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含氰工业废盐中杂质的高温氧化脱除实验研究
引用本文:姜海超,申银山,陈晓飞,刘玉敏,张向京,程丽华,胡永琪. 含氰工业废盐中杂质的高温氧化脱除实验研究[J]. 无机盐工业, 2020, 52(2): 62-64. DOI: 10.11962/1006-4990.2019-0136
作者姓名:姜海超  申银山  陈晓飞  刘玉敏  张向京  程丽华  胡永琪
作者单位:1. 河北科技大学,河北石家庄 0500182. 河北诚信有限责任公司
摘    要:在氰乙酸和三聚氯氰等产品生产的同时副产大量的含氰氯化钠废盐,这些工业废盐含有氰化物和有机物等杂质,需精制后才能回收再利用。采用流化床高温氧化方法对含氰工业废盐中有氰化物和有机物的杂质做脱除实验研究。实验结果表明,温度在700 ℃以上、停留时间为3 min时,经高温流化氧化处理后工业废盐中的总有机碳(TOC)、无机铵和总铵可达到离子膜烧碱用原料盐标准;处理后的工业盐中未检测到氰。该研究为含氰工业废盐精制过程和装置的进一步放大提供了实验依据。

关 键 词:  工业废盐  精制  流化床  
收稿时间:2019-08-14

Experimental study on high temperature oxidation removal of impurities in cyanide-contained industrial waste salts
Jiang Haichao,Shen Yinshan,Chen Xiaofei,Liu Yumin,Zhang Xiangjing,Cheng Lihua,Hu Yongqi. Experimental study on high temperature oxidation removal of impurities in cyanide-contained industrial waste salts[J]. Inorganic Chemicals Industry, 2020, 52(2): 62-64. DOI: 10.11962/1006-4990.2019-0136
Authors:Jiang Haichao  Shen Yinshan  Chen Xiaofei  Liu Yumin  Zhang Xiangjing  Cheng Lihua  Hu Yongqi
Affiliation:1. Hebei University of Science and Technology,Shijiangzhuang 050018,China2. Hebei Chengxin Co.,Ltd.
Abstract:In the production of cyanoacetic acid and cyanuric chloride,a large amount of cyanide-contained industrial waste salt is produced as a by-product.The industrial waste salt needs to be further refined to be recycled due to the highly toxic cyanide and other organic impurities.High temperature oxidation method was employed to remove the impurities in the in-dustrial waste salt with experimental fluidized bed.The results showed that the TOC,inorganic ammonium and total ammoni-um in the industrial waste salt can reach the standard of raw material salt for ionic membrane caustic soda after high tempera-ture oxidation treated in the fluidized bed at above 700 ℃ for 3 min,and there was no cyanide detected.This study provides an experimental basis for the scale up of the cyanide industrial waste salt refining process and apparatus.
Keywords:cyanide  industrial waste salt  refining  fluidized bed  
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