Antireflective transparent covers for solar devices

Promising solutions for low-cost antireflective (AR) covers for solar receivers are based on the principle of mixing bulk material with air on a subwavelength scale in order to obtain very low effective refractive indices. Possibilities to achieve this are given by porous media and by periodic or stochastic subwavelength surface-relief structures. In this work, the mentioned approaches were investigated experimentally. Subwavelength surface-relief structures were embossed in organically modified sol–gel materials or in acrylic materials, and porous sol–gel coatings were produced by dip-coating. It is shown that the solar transmittance of a transparent cover can be improved by up to 6% with a porous sol–gel coating at normal incidence. This improvement of the solar transmittance increases with larger angles of incidence.     

Preparation of a TiMEMO nanocomposite by the sol–gel method and its application in coloured thickness insensitive spectrally selective (TISS) coatings

An organic–inorganic nanocomposite was prepared via sol–gel processing from 3-(trimethoxysilyl)propyl methacrylate (MAPTMS) and titanium(IV) isopropoxide (TIP) precursors (TiMEMO) in the form of a viscous resin, and used as a binder for the preparation of coloured thickness insensitive spectrally selective (TISS) paints and corresponding solar absorber coatings. The spectral selectivity of TiMEMO-based TISS paints was optimized by varying the concentrations of binder and different pigments: black, coloured (red, green and blue) and aluminium flakes, the latter imparting low thermal emittance, which was correlated to the presence of titanium in the TiMEMO sol–gel host. The formation and the ensuing structure of the sol–gel TiMEMO hybrid was studied in detail and the nanocomposite structure of the TiMEMO binder formed was assessed from infrared and ²⁹Si NMR measurements, which confirmed the formation of Ti–O–Si linkages established after the hydrolysed precursors condensed into a compliant resinous material. XRD measurements provided additional information about the existence of small coherent domains of silsesquioxane units in the sol–gel host. The abrasion resistance of the non-pigmented TiMEMO binder deposited in thin film form on a PMMA substrate was assessed by the Taber test, and its hardness compared with other resin binders which have been used for making TISS paint coatings. The surface properties of the non-pigmented TiMEMO binder and the ensuing TISS paint coatings were determined from contact angle measurements. The results showed that the water contact angles of non-pigmented TiMEMO binder increased from 70° to 125–135° for the corresponding pigmented TISS paint coatings, inferring the influence of surface roughness on surface energy in the presence of pigments. SEM measurements revealed a striking similarity in the surface morphology of the TISS paint coatings with some other surfaces exhibiting the Lotus effect.     

Optical, thermal and structural characteristics of carbon nanoparticles embedded in ZnO and NiO as selective solar absorbers

Selective solar absorber coatings of carbon embedded in ZnO and NiO matrices on aluminium substrates have been fabricated by a sol–gel technique. Spectrophotometry was used to determine the solar absorptance and the thermal emittance of the composite coatings. The surface morphology of the samples was studied by scanning electron microscopy (SEM). Cross-sectional high-resolution transmission electron microscopy (X-HRTEM) was used to study the fine structure of the samples. Chemical composition analysis was done by energy dispersive spectroscopy (EDS) and electron energy loss spectroscopy (EELS). The crystal structure of ZnO and NiO samples was also investigated with an X-ray diffraction (XRD) technique. Samples were subjected to an accelerated ageing test for 95 h, with condensation at relative humidity of 95% and at a climate chamber temperature of 45 °C. The thermal emittances of the samples were 6% for the ZnO and 4% for the NiO matrix materials. The solar absorptances were 71% and 84% for ZnO and NiO samples, respectively. The SEM revealed a smooth featureless surface for both C–ZnO and C–NiO samples. Some C–NiO samples showed dentritic features. X-HRTEM, EDS and EELS studies revealed a nanometric grain size for both types of samples. The C–ZnO and C–NiO coatings contained amorphous carbon embedded in nanocrystalline ZnO and NiO matrices, respectively. Selected area electron diffraction (SAED) showed that a small amount of Ni grains of 30 nm diameter also existed in the NiO matrix. The accelerated ageing tests produced performance criterion (PC) values of 0.15 and 0.054 at 95 h for the C–ZnO and C–NiO samples, respectively. Based on these results, C–NiO samples proved to have better solar selectivity behaviour than the C–ZnO counterparts.     

