Formaldehyde Concentrations in Modern Houses

This article from the Institute of Occupational Health, Helsinki, briefly discusses the risks to air quality which may arise from low ventilation rates in modern dwellings. Measurements have shown that nearly half the houses examined had ventilation rates below the accepted minimum, and the incidence of unacceptable formaldehyde concentration was greater in newer houses, emphasising the need for a minimum ventilation rate of 0.5 ach.     

Indoor Climate and the Performance of Ventilation in Finnish Residences

The purpose of the study was to gather information about the actual ventilation and indoor air quality and to evaluate the differences between houses and apartments with different ventilation systems. A sample of 242 dwellings in the Helsinki metropolitan area was studied over periods of no weeks during the 1988-1989 heating season. The mean air-exchange rates had a high variation (average 0.52 l/h, range 0.07-1.55 l/h). The ASHRAE minimum value of 0.35 l/h was not achieved in 28% of the dwellings. The air-exchange rates were significantly her in the houses than in the apartments (averages 0.45/0.64 l/h, p < 0.001); in the natural ventilation systems they, were slightly her than in the mechanical systems. The average temperature in the bedrooms was approximately 22 °C (range 18–27 °C), slightly but significantly higher in the apartment than in the houses. The average dust depositions were higher in the balanced ventilation systems than in the other systems. The median radon concentration was 82 Bq/m³ (range 5-866 Bq/m³); the Finnish target value of 200 Bq/m³ was exceeded in 17% of the houses but in none of the apartment. The measurements indicate that the indoor air quality in Finnish dwellings is not always satisfactory with reference to human health and comfort.     

Radon and Natural Ventilation in Newer Danish Single-Family Houses

Abstract To investigate the effect of ventilation on indoor radon (²²²Rn), simultaneous measurements of radon concentrations and air change rates were made in 117 Danish naturally ventilated slab-on-grade houses built during the period 1984–1989. Radon measurements (based on CR-39 alpha-track detectors) and air change rate measurements (based on the perfluorocarbon tracer technique; PFT) were in the ranges 12–620 Bq m^?3 and 0.16?0.96 h^?1, respectively. Estimates of radon entry rates on the basis of such time-averaged results are presented and the associated uncertainty is discussed. It was found that differences in radon concentrations from one house to another are primarily caused by differences in radon entry rates whereas differences in air change rates are much less important (accounting for only 80,0% of the house-to-house variation). In spite of the large house-to-house variability of radon entry rates it was demonstrated, however, that natural ventilation does have a significant effect on the indoor radon concentration. Most importantly, it was found that the group of houses with an air change rate above the required level of 0.5 h^?1 on average had an indoor radon concentration that was only 50% (0.5±0.1) of that of the group of houses with air change rates below 0.5 h^?1. The reducing effect of increased natural ventilation on the indoor radon concentration was found to be due mainly to dilution of indoor air. No effect could be seen regarding reduced radon entry rates.     

Volatile organic compounds in 169 energy-efficient dwellings in Switzerland

Exposure to elevated levels of certain volatile organic compounds (VOCs) in households has been linked to deleterious health effects. This study presents the first large-scale investigation of VOC levels in 169 energy-efficient dwellings in Switzerland. Through a combination of physical measurements and questionnaire surveys, we investigated the influence of diverse building characteristics on indoor VOCs. Among 74 detected compounds, carbonyls, alkanes, and alkenes were the most abundant. Median concentration levels of formaldehyde (14 μg/m³), TVOC (212 μg/m³), benzene (<0.1 μg/m³), and toluene (22 μg/m³) were below the upper exposure limits. Nonetheless, 90% and 50% of dwellings exceeded the chronic exposure limits for formaldehyde (9 μg/m³) and TVOC (200 μg/m³), respectively. There was a strong positive correlation among VOCs that likely originated from common sources. Dwellings built between 1950s and 1990s, and especially, those with attached garages had higher TVOC concentrations. Interior thermal retrofit of dwellings and absence of mechanical ventilation system were associated with elevated levels of formaldehyde, aromatics, and alkanes. Overall, energy-renovated homes had higher levels of certain VOCs compared with newly built homes. The results suggest that energy efficiency measures in dwellings should be accompanied by actions to mitigate VOC exposures as to avoid adverse health outcomes.     

