A numerical study on the combustion limits of mesoscale methane jet flames with hydrogen addition

A meso-scale jet flame model was established for the flame ports of domestic gas stoves. The influences of hydrogen addition ratio (β = 0%–25%) on the combustion limits were explored. The results show that with the increase of hydrogen addition ratio, the blow-off limit increases obviously, while the extinction limit decreases slightly, namely, the combustible range expands significantly. Quantitative analysis was carried out in terms of chemical effect and thermal effect. It was found that hydrogen addition will reduce O₂ fraction in the pre-mixture for a constant equivalence ratio. Under near-extinction limit condition, since the flame is located at the nozzle exit, the external O₂ cannot be entrained into or diffuse into the upstream of the flame, which leads to the decrease of reaction rate. However, for the near-blow-off cases, the external O₂ can be entrained and diffuse into the flame, which compensates the difference of O₂ content in the pre-mixture. Therefore, the combustion reaction is enhanced by hydrogen addition because more H radicals can be produced. In addition, as the flame is located closer to the tube with the increase of hydrogen addition ratio, heat transfer between flame and tube wall is augmented and the preheating of fresh mixture is strengthened by the inner tube wall. This heat recirculation effect becomes especially notable in low velocity cases. In conclusion, the extension of extinction limit by hydrogen addition is attributed to the thermal effect, while the increase of blow-off limit is mainly due to the intensification of chemical effect.     

The effects of hydrogen addition on soot formation in counterflow diffusion n-heptane flames

The effects of H₂ addition on soot formation are investigated in counterflow diffusion n-heptane flames. Three effects including chemical, thermal, and dilution are fully isolated and characterized by additions of H₂, He, and Ar. Soot volume fractions are measured using LE-calibrated LII technique, and flame temperatures are measured using OH-TLAF method along with a thermocouple. Numerical simulations are conducted with a detailed mechanism with soot model. The simulated soot volume fractions and flame temperatures are in good agreement with experimental data. The experimental results show that H₂ addition can greatly reduce the soot formation. It is also found that the chemical and dilution effects suppress soot formation, while the thermal effect with increasing flame temperature promotes soot formation. Kinetic analysis suggests that HACA growth rate could be the dominant factor that controls the final soot formation through the three effects due to H₂ addition.     

Characterization of the effects of hydrogen addition in premixed methane/air flames

The use of hydrogenated fuels shows considerable promise for applications in gas turbines and internal combustion engines. In the present work, the effects of hydrogen addition in methane/air flames are investigated using both a laminar flame propagation facility and a high-pressure turbulent flame facility. The aim of this research is to contribute to the characterization of lean methane/hydrogen/air premixed turbulent flames at high pressures, by studying the flame front geometry, the flame surface density and the instantaneous flame front thermal thickness distributions. The experiments and analyses show that a small amount of hydrogen addition in turbulent premixed methane–air flames introduces changes in both instantaneous and average flame characteristics.     

Effects of swirl on the stability of jet diffusion flames

An experimental study was made, using a double-swirl burner, of the stability of swirling-fuel-jet diffusion flames in swirling air streams. The fuels were hydrogen and methane. The primary variables studied were swirl intensities of the fuel jet and the air stream. It was found that the stability of flame depended on the swirl intensity of both the fuel jet and the air stream. The application of swirl to the fuel jet decreased the rim stability of the flame, but increased the blowout stability of the lifted diffusion flame. For low swirl intensity of the air stream, the effect was similar to that of the fuel jet. At higher swirl intensities of the air stream, above a critical value, the flame stability increased noticeably because of the formation of a recirculation zone near the injector exit. Even in strongly swirling air streams, the favorable effect of fuel swirl on stability of the lifted flame was evident, particularly for the methane flame.     

