Thermodynamic properties of lithium bromide–water solutions at high temperatures

Emerging triple-effect LiBr–water absorption chillers operate at higher temperatures and pressures than traditional double-effect chillers. However, there is not enough data about thermodynamic properties of LiBr–water solutions at such high temperatures. Using recently measured data of vapor pressure and heat capacity, we have developed the equations which can calculate the vapor pressure, enthalpy and entropy of LiBr solutions at such high temperatures. The developed equations are valid from concentrations of 40–65 wt.% and also from temperatures of 40–210°C. These equations will be very helpful for the modeling and design of triple-effect LiBr–water chillers.     

Simulation study of a hybrid absorber–heat exchanger using hollow fiber membrane module for the ammonia–water absorption cycle

An innovative hybrid hollow fiber membrane absorber and heat exchanger (HFMAE) made of both porous and nonporous fibers is proposed and studied via mathematical simulation. The porous fibers allow both heat and mass transfers between absorption solution phase and vapor phase, while the nonporous fibers allow heat transfer between absorption solution phase and cooling fluid phase only. The application of HFMAE on an ammonia–water absorption heat pump system as a solution-cooled absorber is analyzed and compared to a plate heat exchanger falling film type absorber (PHEFFA). The substantially higher amount of absorption obtained by the HFMAE is made possible by the vast mass transfer interfacial area per unit device volume provided. The most dominant factor affecting the absorption performance of the HFMAE is the absorption solution phase mass transfer coefficient. The application of HFMAE as the solution-cooled absorber and the water-cooled absorber in a typical ammonia–water absorption chiller allows the increase of COP by 14.8% and the reduction of the overall system exergy loss by 26.7%.     

Spray absorbers in absorption systems using lithium nitrate–ammonia solution

In the present work, the spray absorption method is studied for the absorption of ammonia refrigerant vapour by lithium nitrate–ammonia solutions. Mass transfer coefficients attainable using the spray absorption method are estimated. In this study the low-pressure absorber of a double-stage absorption refrigeration system is considered. Results show that the mass transferred is maximum (about 60% of the total) during the deceleration period of the drops. This period represents about 13.4% of the time required to reach the equilibrium state at the end of the absorption chamber. The results show that a time-average mass transfer coefficient equal to k_m=18.6×10⁻⁵ m s⁻¹ may be attained.     

The effect of heat transfer additive and surface roughness of micro-scale hatched tubes on absorption performance

The objectives of this paper are to investigate the effect of heat transfer additive and surface roughness of micro-scale hatched tubes on the absorption performance and to provide a guideline for the absorber design. Two different micro-scale hatched tubes and a bare tube are tested to quantify the effect of the surface roughness on the absorption performance. The roughness of the micro-scale hatched tubes ranges 0.39–6.97 μm. The working fluid is H₂O/LiBr solution with inlet concentration of 55, 58 and 61 wt.% of LiBr. Normal Octanol is used as the heat transfer additive with the concentration of 400 ppm. The absorber heat exchanger consists of 24 horizontal tubes in a column, liquid distributor at the liquid inlet and the liquid reservoir at the bottom of the absorber. The effect of heat transfer additive on the heat transfer rate is found to be more significant in the bare tube than that in the micro-scale hatched tubes. It is found that the absorption performance for the micro-hatched tube with heat transfer additive becomes up to 4.5 times higher than that for the bare tube without heat transfer additive. It is concluded that the heat transfer enhancement by the heat transfer additive is more significant than that by the micro-scale surface treatment.     

Absorption chiller crystallization control strategies for integrated cooling heating and power systems

The concept of an air-cooled absorption chiller system is attractive because the cooling tower and the associated installation and maintenance issues can be avoided. However, crystallization of the LiBr–H₂O solution then becomes the main challenge in the operation of the chiller, since the air-cooled absorber tends to operate at a higher temperature and concentration level than the water-cooled absorber due to the relative heat transfer characteristics of the coolant. This leads to crystallization of the working fluid. The paper focuses on the crystallization issues and control strategies in LiBr–H₂O air-cooled absorption chillers. As a result a novel application opportunity is proposed for the integration of absorption chillers into cooling, heating and power (CHP) systems. This new methodology allows for air cooler operation while avoiding crystallization.     

