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采用低黏度的3官能树脂搭配脂肪酸改性环氧纯丙树脂(6071)和三羟甲基丙烷三丙烯酸酯(TMPTA)树脂为主要成膜物,以1173、184为光引发剂,添加少量的2官能团硅改性丙烯酸酯以改善流平性能,研制出ABS塑胶紫外光固化涂料,讨论了预聚体结构、光引发剂及稀释剂等对UV光固化表面涂层性能的影响以及塑胶用UV涂料常见问题的解决措施.所制涂料综合性能良好,可应用于ABS塑胶底材的表面涂饰. 相似文献
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以丙烯酸羟丙酯(HPA)、1,6-己二异氰酸酯(HDI)三聚体为主要原料合成低相对分子质量三官能度聚氨酯丙烯酸酯(PUA)低聚物,以该低聚物为主体树脂,添加活性稀释剂、丙烯酸共聚体系、光引发剂及其他涂料助剂制成紫外光(UV)固化聚氨酯丙烯酸酯涂料。同时对UV固化膜性能进行研究,分别讨论了主体树脂含量、活性稀释剂含量、丙烯酸体系含量及光引发剂含量对UV固化涂膜性能的影响,进而对涂料不同组分的种类及配比进行优化,确定了紫外光(UV)固化聚氨酯丙烯酸酯涂料的工艺配方,研究结果表明:该涂料的玻璃化温度(Tg)为60.9℃,涂膜具有较好的综合性能。 相似文献
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《中国胶粘剂》2016,(10)
以环氧丙烯酸酯树脂、环氧树脂(EP)、自由基光引发剂和阳离子光引发剂为主要原料,制备混杂UV(紫外光)固化胶粘剂,并且采用响应面法对混杂UV固化胶粘剂的配方进行优化;以预聚体配比、光引发剂配比作为自变量,以混杂UV固化胶粘剂在玻璃上的附着力作为因变量,采用Design Expert软件对2个自变量进行多次拟合,建立相应的数学模型和3维曲面,得到最优的混杂UV固化胶粘剂配方并进行验证。研究结果表明:二项式是描述因变量和自变量之间关系的最佳模型,当环氧丙烯酸酯树脂/EP质量比为1.19、自由基光引发剂/阳离子光引发剂质量比为1.00时,制成的混杂UV固化胶粘剂在玻璃基材上的附着力(9级)相对最强。 相似文献
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为制备贮存稳定性优良的紫外光(UV)固化涂料,采用自制改性环氧丙烯酸酯树脂、活性稀释剂、光引发剂和阻聚剂制备了UV固化涂料体系并通过考察50°C下贮存7 d前后黏度的变化,研究了活性稀释剂、光引发剂和阻聚剂种类及用量对贮存稳定性的影响,并确定了最优体系:活性稀释剂w(己二醇二丙烯酸酯)=20%~30%,光引发剂w(Darocur 11733)=3.0%,阻聚剂w(对羟基苯甲醚)=0.04%。用红外光谱、凝胶渗透色谱等对贮存前后的体系进行了表征。测试了以最优体系为基础配制的UV涂料的涂膜性能。结果表明,加速贮存7 d后,涂料体系的重均分子量和数均分子量分别增加393 g/mol和403 g/mol,C═C双键含量仅损失4.9%,可见涂料具有较好的贮存稳定性,其漆膜性能与贮存前相比并无差异。 相似文献
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以不饱和聚酯为光敏预聚物,加入光引发剂制得天然大理石表面紫外光固涂层(流水线作业)。研究了光引发剂用量对涂层性能的影响,并将UV固化与化学固化浇注体的力学性能和耐热性进行了对比。结果表明,紫外光固化不饱和聚酯树脂涂层的固化效果,硬度和亮度都达到化学固化的效果,且生产效率大大提高。 相似文献
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Preparation of multifunctional thiol‐ and acrylate‐terminated polyurethane: A comparative study on their properties in UV curable coatings
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The multifunctional thiol‐ and acrylate‐terminated polyurethane (PU) has been successfully prepared for using as the main resin in the UV curable coatings. The structure and molecule weight of prepared PUs were analyzed by fourier transformed infrared spectroscopy (FTIR) and gel permeation chromatography, respectively. The results showed that the different terminal multifunctional groups have been grafted onto the PU and their difference in molecule weight was significant. Used as the main resin in coatings, the curing kinetic and percentage conversion of the different UV curing coatings system were investigated by real‐time FTIR method, and the effects of terminal functional groups and photoinitiator on the final conversion percentage and conversion rate were also compared. It is observed that the thiol‐terminated PU had higher conversion speed and final conversion percentage due to the remarkable effect of mercapto groups on reducing oxygen inhibition during UV curing process. The shrinkage, viscosity, and adhesion of UV curable coatings with thiol‐ and acrylate‐terminated PUs were also investigated and compared, and the results indicated that the former exhibited lower shrinkage and higher adhesion performances than the latter, along with the lower viscosity. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40740. 相似文献
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P. Castell M. Wouters H. Fischer G. de With 《Journal of Coatings Technology and Research》2007,4(4):411-423