Sol–gel derived CuCoMnOx spinel coatings for solar absorbers: Structural and optical properties

A novel black coloured coating with the composition CuCoMnO_x was prepared using sol–gel synthesis. The coatings were deposited using the dip-coating technique from alcoholic sols based on Mn-acetate and Co- and Cu-chloride precursors. Thermogravimetric analysis showed that xerogels become crystalline at 316°C while X-ray diffraction analysis revealed that the coatings and powders correspond predominantly to CuCoMnO_x spinels. Rutherford back scattering (RBS) and transmission electron microscopic (TEM) studies combined with energy dispersive X-ray spectroscopy (EDXS) measurements confirmed that Cu, Mn and Co are present in the films in stoichiometric ratios close to that in the initial sols. IR spectroscopy has been employed to study the formation of sols by following the changes in the vibrational bands of the acetate groups during both thermal hydrolysis and the ageing of sols to xerogels. It was found that ageing of xerogels was accompanied by the formation of −COO⁻ bridging units, which at 250°C are no longer visible in the IR spectra but substituted by the vibrational modes characteristic for CuCoMnO_x. The solar absorptance (a_s) and thermal emittance (e_T) of the coatings when deposited on an Al-substrate are a_s=0.9 and e_T=0.05, which rank deposited black sol–gel CuCoMnO_x spinels among the promising candidates for spectrally selective absorber coatings for solar collectors and solar facades.     

Sol–gel niobium pentoxide: A promising material for electrochromic coatings, batteries, nanocrystalline solar cells and catalysis

In the last decade the sol–gel process became a promising method to synthesize materials in form of coatings, nanoscale powders and porous systems. The technique has been mainly used at laboratory scale and has brought interesting contributions for the development of new nanomaterials. Nevertheless, several products or devices made with such a process already exist and new ones should be available in the market in the near future. This paper briefly reviews the state of the art in the development of electrochromic (EC) coatings and devices, batteries, nanocrystalline solar cells and in the field of catalysis achieved during the last decade using sol–gel derived pure and doped niobium pentoxide.     

The preparation and testing of spectrally selective paints on different substrates for solar absorbers

In this paper the preparation and testing of spectrally selective paint coatings for absorbers in flat-plate solar collectors are shown. This represents the most inexpensive way of preparing such an absorber. Basic properties of coatings prepared on aluminum, copper and stainless steel substrates are described together with the stability of the painted substrate. To calculate the performance of the solar collector with a painted absorber, a dynamic multi-node model was applied. It considers the main components and heat transfer fluxes of a flat-plate solar collector.     

Tri-layer antireflection coatings (SiO2/SiO2–TiO2/TiO2) for silicon solar cells using a sol–gel technique

Antireflection coatings (ARCs) have become one of the key issues for mass production of Si solar cells. They are generally performed by vacuum processes such as thermal evaporation, reactive sputtering, and plasma-enhanced chemical vapor deposition. In this work, a sol–gel method has been demonstrated to prepare the ARCs for the non-textured monocrystalline Si solar cells. The spin-coated TiO₂ single-layer, SiO₂/TiO₂ double-layer and SiO₂/SiO₂–TiO₂/TiO₂ triple-layer ARCs were deposited on the Si solar cells and they showed good uniformity in thickness. The measured average optical reflectance (400–1000 nm) was about 9.3, 6.2 and 3.2% for the single-layer, double-layer and triple-layer ARCs, respectively. Good correlation between theoretical and experimental data was obtained. Under a triple-layer ARC condition, a 39% improvement in the efficiency of the monocrystalline Si solar cell was achieved. These indicate that the sol–gel ARC process has high potential for low-cost solar cell fabrication.     

An assessment of solar energy availability in different regions of the solar spectrum

The use of spectrally sensitive devices such as solar cells for electricity generation and selective absorber coatings for solar heaters, require a knowledge of the spectral composition of solar energy arriving at the point of utilization. Work is in progress at the University of Bradford to measure the amounts of available energy in different regions of the solar spectrum.The solar spectral measurement system uses a circularly variable interference filter covering the wavelength range 0.3–1.06 μm.     