Radiation exposure in German dwellings,some results and a proposed formula for dose limitation

The results of our investigations in the Federal Republic of Germany on the indoor and outdoor exposure to natural radiation from gamma rays and radon and thoron daughters are presented. Indoor the median Rn-222 concentration was approximately four times higher than outdoors. A correlation analysis of the data obtained showed that indoors the equilibrium factor F is almost independent of ventilation, Rn-222 concentration and other parameters. The mean equilibrium factor was measured to be F = 0.3 in dwellings and approximately F = 0.4 outdoors. The results of our investigations on diffusion coefficients and exhalation rates showed, that the activity concentration in dwellings and in cellars can generally be explained by the radon exhalation from the building materials. Only in areas of high radon concentrations, the exhalation from the soil was a decisive factor. The mean effective dose equivalent by residence in dwellings amounted to 0.2 – 0.8 mSv/a for Rn-222 daughters and approximately 0.1 mSv/a for Rn-220 daughters. A relationship has been derived which permits the calculation of the expected average radiation exposure in dwellings by gamma radiation and by radon inhalation as function of the radionuclide concentration in building materials.     

Volatile organic pollutants in new and established buildings in Melbourne, Australia

Volatile organic compounds (VOCs) within new and established buildings have been determined and factors significant to their presence have been identified. In established dwellings, total volatile organic compound (TVOC) concentrations were low, but were approximately four times higher than in outdoor air, showing a dominant effect of indoor sources. The presence of attached garages, site contamination and 'faulty' wool carpet were associated with higher indoor pollution. In three dwellings, unidentified sources of benzene were indicated. Much higher VOC concentrations were observed in new or renovated buildings, persisting above "baseline" levels for several weeks, concentration decay rate correlating with VOC molecular volume, indicating emissions were limited by material diffusion processes. VOC and formaldehyde emission decays in a new dwelling occurred by a double-exponential source model. This shows that persistent low levels of volatile organic pollutants in established dwellings can occur due to long-term emissions from building materials.     

Factors controlling volatile organic compounds in dwellings in Melbourne,Australia

This study characterized indoor volatile organic compounds (VOCs) and investigated the effects of the dwelling characteristics, building materials, occupant activities, and environmental conditions on indoor VOC concentrations in 40 dwellings located in Melbourne, Australia, in 2008 and 2009. A total of 97 VOCs were identified. Nine VOCs, n‐butane, 2‐methylbutane, toluene, formaldehyde, acetaldehyde, d‐limonene, ethanol, 2‐propanol, and acetic acid, accounted for 68% of the sum of all VOCs. The median indoor concentrations of all VOCs were greater than those measured outdoors. The occupant density was positively associated with indoor VOC concentrations via occupant activities, including respiration and combustion. Terpenes were associated with the use of household cleaning and laundry products. A petroleum‐like indoor VOC signature of alkanes and aromatics was associated with the proximity of major roads. The indoor VOC concentrations were negatively correlated (P < 0.05) with ventilation. Levels of VOCs in these Australian dwellings were lower than those from previous studies in North America and Europe, probably due to a combination of an ongoing temporal decrease in indoor VOC concentrations and the leakier nature of Australian dwellings.     

Screening of formaldehyde indoor sources and quantification of their emission using a passive sampler

The formaldehyde emission rates from building and furniture materials in 24 student rooms were measured using a passive sampling method parallel to a monitoring of indoor and outdoor concentrations. This passive tool represents an interesting alternative to standard dynamic methods as it is easier to implement for field investigation. Although the indoor formaldehyde concentrations (21.3 μg m⁻³ on average) are at a medium level, consistent with earlier published results, the recorded emission rates are globally low (from 1 to 15 μg m⁻² h⁻¹) except for the high emission of beds identified in one building (87.3 μg m⁻² h⁻¹ on average). Data analysis revealed that the emissions released from furniture and building materials are the main contributions to the indoor formaldehyde concentrations with 45 and 43% on average. The high formaldehyde levels in rooms are mainly explained by the rise of formaldehyde emissions from indoor materials with temperature although the buildings and the furniture were older than 7 years. Basing on the data of emission rates, outdoor concentrations and air exchange rates, a one compartment mass balance model was used to calculate indoor concentrations. A good agreement was found between the predictions of the model and the measured indoor concentrations. This methodology could lead to the definition of arrangements for the efficient reduction of indoor formaldehyde levels.     

