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《Fuel Processing Technology》2004,86(1):13-21
An efficient method for the separation of prime value products from crude xylenol fraction of noncaking coal-derived tar acids involving suitable distillation technique is described. The feed as well as the products was analysed by gas chromatography (G.C.). The crude xylenol comprising a number of close-boiling phenolic compounds was fractionated under reduced pressure to yield three cuts, viz. cresols (30.7%), xylenols (31.2%) and dihydric phenols (23.3%). The dihydric phenols fraction termed as high boiling tar acids (HBTA) was found to contain significant amounts of catechol (6.4%), methyl catechols (32.3%), resorcinol (12.7%) and methyl resorcinols (8.6%). Catechol together with its homologues and resorcinol with its homologues were isolated from the HBTA. These products, not available from the HBTA of metallurgical coke plants, have been shown to offer distinct marketing advantages. A conceptual scheme for the treatment of crude xylenol as well as application pattern of various products obtainable from the crude mixture is presented. 相似文献
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E. O. Barnes R. H. Potts F. B. White 《Journal of the American Oil Chemists' Society》1959,36(4):158-163
Summary The source of crude tall oil and methods to produce the oil have been described. These include acidulation of sulfate pulp,
black liquor skimmings, and gravity settling as well as centrifugal means of separation to reduce the lignin content of the
product.
Subsequent processing of the crude tall oil into fractionated fatty acids and rosin has been outlined with suggestions for
consideration in all stages of the distillation section of the plant. 相似文献
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酚产品收率低的主要原因是:焦油加工车间酚油和素油的酚集中度低、馏分碱洗脱酚和废水萃取脱酚过程中乳化物多;酚盐分解时一些挥发酚进入大气;粗酚精制后酚渣中遗留的二甲酚和高级酚大多。要提高焦化企业的酚收率,除改进工艺制度及认真操作外,还要严格控制入萃取塔的废水质量及焦炉循环氨水质量。同时,应尽量完善设施,诸如设立酚盐分解酸汽吸收塔、酚渣蒸馏等装置。 相似文献
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焦化剩余氨水经预处理去除大量酚类、煤焦油等,预处理后剩余氨水仍含有少量的油类物质,在蒸氨时不断积累,如不分离这部分油类,则影响蒸氨运行,且造成苯系物损失。本文主要介绍了焦化剩余氨水预处理脱酚后溶剂油的回收工艺。实验表明,此工艺简单有效。 相似文献
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Methyl esters of a Canadian Atlantic herring oil containing 62% monoethylenic fatty acids were subjected to batch fractional
distillation under vacuum on a pilot plant scale, to study the feasibility of fractionating fatty acid esters of marine oils
of low iodine value into monounsaturated fractions with increased commercial value for industrial chemical uses. A total of
64 methyl ester fractions were collected and analyzed by gas liquid chromatography. Recoveries of the major saturated and
monounsaturated acids were close to 100%, and some fractions contained over 90% of the desired 22:1 long chain monounsaturated
acids. The short chain polyunsaturated acids were recovered in good yields, but the long chain highly unsaturated acids were
recovered in yields of 60% or less due to oxidative and thermal decomposition in the particular apparatus employed. If small
amounts of unsaturated acids are acceptable, fractional distillation of low iodine value marine oils could inexpensively supply
fractions with high concentrations of methyl esters of longer chain (C20 and C22) monounsaturated and shorter chain (C14) saturated acid or (C16) saturated-monounsaturated acid mixture. 相似文献
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C. S. B. Nair D. K. Sen A. N. Basu 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1967,17(4):113-117
Aqueous acetamide has been found to be a good solvent for the extraction of tar acids from low temperature carbonisation tar oils. Saturated acetamide solution at 15–30° in the molar ratio acetamide/tar acids of 3 : 1 effects a recovery of about 90% of tar acids originally present in the oil in two extraction stages. The tar acids are obtained in 77% purity, the impurities consisting of neutral oils and tar bases. Re-extraction with light petroleum can raise the purity of tar acids to 94%. Tar acids can be separated from the purified acetamide extract by suitable dilution with water. The system tar acids—(bases + neutral oils)—saturated aqueous acetamide has been studied. It has been shown that three theoretical counter-current extraction stages are required to effect a recovery of 95% of tar acids from a feed oil containing 45% tar acids. 98% recovery of the tar acids could be achieved in four stages. 相似文献
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R. L. Logan 《Journal of the American Oil Chemists' Society》1979,56(11):777A-779A