Nanostructured materials for solar energy conversion

This review article deals with the motivation for using nanostructured materials in the field of solar energy conversion. We discuss briefly some recent fundamental observations on supported nanoclusters and optical properties of embedded metallic nanoclusters in a dielectric matrix. An overview on current research and existing applications in this field is given. Nanocomposite thin films developed for the application as optically selective absorber coatings in thermal solar collectors are described in some more detail. These coatings are based on transition metal containing amorphous hydrogenated carbon films (a-C:H/TM) or on transition metal containing silicon–carbon films (a-Si:C:H/TM) produced by a combined PVD/PECVD process.     

Sol–gel deposition and optical characterization of multilayered SiO2/Ti1−xSixO2 coatings on solar collector glasses

Thin films of silicon oxide and silicon titanium mixed oxides are deposited on solar collector glazing in a sol–gel dip-coating process based on alcoxide precursors. Spectrophotometry is used to characterize the relation of film thickness and withdrawal speed for the precursor solutions, and to determine the refractive index of individual layers of the mixed oxides. The inferred dispersion relations n(λ) are compared to the predictions of effective medium theories. Based on the knowledge of the optical properties of individual layers, multilayer interference stacks are designed. Multilayered samples of superior quality are deposited by sol–gel dip-coating in a particle-free environment. The final optical performance of the multilayer stacks are characterized in terms of the visible reflectance R_VIS, CIE color coordinates, and the solar transmission T_sol. Values of up to 2.4 have been attained for the energy efficiency of the colored reflection M=R_VIS/(100%-T_sol). The produced coatings combine a bright colored reflection with an acceptable solar transmittance, and are thus well suited for the application in colored glazed thermal solar collectors. This novel type of colored glazing opens up new perspectives for the architectural integration of thermal solar collectors, e.g. as solar active glass facades.     

A comparison of thermal performance of austenitic stainless steel solar absorber plates coloured by chemical and thermal oxidation techniques

A comparison of thermal performance of the chemically and thermally oxidized $\text{18}\text{8}$ CrNi austenitic stainless steel (SS) solar absorber plates (light blue in colour) under bright sunshine conditions in Benin City, Nigeria, shows that the thermally oxidized austenitic stainless steel AISI 321 performs better than the chemically oxidized (SS) absorbing surface. The highest temperature recorded on a clear bright day, for a singly glazed, thermally oxidized (SS) absorber plate was 108 °C as against 102 °C for the chemically oxidized (SS) absorber plate under the identical conditions of plate masses and dimensions.     

Development and investigation of sol–gel solutions for the formation of TiO2 coatings

We show a technological approach for the sol–gel processing of stabilized xerogel colloidal titanium oxide films. Glycerol was used as a drying control additive agent. Glycerol helped in stabilizing the solution. The thermal transformation of a xerogel film was studied by differential thermal analysis (DTA) and powder X-ray diffraction. The optical index of the annealed coatings was evaluated using UV–VIS–NIR spectrophotometry. The results showed that a nanocrystalline titania anatase film of high optical quality (n=2.34 at 600 nm) can be obtained by the sol–gel process.     

Nanoporous oxide coatings on stainless steel to enable water splitting and reduce the hydrogen evolution overpotential

Nanoporous oxides (SiO₂, TiO₂, ZrO₂, and AlOOH) synthesized from sol–gel chemistry techniques were used as coatings for stainless steel electrodes in water electrolysis systems. These oxide coatings have been shown to provide corrosion protection of the stainless steel electrodes at potentials positive enough to evolve oxygen on the positive electrode. In addition, all four oxide coated electrodes showed a 100–200 mV lower overpotential for hydrogen evolution than an uncoated stainless steel electrode. This was attributed to the ability of the oxide coatings to adsorb hydrogen on the surface of the electrode. To verify gas production from these electrodes, a custom alkaline electrolyzer was built and tested with a constant applied current. The flow rate of gas was measured for five different electrode connection configurations, utilizing both monopolar and bipolar electrodes. The efficiency of the system was calculated to be between 66 and 75% as defined as the ratio of the higher heating value of hydrogen to the energy applied to the system. The oxide coated stainless steel electrodes were used without any additional catalysts, including the precious metals.     

