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Electrically insulating polymeric nanocomposites with enhanced thermal conductivity by visible‐light curing of epoxy–boron nitride nanotube formulations
Authors:Marco Sangermano  Nicolò Razza  Gabriele Graham  Irati Barandiaran  Galder Kortaberria
Affiliation:1. Dipartimento di Scienza Applicata e Tecnologia, Politecnico di Torino, Torino, Italy;2. Chemical and Environmental Engineering Department, Escuela de Ingeniería de Gipuzkoa, Donostia, Spain
Abstract:Epoxy–boron nitride nanotube (BNNT) composites were prepared using visible light through a radical‐induced cationic polymerization method activated by camphorquinone. The fully cured films showed an enhancement of glass transition temperature in the presence of the filler. Electrical characterization showed a slight dielectric constant decrease with BNNT content. Finally, thermal conductivity measured using nano‐flash analysis showed a linear increase in the thermal conductivity of the materials with increasing BNNT content in the photocurable formulations. © 2017 Society of Chemical Industry
Keywords:epoxy composites  thermal conductivity  electrically insulating properties
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