Different chemical effect of hydrogen addition on soot formation in laminar coflow methane and ethylene diffusion flames

Previous studies showed that adding hydrogen (H₂) can have an opposite chemical effect on soot formation: its chemical effect enhances and suppresses soot formation in methane (CH₄) and ethylene (C₂H₄) diffusion flames, respectively. Such opposite chemical effect of H₂ (CE-H₂) remains unresolved. The different CE-H₂ is studied numerically in the two laminar coflow diffusion flames. A detailed chemical mechanism with the addition of a chemically inert virtual species FH₂ is used to model the gas-phase combustion chemistry in this study. Particularly, a reaction pathway analysis was performed based on the numerical results to gain insights into how H₂ addition to fuel affects the pathways leading to the formation of benzene (A₁) in CH₄ and C₂H₄ flames. The numerical results show that the CE-H₂ in CH₄ diffusion flame to prompt soot formation is ascribed that the higher mole fraction of H atom promotes the formation of A₁ and Acetylene (C₂H₂) and leads to higher nucleation rate and eventually higher soot surface growth rate. In contrast, adding H₂ to C₂H₄ diffusion flames decreases soot nucleation and surface growth rate. The lower soot nucleation rate is due to the lower mole fractions of pyrene (A₄), while the lower soot surface growth rate is due to the lower mole fractions of H atom and C₂H₂, higher mole fraction of H₂ and lower soot nucleation rate. Furthermore, the CE-H₂ in C₂H₄ diffusion flames promotes the formation of A₁, but suppresses the formation of A₄.     

Prediction of the liftoff,blowout and blowoff stability limits of pure hydrogen and hydrogen/hydrocarbon mixture jet flames

The paper presents experimental studies of the liftoff and blowout stability parameters of pure hydrogen, hydrogen/propane and hydrogen/methane jet flames using a 2 mm burner. Carbon dioxide and Argon gas were also used in the study for the comparison with hydrocarbon fuel. Comparisons of the stability of H₂/C₃H₈, H₂/CH₄ and H₂/CO₂ flames showed that H₂/C₃H₈ produced the highest liftoff height and H₂/CH₄ required highest liftoff, blowoff and blowout velocities. The non-dimensional analysis of liftoff height was used to correlate liftoff data of H₂, H₂/C₃H₈, H₂/CO₂, C₃H₈ and H₂/Ar jet flames tested in the 2 mm burner. The suitability of extending the empirical correlations based on hydrocarbon flames to both hydrogen and hydrogen/hydrocarbon flames was examined.     

Kinetic incentive of hydrogen addition on nonpremixed laminar methane/air flames

In order to find out the respective influences of chemical reactivity and physical transport of hydrogen additive on nonpremixed flame, two fabricated hydrogen additions were introduced into nonpremixed methane/air flame modeling. Hydrogen addition was assumed as inert gas or partial reactivity fuel to respectively explore the kinetic reasons by the three aspects: the elementary reaction route, heat release, and physical diffusion of hydrogen addition. The analyses were implemented in terms of OH and H production. Results showed that, hydrogen addition can enhance OH and H production via elementary reactions, and causes flame reaction zone migration through the coupling interaction between the low-temperature heat enthalpy release and diffusion behavior of hydrogen addition. R84 (OH + H₂=H + H₂O) and R38 (H + O₂=O + OH) are the most important elementary reactions related to OH and H production. The physical incentive of hydrogen addition can hardly work without the chemical effects of hydrogen addition.     

The effects of hydrogen addition on NO formation in atmospheric-pressure, fuel-rich-premixed, burner-stabilized methane, ethane and propane flames

The effects of hydrogen addition on NO formation in fuel-rich, burner-stabilized methane, ethane and propane flames are reported. Profiles of temperature and NO mole fraction were obtained using spontaneous Raman scattering and laser-induced fluorescence (LIF), respectively. Experiments were performed at equivalent ratio of 1.3, with 0 and 0.2 mole fraction of hydrogen in the fuel; and the mass flux through the burner was varied for each mixture. The addition of hydrogen only modestly affects the flame temperature and NO mole fraction. For the vast majority of the flames studied, the temperature and NO decrease by less than 40 K and 20% (relative), respectively, upon hydrogen addition. The decrease in NO fraction is more distinct in methane and propane flames, and more modest for ethane. The comparison of the experimental data obtained for a given fuel in near-adiabatic C_nH_2n+2/H₂/O₂/N₂ and burner-stabilized C_nH_2n+2/Air flames shows that the NO mole fraction at a given mass flux is practically independent of the composition of the oxidizer. Comparison of the experimental profiles with the predictions of one-dimensional flame calculations with detailed chemical mechanisms indicates that the decrease in the Fenimore NO formation with hydrogen addition arises from the concomitant decrease in CH fraction. Analysis of the computational results suggests that the reaction NCN + H → CH + N₂ returns a considerable fraction of NCN back to N₂.     