A simple model for falling film absorption on vertical tubes in the presence of non-absorbables

Most water–lithium bromide (LiBr) absorption chillers have a purge system to remove non-absorbable gases that cause a reduction in cooling capacity. Generally, the non-absorbables are originated in corrosion/passivation processes inside the machine, but leaks can also be a source of concern. However, since leaks must be corrected immediately to avoid machine deterioration, this study is mostly aimed at the non-absorbables evolved during operation. This paper analyses the effect of inlet non-absorbable air concentration, outlet purge velocity, absorber pressure and cooling water temperature on the falling film absorption process inside a vertical tube absorber, based on a simple transport coefficient model. This model consists of three ordinary differential equations solved with as method for initial-value problem, and a set of auxiliary equations. The study shows that the effect of non-absorbables can be significant, and furthermore provides a quantitative framework to aid in purge design. The nominal working conditions in this study were a solution Reynolds number of 100, an absorber pressure of 1.3 kPa, a cooling water temperature of 35 °C and an inlet solution concentration of 62% LiBr by weight. The results indicate that a minimum vapour velocity is required to sweep the non-absorbables along the absorber towards the purge, thus preventing reduced absorption fluxes. At a cooling water temperature of 35 °C, an inlet air concentration of 20% (by mole) resulted in a 61% reduction in mass absorption flux.     

Surface tension of aqueous lithium bromide with heat/mass transfer enhancement additives: the effect of additive vapor transport

Heat/mass transfer enhancement additives used in aqueous lithium bromide absorption chillers are surfactants that lower the surface tension of the working fluid. It has long been speculated that the surface tension characteristics are a key to the enhancement but the point is controversial because some surfactants do not provide enhancement. In the present study, the surface tension of aqueous lithium bromide was measured, with and without various surfactant additives, using a drop weight method. Measurements were also made on water, with and without an additive. The results provide new information that clarifies several confusing aspects of the literature data. The major result is the realization that the surface tension of aqueous lithium bromide is strongly affected by the presence of surfactant vapor around the liquid interface. This apparently explains the large differences in surface tension data found in the literature since no previous studies mentioned the importance of the vapor conditions.     

Experimental correlation of falling film absorption heat transfer on micro-scale hatched tubes

The objectives of this paper are to investigate the effect of surface roughness of micro-hatching tubes on the absorption performance and to develop an experimental correlation of Nusselt number as a function of the roughness. Two different micro-scale hatched tubes and a bare tube are tested to quantify the effect of the surface roughness on the absorption performance. The roughness of the micro-scale hatched tubes ranges 0.386–11.359 μm. The working fluid is H₂O/LiBr solution with inlet concentration of 55, 58 and 61 wt.% of LiBr. The absorber heat exchanger consists of 24 horizontal tubes in a column, liquid distributor at the liquid inlet and the liquid reservoir at the bottom of the absorber. It was found that absorption performance of micro-hatching tubes was improved up to two times compared with the bare tube. An experimental correlation of Nusselt number was developed as a function of the film Reynolds number and the roughness with an error band of ±25%.     

Experimental verification of H2O/LiBr absorber bundle performance with smooth horizontal tubes

A model for absorption of water vapor into LiBr flowing over horizontal smooth tubes is developed to predict the absorption performance of a tube bundle. The performance of a horizontal smooth tube absorber is calculated and compared with experimental data. The calculation results of absorber performance are found to vary considerably depending on mass diffusivity. The literature value of mass diffusivity, of the order of 10⁻⁹ m² s⁻¹, causes the model to deviate from the experimental results especially for solution side heat transfer coefficient. A parametric study varying mass diffusivity shows that a value of 1.0 × 10⁻¹⁰ m² s⁻¹ gives a better agreement with the experimental results. The effects of absorber capacity, heat transfer coefficient of droplets ejected from the system (slinging) and number of tubes in the bundle on the absorption performance are also discussed.     

Energy and exergy analysis of single effect and series flow double effect water–lithium bromide absorption refrigeration systems

In this paper, the energy and exergy analysis of single effect and series flow double effect water–lithium bromide absorption systems is presented. A computational model has been developed for the parametric investigation of these systems. Newly developed computationally efficient property equations of water–lithium bromide solution have been used in the computer code. The analysis involves the determination of effects of generator, absorber and evaporator temperatures on the energetic and exergetic performance of these systems. The effects of pressure drop between evaporator and absorber, and effectiveness of heat exchangers are also investigated. The performance parameters computed are coefficient of performance, exergy destruction, efficiency defects and exergetic efficiency. The results indicate that coefficient of performance of the single effect system lies in range of 0.6–0.75 and the corresponding value of coefficient of performance for the series flow double effect system lies in the range of 1–1.28. The effect of parameters such as temperature difference between heat source and generator and evaporator and cold room have also been investigated. Irreversibility is highest in the absorber in both systems when compared to other system components.     

