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Effect of Different Cosolvents on Transesterification of Waste Cooking Oil in a Microreactor
Authors:Babak Aghel  Majid Mohadesi  Sasan Sahraei
Affiliation:Kermanshah University of Technology, Department of Chemical Engineering, Faculty of Energy, Kermanshah, Iran
Abstract:Biodiesel was prepared from waste cooking oil combined with methanol. The process was performed via transesterification in a microreactor using kettle limescale as a heterogeneous catalyst and various cosolvents under different conditions. n‐Hexane and tetrahydrofuran were selected as cosolvents to investigate fatty acid methyl esters (FAMEs). To optimize the reaction conditions, the main parameters affecting FAME% including reaction temperature, catalyst concentration, oil‐to‐methanol volumetric ratio, and cosolvent‐to‐methanol volumetric ratio were studied via response surface methodology. Under optimal reaction conditions and in the presence of the cosolvents n‐hexane and tetrahydrofuran, high FAME purities were achieved. Considering the experimental results, the limescale catalyst is a unique material, and the cosolvent method can reduce significantly the reaction time and biodiesel production cost.
Keywords:Biodiesel  Cosolvent  Heterogeneous catalyst  Microreactor  Waste cooking oil
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