The blowout mechanism of turbulent jet diffusion flames

The complicated flame stabilization mechanisms and flame/flow interactions in the blowout of turbulent nonpremixed jet flames are experimentally studied using phenomenological observation, 2D Rayleigh scattering, 2D laser-induced predissociative fluorescence (LIPF) images of OH, and particle image velocimetry (PIV) techniques. The blowout process may be categorized into four characteristic regions: pulsating, onset of receding, receding, and extinction. Based on experimental findings, a blowout mechanism is proposed. The maximum “waistline” point of the stoichiometric contour, defined as the point where the radial distance between the elliptic stoichiometric contour and the jet axis reaches a maximum value, can be regarded as the dividing point separating the unstable and stable regions for the lifted flame in the blowout process. If the flame base is pushed beyond the maximum “waistline” point, the flame will step into the pulsating region and become unstable, triggering the blowout process. The triple flame structure is identified and found to play an important role in flame stabilization within the stable liftoff and pulsating regions. In the pulsating region, the stabilization point of the triple flame moves along the stoichiometric contour, stabilizing the flame where the flame base is bounded by the contours of lean and rich limits. If the flame is pushed beyond the tip of the stoichiometric contour, the stabilization point and triple flame structure vanish and the flame becomes lean. The flame then recedes downstream continuously and finally extinguishes.     

Hydrodynamic and diffusion effects on the stability of spherically expanding flames

We examine the stability of an outwardly propagating spherical flame accounting for both hydrodynamic and thermodiffusive effects. For Lewis numbers less than a critical value Le¹ < 1, disturbances of the flame front grow during the initial phase of propagation, i.e., when the radius is comparable to the flame thickness. However, for Le > Le¹, the flame, which is stable to thermodiffusive effects, becomes unstable only after a critical size is reached. This instability is hydrodynamic in nature and is caused by the thermal expansion of the gas. In this study we provide an expression for the determination of the critical size, or a critical Peclet number, which depends on the thermal expansion coefficient and on the Lewis number. The explicit dependence on all the relevant physicochemical parameters enables us to compare our results with experimental data.     

The effects of hydrogen addition on silica aggregate growth in atmospheric-pressure, 1-D methane/air flames with hexamethyldisiloxane admixture

The effect of hydrogen addition on silica growth in burner-stabilized methane/air flames with trace amounts of hexamethyldisiloxane are reported. Profiles of the aggregates' radius of gyration $R_g$ and monomer radius $a$ versus residence time were measured by laser light scattering. Experiments were performed at equivalence ratios of 0.8, 1.0 and 1.3, with mole fractions of 0–0.4 of hydrogen in the fuel. At equal mass flux, the addition of hydrogen was found to result in decreasing $R_g$ and $a$. However, keeping the flame temperature rather than the mass flux constant upon hydrogen addition resulted in the same measured profiles.     

Experimental analysis of the effects of hydrogen addition on methane combustion

This paper presents gas emissions from turbulent chemical flow inside a model combustor, for different blending ratios of hydrogen–methane composite fuels. Gas emissions such as CO and O₂ from the combustion reaction were obtained using a gas analyzer. NOx emissions were measured with a NOx analyzer. The previously obtained flame temperature distributions were also presented. As the amount of hydrogen in the mixture increases, more hydrogen is involved in the combustion reaction, and more heat is released, and the higher temperature levels are resulted. The results have shown that the combustion efficiency increases and CO emission decreases when the hydrogen content is increased in blending fuel. It is also shown that the hydrogen–methane blending fuels are efficiently used without any important modification in the natural gas burner. Copyright © 2011 John Wiley & Sons, Ltd.     

