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Accelerated weathering properties of compatibilized composites made from recycled HDPE and nonmetallic printed circuit board waste
Authors:Shantha Kumari Muniyandi  Johan Sohaili  Azman Hassan
Affiliation:1. Department of Quantity Surveying and Real Estate, Faculty of Engineering and Built Environment, Tunku Abdul Rahman University College, Jalan Genting Kelang, Setapak, Kuala Lumpur, Malaysia;2. Department of Environmental, Faculty of Civil Engineering, Universiti Teknologi Malaysia, Johor, Malaysia;3. Department of Polymer Engineering, Faculty of Chemical Engineering, Universiti Teknologi Malaysia, Johor, Malaysia
Abstract:The main aim of this work is to examine the influence of the contents of nonmetallic printed circuit board (PCB) waste component on the photodegradation of recycled high‐density polyethylene (rHDPE) composites. The properties tested were chemical changes, flexural properties, color stability, water absorption, leaching properties, and crystallinity changes of the composites after exposure to 2,000 h of accelerated weathering. Surface degradation for composites with nonmetallic PCB was less compared to unfilled rHDPE mainly because glass fibers covered almost the whole surface of specimens, acting as a protective layer, thus, slowing down the photodegradation reaction. Incorporation of compatibilizer in rHDPE/PCB composites had played an important role in resisting degradation due to UV exposure. All the composite samples became lighter in the early stages of weathering exposure; however, compatibilized composites showed less lightening and reduction on strength and modulus. Carbonyl index increases with exposure time indicating that the oxidation reaction continuously occurred during the aging process. Incorporation of compatibilizer had successfully reduced the water absorption uptake by the composites and effectively delayed some degradation properties of weathering. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43110.
Keywords:compatibilization  composites  degradation  mechanical properties
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