About 1949, with the advent of effective fractional distillation, the tall oil industry came of age, and tall oil fatty acids
(TOFA), generally any product containing 90% or more fatty acids and 10% or less of rosin, have grown in annual volume ever
since, until they amount to 398.8 million pounds annual production in the U.S. in 1978. Crude tall oil is a byproduct of the
Kraft process for producing wood pulp from pine wood. Crude tall oil is about 50% fatty acids and 40% rosin acids, the remainder
unsaps and residues; actually, a national average recovery of about 1–2% of tall oil is obtained from wood. On a pulp basis,
each ton of pulp affords 140–220 pounds black liquor soaps, which yields 70–110 pounds crude tall oil, yielding 30–50 pounds
of TOFA. Separative and upgrading technology involves: (a) recovery of the tall oil; (b) acid refining; (c) fractionation
of tall oil; and occasionally (d) conversion to derivatives. TOFA of good quality and color of Gardner 2 corresponds to above
97% fatty acids with the composition of 1.6% palmitic & stearic acid, 49.3% oleic acid, 45.1% linoleic acid, 1.1% miscellaneous
acids, 1.2% rosin acids, and 1.7% unsaponifiables. 相似文献
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介绍了国内首套引进的30万t/a煤焦油蒸馏装置的工艺情况及主要中间馏分质量情况,指出了该装置在产品质量、能量平衡和环境保护等方面的优势,提出了我国煤焦油加工应该改进的方面。 相似文献
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Harold C. Templeton 《Journal of the American Oil Chemists' Society》1970,47(4):A138-A140
Plant corrosion tests of various metals and alloys in tall oil distillation streams present the effect of alloy composition
on corrosion rate. Stream temperature, alloy composition and stream composition are correlated so as to provide a useful guide
to material selection for tall oil distillation plants. Alloys exposed to corrosion test were iron or nickel base with chromium
plus varying amounts of molybdenum. Molybdenum is the most important alloy addition in reducing the rate of corrosion attack,
with corrosion attack at a very low rate, <.1 mil per year, at the 6% molybdenum level in the most aggressive stream tested,
i.e., 85% fatty acids at 518F. The presence of chromium does not appear to be essential to obtaining good corrosion resistance
to the more corrosive conditions. Corrosion rates increase with increasing temperature. The streams classed as high in fatty
acids are much more corrosive than those which are classed as high in rosin acids. Vapor phase streams are more corrosive
than liquid phase streams. Corrosion attack is normally from pitting. Most of the more corrosive conditions can be handled
with an alloy containing 3% to 4% molybdenum (AISI Type 317), but some process conditions require higher molybdenum contents
in order to obtain acceptable corrosion rates. Less corrosive streams can be handled with an alloy containing less than 3%
molybdenum (AISI Type 316). 相似文献
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介绍了洗油加工系统和焦油萘蒸馏系统的结渣情况,根据生产实际情况,通过对实际数据的研究分析,提出了结渣问题的解决方法,就是将萘油改送到焦油萘蒸馏装置,与焦油混合后一起蒸馏,使渣残留在重质馏分中,从而避免了渣对洗油加工系统和焦油萘蒸馏系统产生的不利影响。同时,对改变萘油处理途径的优劣进行了分析,为解决该系统的结渣问题提供了参考。 相似文献
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Decomposition of the tar residue from oil distillation was carried out under hydrothermal conditions using a batch reactor at 623–673 K and 25–40 MPa, with and without K2CO3 as a catalyst. The reaction scheme for tar decomposition was determined as follows: the liquefaction and dissolution process of tar occur first and then intermediate chemical compounds are transformed into lighter molecular weight species. The presence of K2CO3 activates the dissociation of molecular hydrogen to facilitate hydrogenation reactions. The main products from the decomposition of tar were phenol, biphenyl, diphenylether (DPE), and diphenylmethane (DPM). These results indicate that hydrolysis was important in the cleavage of the macromolecular structure of tar under both catalytic and non‐catalytic hydrothermal conditions. This method can be developed for efficient tar liquefaction to generate high yields of valuable chemicals in an environmentally friendly way. 相似文献
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以研究低温煤焦油中特定芳烃组分的选择性分离为目标, 通过预处理分离酚类化合物和富集特定芳烃组分, 采用多元溶剂萃取方法选择性分离芳烃和非芳烃组分, 采用Hansen溶度参数理论进行多元溶剂的设计和萃取条件的优化。结果表明, 溶剂对原料焦油的选择性随Hansen溶度参数“距离”(Ra)增加而增大, 萃取能力则相反。研究得到的多元萃取剂是含水量为体积分数6%的N,N-二甲基甲酰胺溶液, 优化萃取条件是温度25℃、剂/油比6:1。萃余物经多次萃取进一步分离芳烃组分, 萃出物经甲酰胺多次萃取以分离出杂环化合物和极性组分。芳烃组分在最终分离产物中的质量分数为94%, 其总萃取收率为95%。另外非芳烃化合物、杂环化合物和其他极性组分也在本过程中得到了有效富集。 相似文献
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