| 一步水热法制备电解水析氧反应Ni3S2@Mo2S3高效催化剂 |
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| 引用本文： | 赵娟,吴梦成,雷惊雷,李凌杰. 一步水热法制备电解水析氧反应Ni3S2@Mo2S3高效催化剂[J]. 化工学报, 2022, 73(4): 1575-1584. DOI: 10.11949/0438-1157.20211147 |
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| 作者姓名： | 赵娟 吴梦成 雷惊雷 李凌杰 |
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| 作者单位： | 重庆大学化学化工学院，重庆 400044 |
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| 基金项目： | 国家自然科学基金项目(22072008)； |
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| 摘 要： | 采用一步水热法，由泡沫钼镍合金同时提供钼源和镍源在泡沫钼镍合金表面原位制备了Ni3S2@Mo2S3，并将其直接作为自支撑电极用于催化碱性介质中的电解水析氧反应（OER）。利用多种表征测试技术研究了样品的形貌、组成、OER电催化性能，结果显示：Ni3S2@Mo2S3呈纳米板形貌，由六方Ni3S2和单斜Mo2S3按5∶1的比例复合而成；在1 mol·L-1 KOH 溶液中，Ni3S2@Mo2S3催化剂仅需要170 mV过电位就可达到10 mA·cm-2电流密度（欧姆补偿后），且在50 h的稳定性测试期间性能基本无衰减，优于贵金属催化剂IrO2以及文献报道的Ni-Mo基复合催化剂。Ni3S2@Mo2S3具有优异电催化性能的原因可归于不同过渡金属化合物的协同作用、原位生长自支撑、电化学活性面积大以及液下疏气性等因素。
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| 关 键 词： | 水热 电化学 催化 析氧反应 |
| 收稿时间： | 2021-08-12 |
One-step hydrothermal method toward preparation of Ni3S2@Mo2S3 high-efficient catalyst for oxygen evolution reaction in water electrolysis |
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| ZHAO Juan,WU Mengcheng,LEI Jinglei,LI Lingjie. One-step hydrothermal method toward preparation of Ni3S2@Mo2S3 high-efficient catalyst for oxygen evolution reaction in water electrolysis[J]. Journal of Chemical Industry and Engineering(China), 2022, 73(4): 1575-1584. DOI: 10.11949/0438-1157.20211147 |
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| Authors: | ZHAO Juan WU Mengcheng LEI Jinglei LI Lingjie |
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| Affiliation: | School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China |
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| Abstract: | The Ni3S2@Mo2S3 self-supported catalyst for oxygen evolution reaction in water electrolysis was in situ synthesized on MoNi foam (MNF) by one-step hydrothermal method with MNF as the sources of Ni and Mo. The morphology, composition and OER electrocatalytic performance of the as-prepared catalyst were characterized by the corresponding characterization techniques and electrochemical methods. The catalyst was consisted of irregular nano-slabs with the composition of hexagonal Ni3S2 and monoclinic Mo2S3 in a ratio of 5∶1. The as-prepared Ni3S2@Mo2S3 only needed an overpotential of 170 mV (after IR compensation) to drive a current density of 10 mA·cm-2 in 1 mol·L-1 KOH with negligible degradation during the 50 h stability test, which was superior to the commercial catalyst IrO2 and other Ni-Mo based catalysts reported. The excellent electrocatalytic performance of Ni3S2@Mo2S3 can be attributed to the synergistic effect of different transition metal compounds, self-supporting in situ growth, large electrochemically active area, and aerophobicity under liquid. |
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| Keywords: | hydrothermal electrochemistry catalysis oxygen evolution reaction |
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