The role of surfactant adsorption rate in heat and mass transfer enhancement in absorption heat pumps

The importance of heat and mass transfer additives in absorption chillers and heat pumps has been recognized for over three decades. However, a universally accepted model for the mechanisms responsible for enhanced absorption rates has yet to be proposed. The Marangoni effect—an instability arising from gradients in surface tension at the liquid-vapor interface—is generally accepted as the cause of the convective flows that enhance transfer rates. Certain surfactant additives can significantly improve absorption rates and thus reduce the overall transfer area required by a given machine. Any means available that can increase the efficiency and acceptability of absorption machines is to be welcomed, as this technology provides an alternative to vapor compression systems which is both environmentally friendly and more versatile with regards to energy sources. This study investigates the rate at which a surfactant additive adsorbs at a liquid-vapor interface. The residence time of the falling liquid solution in an absorber is quite short. An effective additive must not only reduce the surface tension of the solution; it must do so quickly enough to cause the Marangoni instability within the short absorption process time. The entrance region of an absorber features a freshly exposed interface at which no surfactant has adsorbed. A numerical model is used to analyze surfactant relaxation rates in a static film of additive-laced solution. Kinetic parameters for the combination of the working pair LiBr-H₂O and the additive 2-ethyl-1-hexanol are derived from data in the literature for static and dynamic surface tension measurements. Bulk, interfacial and boundary parameters influencing relaxation rates are discussed for surfactant adsorption occurring in the absence of absorption, as well as for concurrent adsorption and stable vapor absorption. Initial solution conditions and absorption driving force are shown to impact the potential for instability in the effect they have on the rate of interfacial additive adsorption.     

Economic biogas and cooling water rates in a lithium bromide—water absorption system

An economic analysis of the role of biogas and cooling water in a lithium bromide—water absorption system has been carried out to optimize the generator, condenser and absorber temperatures at a given evaporator temperature and solution pumping rate. The analysis has been repeated for different pumping rates (PR) to determine the optimum PR corresponding to the minimum over-all operating cost of the system. The study has also been carried out for the condition when biogas in the generator and cooling water in the absorber and condenser are supplied at equal flow-rates. It is found that the performance of the LiBr-H₂O system at equal biogas and cooling water flow-rates is about 5.988% higher than when operated at the minimum over-all operating cost, the latter being cheaper by only 2.71%. For low evaporation temperatures, use of a preheater in a LiBr-H₂O system creates a crystallization problem when operated at low pumping rates. The study has therefore been extended for a system without preheater. The parameters under study are illustrated graphically against the generator temperature. Equations to obtain the corresponding optimum condenser and absorber temperature are given. The functional relationship between crystallization limit and absorbent temperature has also been obtained. The optimum operating parameters are presented graphically.     

A dynamic simulation model for transient absorption chiller performance. Part I: The model

This paper is the first of two which presents the development of a dynamic model for single-effect LiBr/water absorption chillers. The model is based on external and internal steady-state enthalpy balances for each main component. Dynamic behaviour is implemented via mass storage terms in the absorber and generator, thermal heat storage terms in all vessels and a delay time in the solution cycle. A special feature is that the thermal capacity is partly connected to external and partly to internal process temperatures.In this paper, the model is presented in detail. For verification, the model has been compared to experimental data. The dynamic agreement between experiment and simulation is very good with dynamic deviations around 10 s. General functionality of the model and a more detailed comparison with experimental data are presented in Part II of this paper.     

Visualization of bubble behavior and bubble diameter correlation for NH3–H2O bubble absorption

The objectives of this paper are to visualize the bubble behavior for an ammonia–water absorption process, and to study the effect of key parameters on ammonia–water bubble absorption performance. The orifice diameter, orifice number, liquid concentration and vapor velocity are considered as the key parameters. The departing bubbles tend to be spherical for surface tension dominant flow, and the bubbles tend to be hemispherical for inertial force dominant flow. A transition vapor Reynolds number is observed at a balance condition of internal absorption potential (by the concentration difference) and external absorption potential (by the vapor inlet mass flow rate). As the liquid concentration increases, the transition Reynolds number and the initial bubble diameter increase. The initial bubble diameter increases with an increase of the orifice diameter while it is not significantly affected by the number of orifices. Residence time of bubbles increases with an increase in the initial bubble diameter and the liquid concentration. This study presents a correlation of initial bubble diameter with ±20% error band. The correlation can be used to calculate the interfacial area in the design of ammonia-water bubble absorber.     

Extended temperature–entropy (T–s) diagrams for aqueous lithium bromide absorption refrigeration cycles

Temperature–entropy (T–s) diagrams have the unique capability of being able to quantify processes in terms of both the first and second laws of thermodynamics. Although use of generalised T–s diagrams has been made to indicate or represent generalised absorption cycles, with the exception for NH₃/water systems, these diagrams have not been specifically tailored to scale to quantify LiBr/water systems. The main barrier for this is that the diagram needs to represent the necessary properties of both the refrigerant (water) and of the solution (LiBr/water). This paper describes the use of the T–s diagram of water extended with additional curves to represent real and ideal LiBr/water absorption cycles. An explanation is provided on several methods available, including details of the thermodynamic justification of the method that was used, to construct the extended diagrams. Finally, the extended T–s diagram is provided with the representation of a real single-effect LiBr/water absorption refrigeration cycle. This should prove to be a valuable tool for design and research engineers to study and optimise LiBr/water chillers.     

