Hybridization of MOFs and COFs: A New Strategy for Construction of MOF@COF Core–Shell Hybrid Materials |
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| Authors: | Yongwu Peng Meiting Zhao Bo Chen Zhicheng Zhang Ying Huang Fangna Dai Zhuangchai Lai Xiaoya Cui Chaoliang Tan Hua Zhang |
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| Affiliation: | Center for Programmable Materials, School of Materials Science and Engineering, Nanyang Technological University, Singapore, Singapore |
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| Abstract: | The exploration of new porous hybrid materials is of great importance because of their unique properties and promising applications in separation of materials, catalysis, etc. Herein, for the first time, by integration of metal–organic frameworks (MOFs) and covalent organic frameworks (COFs), a new type of MOF@COF core–shell hybrid material, i.e., NH2‐MIL‐68@TPA‐COF, with high crystallinity and hierarchical pore structure, is synthesized. As a proof‐of‐concept application, the obtained NH2‐MIL‐68@TPA‐COF hybrid material is used as an effective visible‐light‐driven photocatalyst for the degradation of rhodamine B. The synthetic strategy in this study opens up a new avenue for the construction of other MOF–COF hybrid materials, which could have various promising applications. |
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| Keywords: | core– shell structure covalent organic frameworks (COFs) metal‐organic frameworks (MOFs) MOF@COF hybrid material photocatalyst |
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