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三类聚酸酐的重均分子质量与特性粘度的关系
引用本文:帅心涛,谭惠民,王晓青. 三类聚酸酐的重均分子质量与特性粘度的关系[J]. 北京理工大学学报(英文版), 1998, 7(1): 39-42
作者姓名:帅心涛  谭惠民  王晓青
作者单位:北京理工大学化工与材料学院
摘    要:研究聚酸酐重均分子质量与特性粘度的关系.方法通过溶液沉淀分级法,以氯仿为溶济,石油醚为沉淀剂,对聚酸酐行分级,并测定出每一级分的绝对重均分子质量和特性粘度.结果与结论从特性粘度与分子质量的双对数图中,得出了三类聚酸酐重均分子质量与特性粘度的关系.

关 键 词:聚酸酐;[n]-M关系;光散射;特性粘度

Relationships Between Average Molecular Mass and Intrinsic viscosity of Three Typical Polyanhydrides
Shuai Xintao,Tan Huimin and Wang Xiaoqing. Relationships Between Average Molecular Mass and Intrinsic viscosity of Three Typical Polyanhydrides[J]. Journal of Beijing Institute of Technology, 1998, 7(1): 39-42
Authors:Shuai Xintao  Tan Huimin  Wang Xiaoqing
Affiliation:School of Chemical Engineering and Materials Science, Science, beijing Institute of Technology, Beijing 100081;School of Chemical Engineering and Materials Science, Science, beijing Institute of Technology, Beijing 100081;School of Chemical Engineering and Materials Science, Science, beijing Institute of Technology, Beijing 100081
Abstract:Aim To study the relationships between average molecular mass and intrinsic viscosity of polyanhydrides. Methods With chloroform as solvent and petroleum ether as the precipitating agent polyanhydride was separated into a series of grades with different average molecular mass. The absolute average molecular mass (M) and intrinsic viscosity ([]) of every grade were measured. Results and Conclusion The relationships between [] and M of three typical polyanhydrides were obtained from bi-logarithm coordinate plotting of [] versus M.
Keywords:polanhydrides  []-M relationship  light scattering  intrinsic viscosity
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