Challenges in Comparing Radon Data Sets from the Same Swedish Houses: 1955–1990

We compare data sets from two different Swedish studies which included measuremem of the indoor radon concentration both in 1955 and in 1990 in 178 of the same houses. The purpose is to learn more about how the indoor radon concentration changes over a time scale of years in the same houses. Many sources of both systematic and random errors exist when comparing these types of data sets. Specific types of errors are due to uncertainties in the calibration of the epuipment, the influence of the weather, the time lengths of sampling, airing of some of the dwellings, and changes in ventilation rates. The data indicate a general increase of the radon concentration in the dwellings between 1955 and 1990, with a 1990/1955 ratio of the averages of 1.3. The average radon concentration in all alum shale houses, (where the building material is a source of radon) in 1990 versus 1955 is 204 ± 22 and 163 ± 23 Bq/m³ and in non-alum shale houses is 62 ± 8 and 42 ± 7 Bq/m³, respectively.     

Effects of Climatic Parameters on Formaldehyde Concentrations in Indoor Air

The results of measurements of indoor air formaldehyde concentrations in occupational and private residences are presented for the period 1986 to 1993, based on requests of persons who complained about irritations. In many cases, climatic parameters such as the air exchange rate, temperature and relative humidity were also monitored. Calculated mean values for temperature and humidity were 22°C and 45% respectively. The average air exchange rate was 0.36 h^?1, which is well below a recommended guideline value of 0.8 h?' and it was evident that the ventilation is clearly insufficient in many rooms. The average formaldehyde concentration was 119 μg/m ^?3 (252 data), which is only slightly below the German guideline value of 125 μg/m ^?3. In 31% of the cases this guideline was exceeded. As expected, a clear relation between formaldehyde concentrations and the air exchange rate was found. The highest levels result at AE≤0.8 h^?1, but only a single value exceeds 125 μg/m ^?3 at AE≥0.8 h^?1. The association of law ventilation rates with high formaldehyde levels is also evident from a comparison with theoretical data after normalization to AE=0.8 h^?1, using the Hoetjer-equation. It was also observed that the calculated annual mean concentrations decreased from 1986 to 1993.     

Indoor air quality and the associated health risk in primary school buildings in Central Europe – The InAirQ study

The indoor air quality (IAQ) was investigated in sixty-four primary school buildings in five Central European countries (Czech Republic, Hungary, Italy, Poland, and Slovenia). The concentration of volatile organic compounds, aldehydes, PM_2.5 mass, carbon dioxide, radon, as well as physical parameters were investigated during the heating period of 2017/2018. Significant differences were identified for the majority of the investigated IAQ parameters across the countries. The median indoor/outdoor ratios varied considerably. A comprehensive evaluation of IAQ in terms of potential health effects and comfort perception was performed. Hazard quotient values were below the threshold value of 1 with one exception. In contrast, 31% of the school buildings were characterized by hazard index values higher than 1. The maximum cumulative ratio approach highlighted that the concern for non-carcinogenic health effects was either low or the health risk was driven by more substances. The median excess lifetime cancer risk values exceeded the acceptable value of 1 × 10⁻⁶ in the case of radon and formaldehyde. PM_2.5 mass concentration values exceeded the 24 h and annual guideline values set by the World Health Organization in 56 and 85% of the cases, respectively. About 80% of the schools could not manage to comply with the recommended concentration value for carbon dioxide (1000 ppm).     

A comparison of calculated indoor radiation exposure with the results of measurements

A model has been developed for the calculation of external and internal radiation exposure of the population in dwellings. The model consists of two adjacent rooms on top of a crawl-space. The indoor gamma ray exposure rates and the radon concentrations in indoor air, predicted for a variety of conditions, are compared with observations. Predictions and observations are in reasonable agreement; for the radon concentration the predictions may be around 40% too low.     