Numerical study on the extinction dynamics of partially premixed meso-scale methane-air jet flames with hydrogen addition

In this paper, a model of partially premixed jet flames that sustained above a meso-scale short tube was established for an individual flame port of domestic gas stoves. The effects of hydrogen addition (volume ratio β = 0%, 10%, 20%, 30%) on the extinction dynamics of CH₄-air jet flames were numerically investigated. It is found that flame oscillation occurs once (β = 10% and 20%) or twice (β = 30%) in the extinction process. Moreover, the larger of β, the longer the extinction process can sustain. Analysis was performed in terms of both chemical effect and thermal effect. As to the chemical effect, in the first place, the reaction rate decreases as the inlet velocity is reduced. As a result, the consumption rate of O₂ will be less than the supply rate from the incoming mixture, which makes the O₂ concentration in the flame center increase. On the other hand, the amount of H radicals increases with the increase of β, and when the O₂ content at the flame center reaches a “critical point”, the key elementary reaction “H + O₂ ? O + OH” will be enhanced and consequently the total reaction rate will also be intensified. After that, the consumption rate of O₂ will be larger than the supply rate due to the reduced flow rate of incoming mixture. The total heat release rate will decrease sharply and extinction occurs. As regards the thermal effect, it is revealed that heat recirculation effect (indirect preheating effect) lags behind the variation of the reaction zone (i.e., flame), thus, it has a negligible impact on flame oscillation. In contrast, the preheating temperature in the vicinity of flame front (named as “direct preheating effect”) exhibits a similar variation tendency with the total heat release rate of the flame. And the larger of β, the more remarkable of the direct preheating effect can be. In summary, due to the chemical effect and thermal effect caused by hydrogen addition, the flame can survive for a longer time with fluctuation during the extinction process.     

Kinetic analysis of the chemical effects of hydrogen addition on dimethyl ether flames

The chemical effects of hydrogen addition on premixed laminar low-pressure dimethyl ether flames were studied by kinetic analysis. The chemical effects of hydrogen addition on flame structures and mole fractions of major species, intermediate species and free radicals have been distinguished clearly from the dilution and thermal effects. The results show that the chemical effects of hydrogen addition cause the DME profile to move toward the upstream side and can suppress the production of acetylene and ethylene. The production of formaldehyde is promoted by the chemical effects of hydrogen addition but the dilution and thermal effects are more dominant which decrease the mole fraction of formaldehyde so that the overall effects make formaldehyde mole fraction decrease. The dominant effects of hydrogen addition on H, OH and O radicals are the chemical effects that make mole fractions of these radicals increase.     

Kinetic and fluid dynamics modeling of methane/hydrogen jet flames in diluted coflow

MILD combustion is a recent development in the combustion of hydrocarbon fuels which promises high efficiencies and low NO_x emissions. In this paper we analyze the mathematical and numerical modeling of a Jet in Hot Coflow (JHC) burner, which is designed to emulate a moderate and intense low oxygen dilution (MILD) combustion regime [1]. This paper initially discusses the effects of several modeling strategies on the prediction of the JHC flame structure using the CFD code FLUENT 6.3.26. Effects of various turbulence models and their boundary conditions have been studied. Moreover, the detailed kinetic mechanism adopted in the CFD simulations is successfully validated in the conditions of interest using recent literature data [2] on the effect of nitrogen dilution on the flame speeds of several CH₄/H₂/air lean mixtures. One of the aims of this paper is also to describe a methodology for computing pollutant formation in steady turbulent flows to verify its applicability to the MILD combustion regime. CFD results are post-processed for calculating the NO_x using a numerical tool called Kinetic Post Processor (KPP). The modeling results agree with the experimental results [1] and support the proposed approach as a useful tool for optimizing the design of new burners also in the MILD combustion regime.     

Investigating the effect of local addition of hydrogen to acoustically excited ethylene and methane flames

While lean combustion in gas turbines is known to reduce NOx, it makes combustors more prone to thermo-acoustic instabilities, which can lead to deterioration in engine performance. The work presented in this study investigates the effectiveness of secondary injection of hydrogen to imperfectly premixed methane and ethylene flames in reducing heat release oscillations. Both acoustically forced and unforced flames were studied, and simultaneous OH and H atom PLIF (planar laser induced fluorescence) was conducted. The tests were carried out on a laboratory scale bluff-body combustor with a central V-shaped bluff body. Two-microphone method was used to estimate velocity perturbations from pressure measurements, flame boundary images were captured using high speed Mie scattering, while global heat release fluctuations were determined from OH* chemiluminescence.The results showed that hydrogen addition considerably reduced heat release oscillations for both methane and ethylene flames at all the forcing frequencies tested, with the exception of methane flames forced at 315 Hz, where oscillations increased with hydrogen addition. The addition of hydrogen reduced the extent of flame roll-up for both methane and ethylene flames, however, this reduction was larger for methane flames. NOx exhaust emissions were observed to increase with hydrogen addition for both methane and ethylene flames, with absolute NOx concentrations higher for ethylene flames, due to higher flame temperatures.     