Absorption of water vapour into falling films of aqueous lithium bromide

In this study, experiments have been performed for water vapour absorption into 50 and 60 mass% aqueous lithium bromide solution films flowing down a vertical surface to investigate the effects of liquid diffusivity values, molecular properties of the concentrated solutions and non-absorbable gases. The experimental results for wavy films over a film Reynolds number range of 15–90 indicate larger dimensionless mass transfer rates than for strictly laminar flow when the diffusivity of water in a concentrated lithium bromide solution is less than that in a dilute solution. The complete set of results shows that the physical property data for lithium bromide solutions including the diffusivities measured by Kashiwagi are sufficient to explain mass transfer behavior.     

Heat transfer enhancement by Marangoni convection in the NH3–H2O absorption process

The objectives of this paper are to quantify the effect of Marangini convection on the absorption performance for the ammonia–water absorption process, and to visualize Marangoni convection that is induced by adding a heat transfer additive, n-octanol. A real-time single-wavelength holographic interferometer is used for the visualization using a He–Ne gas laser. The interface temperature is always the highest due to the absorption heat release near the interface. It was found that the thermal boundary layer (TBL) increased faster than the diffusion boundary layer (DBL), and the DBL thickness increased by adding the heat transfer additive. At 5 s after absorption started, the DBL thickness for 5 mass% NH₃ without and with the heat transfer additive was 3.0 and 4.5 mm, respectively. Marangoni convection was observed near the interface only in the cases with heat transfer additive. The Marangoni convection was very strong just after the absorption started and it weakened as time elapsed. It was concluded that the absorption performance could be improved by increasing the absorption driving potential (x_vb−x_vi) and by increasing the heat transfer additive concentration. The absorption heat transfer was enhanced as high as 3.0–4.6 times by adding the heat transfer additive that generated Marangoni convection.     

An absorption based miniature heat pump system for electronics cooling

The development of an absorption based miniature heat pump system is motivated by the need for removal of increasing rates of heat from high performance electronic chips such as microprocessors. The goal of the present study is to keep the chip temperature near ambient temperature, while removing 100 W of heat load. Water/LiBr pair is used as the working fluid. A novel dual micro-channel array evaporator is adopted, which reduces both the mass flux through each micro-channel, as well as the channel length, thus reducing the pressure drop. Micro-channel arrays for the desorber and condenser are placed in intimate communication with each other using a hydrophobic membrane. This acts as a common interface between the desorber and the condenser to separate the water vapor from LiBr solution. The escaped water vapor is immediately cooled and condensed at the condenser side. For direct air cooling of condenser and absorber, offset strip fin arrays are used. The performance of the components and the entire system is numerically evaluated and discussed.     

Heat transfer characteristics of the ice slurry at melting process in a tube flow

The heat transfer characteristics were experimentally investigated for ice slurry made from 6.5% ethylene glycol–water solution flow in a 13.84 mm internal diameter, 1500 mm long horizontal copper tube. The ice slurry was heated by hot water circulated at the annulus gap of the test section. Experiments of the melting process were conducted with changing the ice slurry mass flux and the ice fraction from 800 to 3500 kg/m² s and 0–25%, respectively. During the experiment, it was found that the measured heat transfer rates increase with the mass flow rate and ice fraction; however, the effect of ice fraction appears not to be significant at high mass flow rate. At the region of low mass flow rates, a sharp increase in the heat transfer coefficient was observed when the ice fraction was more than 10%.     

A dynamic simulation model for transient absorption chiller performance. Part II: Numerical results and experimental verification

This paper is the second paper out of two which present the development of a dynamic model for single-effect LiBr/water absorption chillers. The first part describes the model in detail with respect to the heat and mass balances as well as the dynamic terms. This second part presents a more detailed investigation of the model performance, including performance analysis, sensitivity checks and a comparison to experimental data. General model functionality is demonstrated.A sensitivity analysis gives results which agree very well to fundamental expectations: it shows that an increase in both external and internal thermal mass results in a slower response to the step change but also in smaller heat flow oscillations during the transient period. Also, the thermal mass has been found to influence the heat flow transients more significantly if allocated internally. The time shift in the solution cycle has been found to influence both the time to reach steady-state and the transients and oscillations of the heat flow. A smaller time shift leads to significantly faster response.A comparison with experimental data shows that the dynamic agreement between experiment and simulation is very good with dynamic temperature deviations between 10 and 25 s. The total time to achieve a new steady-state in hot water temperature after a 10 K input temperature step amounts to approximately 15 min. Compared to this, the present dynamic deviations are in the magnitude of approximately 1–3%.