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膜技术在含钴浓盐水资源化中应用
引用本文:彭文博,李腾飞,白祖国,陈道康,恽建军. 膜技术在含钴浓盐水资源化中应用[J]. 无机盐工业, 2020, 52(5): 65-67. DOI: 10.11962/1006-4990.2019-0368
作者姓名:彭文博  李腾飞  白祖国  陈道康  恽建军
作者单位:江苏久吾高科技股份有限公司,江苏南京 211808
摘    要:采用陶瓷膜-二级纳滤-树脂-蒸发集成工艺对含钴高盐废水做处理研究,分析了膜通量随时间衰减变化趋势,确定了树脂吸附优化条件,核算了废水处理成本及收益。结果表明:50 nm陶瓷膜能有效去除水中悬浮颗粒,通量达到933 L/(m 2·h);纳滤膜能有效实现氯化钴与氯化铵分离,二级平均钴去除率达到71.14%;树脂能深度净化氯化铵溶液,得到的氯化铵产品满足GB/T 2946—2018《氯化铵》。该工艺是一种经济可行的含钴废水处理工艺。

关 键 词:含钴废水  陶瓷膜  纳滤  离子交换树脂  
收稿时间:2019-11-11

Application of membrane technology in resource recovery of cobalt-containing saline wastewater
Peng Wenbo,Li Tengfei,Bai Zuguo,Chen Daokang,Yun Jianjun. Application of membrane technology in resource recovery of cobalt-containing saline wastewater[J]. Inorganic Chemicals Industry, 2020, 52(5): 65-67. DOI: 10.11962/1006-4990.2019-0368
Authors:Peng Wenbo  Li Tengfei  Bai Zuguo  Chen Daokang  Yun Jianjun
Affiliation:Jiangsu Jiuwu Hi-Tech Co.,Ltd.,Nanjing 211808,China
Abstract:Cobalt-containing wastewater was treated by ceramic membrane-two stage nanofiltration-resin-evaporation process. The trend of membrane flux changing with time was analyzed.The optimum conditions of resin adsorption was determined and the economic benefits of wastewater treatment process were calculated.The results showed that 50 nm ceramic membrane can effectively remove suspended particles in wastewater,and the flux reached 933 L/(m 2·h).CoCl2 can be separated effectively from NH4Cl by nanofiltration,and the removal rate of Co 2+ reached 71.14%.After deep purification of by resin,NH4Cl met the requirement of GB/T 2946—2018,Ammonium Chloride.The treatment process is an economical and feasible cobalt-contain-ing wastewater treatment process.
Keywords:wastewater containing-cobalt  ceramic membrane  nanofiltration  ion exchange resin  
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