Melt extruded nanocomposites of polybutylene adipate‐co‐terephthalate (PBAT) with phenylbutyl isocyanate modified cellulose nanocrystals |
| |
| Authors: | Carolina L Morelli Naceur Belgacem Rosario E. S. Bretas Julien Bras |
| |
| Affiliation: | 1. Univ. Grenoble Alpes, LGP2, Saint Martin D'Hères, France;2. Materials Engineering Department, Federal University of S?o Carlos (UFSCar), S?o Carlos, SP, Brazil |
| |
| Abstract: | Traditional commodity polymers are widely used in several disposable or short‐life items and take hundreds of years to decompose in nature. These polymers could be replaced in several uses by biodegradable polymers, like polybutylene adipate‐co‐terephthalate (PBAT) studied in this work. For this, nonetheless, it is necessary to improve some of the PBAT properties, like mechanical resistance and barrier properties. In this work, cellulose nanocrystals (CNC) were incorporated in PBAT with this intention, through melt extrusion. Aiming to avoid CNC aggregation during the drying and extrusion process, a CNC chemical modification with phenylbutyl isocyanate was done. It was possible to obtain PBAT‐CNC melt extruded composites with an elastic modulus 55% higher and water vapor permeability 63% lower than the values of the pure polymer, without compromising PBAT biodegradation. Therefore, the composites prepared with these enhanced properties have great potential as substitutes for traditional commodity polymers. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43678. |
| |
| Keywords: | biodegradable cellulose and other wood products extrusion grafting nanoparticles nanowires and nanocrystals |
|
|