Formaldehyde and acetaldehyde exposure mitigation in US residences: in‐home measurements of ventilation control and source control

Measurements were taken in new US residences to assess the extent to which ventilation and source control can mitigate formaldehyde exposure. Increasing ventilation consistently lowered indoor formaldehyde concentrations. However, at a reference air exchange rate of 0.35 h^?1, increasing ventilation was up to 60% less effective than would be predicted if the emission rate were constant. This is consistent with formaldehyde emission rates decreasing as air concentrations increase, as observed in chamber studies. In contrast, measurements suggest acetaldehyde emission was independent of ventilation rate. To evaluate the effectiveness of source control, formaldehyde concentrations were measured in Leadership in Energy and Environmental Design (LEED)‐certified/Indoor airPLUS homes constructed with materials certified to have low emission rates of volatile organic compounds (VOC). At a reference air exchange rate of 0.35 h^?1, and adjusting for home age, temperature and relative humidity, formaldehyde concentrations in homes built with low‐VOC materials were 42% lower on average than in reference new homes with conventional building materials. Without adjustment, concentrations were 27% lower in the low‐VOC homes. The mean and standard deviation of formaldehyde concentration was 33 μg/m³ and 22 μg/m³ for low‐VOC homes and 45 μg/m³ and 30 μg/m³ for conventional.     

Surveys of natural radiation exposure in UK dwellings with passive and active measurement techniques

A representative sample of over 2,000 UK dwellings was monitored for a year using thermoluminescent and etchable plastic dosemeters to measure gamma-ray dose rates and radon concentrations. The survey was carried out by post. Each householder completed a questionnaire on the type of dwelling and its characteristics. These data will be used in the assessment of the factors affecting indoor exposure. The mean gamma-ray dose rates were 0.062 and 0.057 μGy h^?1 in air and the mean radon concentrations were 25 and 18 Bq m^?3 for living areas and bedrooms respectively. Other results of the preliminary data analysis are given.More detailed surveys were conducted in areas where the local geology indicated that elevated exposures to natural radiation might occur. Over 800 dwellings were visited and measurements made of several parameters. The mean gamma-ray dose rates varied from 0.05 to 0.10 μGy h^?1 in air. The mean radon concentrations varied from 14 Bq m^?3 to 520 Bq m^?3. Other findings related to equilibrium factors and regional differences are discussed.     

Volatile organic compounds in fourteen U.S. retail stores

Retail buildings have a potential for both short‐term (customer) and long‐term (occupational) exposure to indoor pollutants. However, little is known about volatile organic compound (VOC) concentrations in the retail sector and influencing factors, such as ventilation, in‐store activities, and store type. We measured VOC concentrations and ventilation rates in 14 retail stores in Texas and Pennsylvania. With the exception of formaldehyde and acetaldehyde, VOCs were present in retail stores at concentrations well below health guidelines. Indoor formaldehyde concentrations ranged from 4.6 ppb to 67 ppb. The two mid‐sized grocery stores in the sample had the highest levels of ethanol and acetaldehyde, with concentrations up to 2.6 ppm and 92 ppb, respectively, possibly due to the preparation of dough and baking activities. Indoor‐to‐outdoor concentration ratios indicated that indoor sources were the main contributors to indoor VOC concentrations for the majority of compounds. There was no strong correlation between ventilation and VOC concentrations across all stores. However, increasing the air exchange rates at two stores led to lower indoor VOC concentrations, suggesting that ventilation can be used to reduce concentrations for some specific stores.     

