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醋酸乙烯与双环戊二烯顺丁烯二酸单酯的共聚
引用本文:侯慧玉,涂伟萍. 醋酸乙烯与双环戊二烯顺丁烯二酸单酯的共聚[J]. 化工学报, 2007, 58(2): 518-521
作者姓名:侯慧玉  涂伟萍
作者单位:华南理工大学化工与能源学院,广东,广州,510640;华南理工大学化工与能源学院,广东,广州,510640
摘    要:引言 聚醋酸乙烯乳液是热塑性树脂,它具有粘接强度高、固化速度快、胶黏范围广泛、制备简单、使用方便等优点,但其软化点较低,且合成中通常用亲水性聚乙烯醇作保护胶,因而其耐热性和耐水性都较差,降低了其使用价值.

关 键 词:乳液聚合  醋酸乙烯  双环戊二烯  双环戊二烯顺丁烯二酸单酯
文章编号:0438-1157(2007)02-0518-04
收稿时间:2005-10-26
修稿时间:2005-10-262006-03-16

Co-polymerization of vinyl acetate and DHCM
HOU Huiyu,TU Weiping. Co-polymerization of vinyl acetate and DHCM[J]. Journal of Chemical Industry and Engineering(China), 2007, 58(2): 518-521
Authors:HOU Huiyu  TU Weiping
Affiliation:School of Chemical Engineering and Energy, South China University of Technology, Guangzhou 510640, Guangdong, China
Abstract:By using dicyclopentadiene reacting with maleic acid, dicyclopentadiene maleate (DHCM) was synthesized and its structure was characterized with IR and NMR spectrumThe co-polymerization of vinyl acetate and DHCM was studied at 70℃The structure and particle morphology of the co-polymer were characterized with IR and TEMThe effects of DHCM content on the monomer conversion and average particle size were investigatedThe results showed that when DHCM content was 2%(mass), the synthesized latex was of high conversion efficiency, small particle size and good stability.
Keywords:emulsion polymerization   vinyl acetate   dicyclopentadiene   dicyclopentadiene maleate
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