Industrially sputtered solar absorber surface

We report on solar absorber surfaces prepared in a sputtering unit designed for industrial production using roll coating technique and high sputtering rates. The reproducibility and stability of the sputtering process is very good. Solar absorbtance of 0.96 and thermal emittance of 0.10 are obtained. The sputtered absorber is as cost effective as other commercial coatings available for flat plate collectors.     

Solar absorptance of black cobalt and black cobalt–silver films and its relation with roughness coefficient

Cobalt oxide and cobalt oxide–silver selective surfaces were prepared in a galvanostatic mode by means an electrodeposition bath, using different deposition times, on stainless steel substrates. Later, the roughness factor of the selective surfaces, were determined in order to establish one relation with the electrodeposition time and the solar absorptance of the black cobalt and black cobalt–silver coatings.     

Anti-reflection (AR) coatings made by sol–gel processes: A review

Traditionally, various vacuum-based processes, depending on material systems and properties, and chemical etching process have been used for producing different types of anti-reflection (AR) coating on different substrate materials. In this paper, the development of sol–gel derived AR coating on different substrates for various applications in the past 40 years are reviewed. These coatings possess good uniformity in thickness and properties which have met requirements for various applications. The major approaches to fabricate AR coating and their characteristics have been discussed. This paper outlines the major solution coating processes and design principles of AR coatings. Major fabrication processes used in AR coating technologies have been compared. Different solution chemistries developed for producing different materials for AR coating preparation have been extensively reviewed. The optical performance of different types of sol–gel-derived AR coatings have been summarized and comparison to the commercial AR coating produced by traditional technologies have been discussed. The sol–gel AR coating has been shown to possess comparable or superior performance to those produced by vacuum-based processes.     

Advanced procedure for the assessment of the lifetime of solar absorber coatings

New solar absorber coatings are developed and used in advanced collector designs with improved efficiency. The operation temperature and stagnation temperature as the main durability load for the absorbers were increasing during the past due to these innovations. Especially the highly selective new coatings have to suffer by these stronger loads. The service life estimation procedures developed in the framework of research activities of the IEA Solar Heating and Cooling Programme (Task 10 and Working Group Materials in Solar–Thermal Collectors) were based on load profiles for less-advanced absorbers and collectors and did not take into account the impact of the optical properties of the absorber coatings on the stagnation temperature of the collectors, which is the main reason for temperature degradation. A new procedure was developed, which allows testing depending on the optical properties (Solar absorptance and thermal emittance) of the absorbers.     

The real utility ranges of the solar selective coatings

The efficiency of the solar selective coatings (η_sel) with various combinations of the optical properties (solar absorptance and thermal emittance), and their impact on the performance of solar thermal systems of different concentration ratios (CRs) have been analyzed. The stagnation temperatures of the selective coatings have been measured using stagnation temperature measurement (STM) chamber. From the results of the simulation study, it is recommended that selective solar absorber coatings should be used only in systems with CR=1 (solar flat plate collectors) and its use in systems with high CR values (parabolic collector) is an additional expenditure with reduced efficiency. The dependence of the performance of the system with CR=1 on the low emittance of the absorber coating has also been experimentally confirmed by the stagnation temperatures recorded for different selective coatings measured in an STM chamber, a system with unit CR. For systems with CR=1, a simple and new parameter, specific area ratio (SAR) has been proposed which further pinpoints the exact solar system wherein the selective coatings are to be used.     

Spectrally selective solar absorber coatings

A review is presented of the physical processes responsible for spectral selectivity in solar absorber coatings. Examples of practical coatings which have found common usage in solar heating systems are surveyed. The durability requirements of coatings are assessed and a summary of techniques of surface analysis is given.     

a-C:H absorber layer for solar cells matched to solar spectrum

An a-C:H-based absorber layer for photovoltaic application was fabricated by a DC PECVD. The stepped voltage biasing of the deposition process makes it possible to tailor the bandgap of the manufactured layers and match them to the solar spectrum. Such system can be used as intrinsic layer in p–i–n solar cells as well as in converter solar cells.