型低共熔溶剂(DES)，并用于脱除模型油和中低温煤焦油柴油馏分中氮化物。考察不同类型氢键供体和水分含量对低共熔溶剂碱性氮脱除率的影响。结果表明：氢键供体的酸性越强，合成的低共熔溶剂对碱性氮化物的脱除率越高；水的存在会显著提高低共熔溶剂对碱性氮化物的脱除率；在剂/油质量比1∶2、萃取温度50 ℃、萃取时间40 min、沉降2 h条件下，含有一定水分的氯化胆碱/草酸型低共熔溶剂D4对中低温煤焦油柴油馏分中氮化物有较高的脱除率，对碱性氮脱除率达到98.06%，总氮脱除率为75.29%。
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| 关 键 词： | 低共熔溶剂 氯化胆碱 煤焦油 柴油馏分 脱氮 |
| 收稿时间： | 2019-03-26 |
Removal of Nitrogen Compounds From Diesel Fraction of Coal Tar With Deep Eutectic Solvents |
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| ZHAO Ning,LIU Dong,LI Zhiheng,GUO Zhongshan,LOU Bin,YU Ran,WANG Feng. Removal of Nitrogen Compounds From Diesel Fraction of Coal Tar With Deep Eutectic Solvents[J]. Acta Petrolei Sinica (Petroleum Processing Section), 2020, 36(2): 410-419. DOI: 10.3969/j.issn.1001-8719.2020.02.023 |
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| Authors: | ZHAO Ning LIU Dong LI Zhiheng GUO Zhongshan LOU Bin YU Ran WANG Feng |
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| Affiliation: | 1State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, China University of Petroleum,Qingdao 266580, China；2CTL Chemical of SNCG, Yinchuan 751410, China |
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| Abstract: | A series of ChCl type deep eutectic solvents (DESs) were synthesized through the reaction of choline chloride (ChCl), a hydrogen bond acceptor (HBA), and various hydrogen bond donors (HBDs). Then the above DESs were used to remove nitrogen compounds from model oil and diesel fraction of mid-low temperature coal tar. In addition, effects of various HBDs and moisture contents in DESs on nitrogen removal efficiency were further studied. Experimental results indicate that nitrogen removal efficiency of different DESs increases with acidity strength of HBDs. It is found that water in EDSs can significantly improve basic nitrogen removal efficiency. Deep eutectic solvent D4 has the best performance to remove nitrogen compounds from diesel fraction of mid low temperature coal tar. At the conditions of temperature 50 ℃, m(DESs)∶m(Oil)=1∶2, extraction time 40 min and settling time 2 h, basic nitrogen and total nitrogen removal efficiency can reach 98.06% and 75.29%, respectively. |
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| Keywords: | deep eutectic solvent choline chloride coal tar diesel fraction denitrogenation |
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