Fully Solution‐Processed Conductive Films Based on Colloidal Copper Selenide Nanosheets for Flexible Electronics |
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| Authors: | Sergey Vikulov Francesco Di Stasio Luca Ceseracciu Pearl L. Saldanha Alice Scarpellini Zhiya Dang Roman Krahne Liberato Manna Vladimir Lesnyak |
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| Affiliation: | 1. Department of Nanochemistry, Istituto Italiano di Tecnologia, Genoa, Italy;2. Smart Materials, Istituto Italiano di Tecnologia, Genoa, Italy;3. Physical Chemistry, TU Dresden, Dresden, Germany |
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| Abstract: | A novel colloidal synthesis of copper selenide nanosheets (NSs) with lateral dimensions of up to 3 μm is developed. This material is used for the fabrication of flexible conductive films prepared via simple drop‐casting of the NS dispersions without any additional treatment. The electrical performance of these coatings is benchmarked against copper selenide spherical nanocrystals (SNCs) in order to demonstrate the advantage of 2D morphology of the NSs for flexible electronics. In this contest, Cu2?xSe SNC films exhibit higher conductivity but lower reproducibility due to the formation of cracks leading to discontinuous films. Furthermore, the electrical properties of the films deposited on different flexible substrates following their bending, stretching and folding are studied. A comparison of Cu2?xSe SNC and CuSe NS films reveals an increased stability of the CuSe NS films under mechanical stress applied to the samples and their improved long‐term stability in air. |
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| Keywords: | colloidal synthesis copper selenide flexible conductive films nanocrystals nanosheets |
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