The curing kinetics of UV-curable powder coatings based on commercial unsaturated polyesters were monitored using photo-DSC,
Real-Time FTIR-ATR and a modified rheometer equipped with a UV source. The effect of physical and chemical factors on curing
such as type of photoinitiator, photoinitiator concentration, temperature and atmosphere of curing were evaluated. Coatings
containing amounts of photoinitiator from 0.5 to 10 wt% were cured at different temperatures in less than 10 s reaching conversions
approximately of 60%. The increase of the temperature of curing reduces the final conversion and also the rate of polymerization
due to the chain transfer process and depolymerization that dominates the photopolymerization at high temperatures. The reactivity
of the photoinitiators was similar for all the studied photoinitiators apart from benzophenone that was found to be the slowest
initiator. 相似文献
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Frank Bauer Roman Flyunt Konstanze Czihal Helmut Langguth Reiner Mehnert Rolf Schubert Michael R. Buchmeiser 《Progress in Organic Coatings》2007
For UV curable coatings, the effect of the type of photoinitiator and of the photoinitiator content on surface properties has been studied. Increasing photoinitiator concentrations yielded higher acrylate conversion but a lowering of surface hardness. Thus, curing under oxygen-free conditions with 2 wt.% photoinitiator should be applied rather than 6 wt.% photoinitiator for irradiation in air. Compared to nanocomposite materials, UV-cured polyacrylate coatings reinforced by silica nanoparticles and corundum microparticles exhibit markedly improved scratch and abrasion resistance. By using various grades of corundum, a synergetic effect between nano- and microparticles has been observed. These nano/micro-hybrid composite materials are recommended as clear coat for parquet and flooring applications. 相似文献
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An organo-modified Boehmite (OMB) was used to prepare nanocomposite UV-cured coatings, based on an innovative photopolymerizable siloxane-modified acrylic formulation, for possible use as protective coatings. 3 wt.% of the nanofiller was dispersed into the mixture in the presence of a proper photoinitiator for UV curing. Different amounts of a silane coupling agent were added to the mixture in order to enhance the compatibility between the nanofiller and the siloxane-modified acrylic formulation. The kinetics of the radical photopolymerization reaction, induced by UV radiations, was studied by photo-calorimetric analysis. The rheological behaviour of the formulations produced was studied as function of the shear rate using a plate and plate rheometer. The formulations, coated on a glass substrate, were photo-cured by using a medium pressure Hg UV lamp. On the coatings photo-polymerized in air were measured: gel content, transparency, scratch and surface hardness. The water absorption effect of the coating based on the novel organic photo-curable nanocomposite on walnut wood elements was evaluated. 相似文献
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以双酚A型环氧树脂紫外光阳离子固化体系为对象,系统研究了光引发剂和各种单体组成对光固化速度及固化膜机械物理性质的影响。结果表明,光引发剂的种类不但可以有效地影响光固化速度,还能对涂层硬度产生影响;环氧稀释剂在降低体系黏度的同时,对光固化速度和硬度产生负面影响;而羟基化合物对光固化速度几乎不产生影响,但是可以大幅度提高涂层的硬度和柔韧性;三元体系中,由于存在加合作用,在光固化速度和物理机械性质两方面都得到了很好的结果。这就使得能够根据具体要求,配制出各种性能都较好的材料,将大大扩展阳离子紫外光固化技术的应用领域。 相似文献