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CF4和惰性气体混合物的输运性质的计算
引用本文:Soodabeh Nikmanesh,Jalil Moghadasi,Mohammad Mehdi Papari. CF4和惰性气体混合物的输运性质的计算[J]. 中国化学工程学报, 2009, 17(5): 814-821. DOI: 10.1016/S1004-9541(08)60281-5
作者姓名:Soodabeh Nikmanesh  Jalil Moghadasi  Mohammad Mehdi Papari
作者单位:1. Department of Chemistry, Shiraz University, Shiraz 71454, Iran;2. Department of Chemistry, Shiraz University of Technology, Shiraz 71555-313, Iran
基金项目:Research Committees of Shiraz University and Shiraz University of Technology for supporting this project and making computer facilities available
摘    要:The present work is concerned with determining the viscosity, diffusion, thermal diffusion factor and thermal conductivity of five equimolar binary gas mixtures including: CF4-He, CF4-Ne, CF4-Ar, CF4-Kr, CF4-Xe from the principle of corresponding states of viscosity by the inversion technique. The Lennard-Jones (12-6) model potential is used as the initial model potential. The calculated interaction potential energies obtained from the inversion procedure is employed to reproduce the viscosities, diffusions, thermal diffusion factors, and thermal conductivities. The accuracies of the calculated viscosity and diffusion coefficients were 1% and 4%, respectively.

关 键 词:corresponding states principle  diffusion  inversion method  kinetic theory of gases  thermal conductivity  transport properties  viscosity  
收稿时间:2009-01-05
修稿时间:2009-6-25 

Calculation of transport properties of CF4+noble gas mixtures
Soodabeh Nikmanesh,Jalil Moghadasi,Mohammad Mehdi Papari. Calculation of transport properties of CF4+noble gas mixtures[J]. Chinese Journal of Chemical Engineering, 2009, 17(5): 814-821. DOI: 10.1016/S1004-9541(08)60281-5
Authors:Soodabeh Nikmanesh  Jalil Moghadasi  Mohammad Mehdi Papari
Affiliation:1. Department of Chemistry, Shiraz University, Shiraz 71454, Iran;2. Department of Chemistry, Shiraz University of Technology, Shiraz 71555-313, Iran
Abstract:The present work is concerned with determining the viscosity, diffusion, thermal diffusion factor and thermal conductivity of five equimolar binary gas mixtures including: CF4-He, CF4-Ne, CF4-Ar, CF4-Kr, CF4-Xe from the principle of corresponding states of viscosity by the inversion technique. The Lennard-Jones (12-6) model potential is used as the initial model potential. The calculated interaction potential energies obtained from the inversion procedure is employed to reproduce the viscosities, diffusions, thermal diffusion factors, and thermal conductivities. The accuracies of the calculated viscosity and diffusion coefficients were 1% and 4%, respectively.
Keywords:corresponding states principle  diffusion  inversion method  kinetic theory of gases  thermal conductivity  transport properties  viscosity
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