Buoyancy effects on hydrogen diffusion flames confined in a small tube

In this work, buoyancy effects on hydrogen jet flames confined in a small tube without air co-flow were numerically investigated. The results show that the extinction limit of fuel velocity under buoyant condition is much lower than that without buoyancy. Moreover, hydrogen flames under buoyant condition attatch the nozzle exit for all fuel velocities investigated; however, the flames without buoyancy surround the lower wall at low fuel velocity. In addition, combustion is nearly complete in the presence of buoyancy, whereas the combustion efficiency under non-buoyant condition is below 45%. Furthermore, flame temperature under buoyant condition is much higher compared to the counterpart under non-buoyant condition at low and moderate fuel velocities. Analysis reveals that in the case without buoyancy, the negative gauge pressure in the annular space is unable to entrain sufficient air from the ambient. Hence, hydrogen has to diffuse downwards to sustain the flame and complete combustion is unrealizable.     

Effects of hydrogen addition on the propagation of spherical methane/air flames: A computational study

A computational study is performed to investigate the effects of hydrogen addition on the fundamental characteristics of propagating spherical methane/air flames at different conditions. The emphasis is placed on the laminar flame speed and Markstein length of methane/hydrogen dual fuel. It is found that the laminar flame speed increases monotonically with hydrogen addition, while the Markstein length changes non-monotonically with hydrogen blending: it first decreases and then increases. Consequently, blending of hydrogen to methane/air and blending methane to hydrogen/air both destabilize the flame. Furthermore, the computed results are compared with measured data available in the literature. Comparison of the computed and measured laminar flame speeds shows good agreement. However, the measured Markstein length is shown to strongly depend on the flame radii range utilized for data processing and have very large uncertainty. It is found that the experimental results cannot correctly show the trend of Markstein length changing with the hydrogen blending level and pressure and hence are not reliable. Therefore, the computed Markstein length, which is accurate, should be used in combustion modeling to include the flame stretch effect on flame speed.     

Measurements of soot production and thermal radiation from confined turbulent jet diffusion flames of methane

Turbulent methane/air jet diffusion flames at atmospheric and elevated pressure have been studied experimentally to provide data for coupled thermal radiation and soot production model development and validation. Although methane is only lightly sooting at atmospheric pressure, at elevated pressure the soot yield increases greatly. This allows the creation of a highly radiating flame, of moderate optical depth, within a laboratory scale rig. Spatially resolved flame properties needed for model validation have been measured at 1 and 3 atm. These measurements include detailed maps of mean mixture fraction, mean temperature, mean soot volume fraction, and mean and instantaneous spectrally resolved, path integrated radiation intensity.     

A numerical study on the effect of hydrogen/reformate gas addition on flame temperature and NO formation in strained methane/air diffusion flames

This paper investigates the effects of hydrogen/reformate gas addition on flame temperature and NO formation in strained methane/air diffusion flames by numerical simulation. The results reveal that flame temperature changes due to the combined effects of adiabatic temperature, fuel Lewis number and radiation heat loss, when hydrogen/reformate gas is added to the fuel of a methane/air diffusion flame. The effect of Lewis number causes the flame temperature to increase much faster than the corresponding adiabatic equilibrium temperature when hydrogen is added, and results in a qualitatively different variation from the adiabatic equilibrium temperature as reformate gas is added. At some conditions, the addition of hydrogen results in a super-adiabatic flame temperature. The addition of hydrogen/reformate gas causes NO formation to change because of the variations in flame temperature, structure and NO formation mechanism, and the effect becomes more significant with increasing strain rate. The addition of a small amount of hydrogen or reformate gas has little effect on NO formation at low strain rates, and results in an increase in NO formation at moderate or high strain rates. However, the addition of a large amount of hydrogen increases NO formation at all strain rates, except near pure hydrogen condition. Conversely, the addition of a large amount of reformate gas results in a reduction in NO formation.