木板壁民居对湿热气候的适应性

为调查山地木板壁民居对重庆夏季湿热气候的适应性,选取当地典型木板壁民居作为研究对象,在夏季对其室内热环境进行实测。结合当地建筑特点及居民生活习惯,对实测数据进行分析,并利用APMV对室内热环境进行评价。结果表明,木板壁民居夏季依靠自然通风显著改善了室内热舒适度,夏季典型日APMV达Ⅱ级以上的约占65%。传统木夹壁民居在热环境营造上响应了当地气候特点,具有较好的气候适应性。     

Modeling ventilation and radon in new Dutch dwellings

Indoor radon concentrations were estimated for various ventilation conditions, the differences being mainly related to the airtightness of the dwelling and the ventilation behavior of its occupants. The estimations were aimed at describing the variation in air change rates and radon concentrations to be expected in the representative newly built Dutch dwellings and identifying the most important parameters determining air change rate and indoor radon concentration. The model estimations were compared with measurements. Most of the air was predicted to enter the model dwelling through leaks in the building shell, independent of the ventilation conditions of the dwelling. Opening the air inlets was shown to be an efficient way to increase infiltration and thus to decrease radon concentration. The effect of increasing the mechanical ventilation rate was considerably less than opening the air inlets. The mechanical ventilation sets the lower limit to the air change rate of the dwelling, and is effective in reducing the radon concentration when natural infiltration is low. Opening inside doors proved to be effective in preventing peak concentrations in poorly ventilated rooms. As the airtightness of newly built dwellings is still being improved, higher radon concentrations are to be expected in the near future and the effect of occupant behavior on indoor radon concentrations is likely to increase. According to the model estimations soil-borne radon played a moderate role, which is in line with measurements.     

Occupational exposure and health risks of volatile organic compounds of hotel housekeepers: Field measurements of exposure and health risks

Hotel housekeepers represent a large, low-income, predominantly minority, and high-risk workforce. Little is known about their exposure to chemicals, including volatile organic compounds (VOCs). This study evaluates VOC exposures of housekeepers, sources and factors affecting VOC levels, and provides preliminary estimates of VOC-related health risks. We utilized indoor and personal sampling at two hotels, assessed ventilation, and characterized the VOC composition of cleaning agents. Personal sampling of hotel staff showed a total target VOC concentration of 57 ± 36 µg/m³ (mean ± SD), about twice that of indoor samples. VOCs of greatest health significance included chloroform and formaldehyde. Several workers had exposure to alkanes that could cause non-cancer effects. VOC levels were negatively correlated with estimated air change rates. The composition and concentrations of the tested products and air samples helped identify possible emission sources, which included building sources (for formaldehyde), disinfection by-products in the laundry room, and cleaning products. VOC levels and the derived health risks in this study were at the lower range found in the US buildings. The excess lifetime cancer risk (average of 4.1 × 10⁻⁵) still indicates a need to lower exposure by reducing or removing toxic constituents, especially formaldehyde, or by increasing ventilation rates.     

A review of the emission of VOCs from polymeric materials used in buildings

Building and furnishing materials and consumers products are important sources of formaldehyde and other volatile organic compounds (VOCs) in the indoor environment. The emission from materials is usually continuous and may last for many years in a building. The available evidence indicates that VOCs can cause adverse health effects to the building occupants and may contribute to symptoms of ‘Sick Building Syndrome’.

Control of VOC emission should increasingly become an important consideration for the design and manufacture of polymeric materials used in buildings. The EC Construction Products Directive ‘Essential Requirements’ set a framework for limiting the use of materials that could pose a health risk to building occupants. Furthermore, the on-going development of voluntary labelling schemes and data bases of material emissions that could be used by building designers, should further strengthen the demand for ‘low VOC emitting’ products.

This paper reviews available information about the emission of VOCs from polymeric building materials, the level of emissions in the indoor environment and the requirements for testing of the materials.     

A quantitative estimate of the accuracy of tracer gas methods for the determination of the ventilation flow rate in buildings

The paper presents a quantitative estimate of the error of the decay and constant concentration method. A number of tests were carried out in an indoor test house located in the laboratory hall at the National Swedish Institute for Building Research. At the beginning of the paper the relevant meaning of the concept ‘air-exchange rate’ is discussed and an appropriate terminology is suggested. Then follows a presentation of the theoretical background, based on a multi-cell model, of the two tracer gas methods studied experimentally. Finally, the results obtained are given. Apart from the accuracy of the tracer gas methods, some results of studies of the effect on the infiltration rate due to different operation modes of mechanical ventilation systems are also presented.