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1.
Characterization and Oxidative Stability of Structured Lipids: Infant Milk Fat Analog 总被引:2,自引:0,他引:2
C. O. Maduko Y. W. Park C. C. Akoh 《Journal of the American Oil Chemists' Society》2008,85(3):197-204
Structured lipids (SLs) for infant milk formulation were produced by enzymatic interesterification of tripalmitin with vegetable
oil blends and fish oil. The SLs were characterized by fatty acid content and structure, melting profiles, oxidative stability
index, free fatty acid (FFA) concentration, and tocopherol content. Oxidative stability was studied using accelerated methods
by quantifying FFA, peroxides (peroxide value) and aldehydes (p-anisidine value) production. Total oxidation (TOTOX value)
was calculated as 2 × (peroxide value) + (p-anisidine value). The structured lipids after purification by distillation and
addition of antioxidants had melting profiles, oxidative stability index, and initial FFA concentration that were similar
to that of the starting oil blends, while the fatty acid composition and structure of the SLs were similar to that of human
milk fat. Oxidative stability of the SLs was improved with tocopherol addition as antioxidants and was comparable to that
of the vegetable oils and oil blends. 相似文献
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Zhiping Shen Sukhdeep Bhail Luz Sanguansri Mary Ann Augustin 《Journal of the American Oil Chemists' Society》2014,91(8):1347-1354
A positively charged protein (fish gelatin) or a negatively charged protein species (heat-treated milk protein–carbohydrate mixture) was added to a primary krill oil (KO) emulsion stabilized by the phospholipids inherent in KO, with the aim of improving the oxidative stability of KO-in-water emulsions at pH 8.0 (10 % KO). The positively charged fish gelatin deposited on the primary interface of the oil droplets in the primary KO-in-water emulsion improved the oxidative stability of the KO-in-water emulsion as evidenced by the higher eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA) remaining and lower propanal produced after accelerated oxidation (40 °C, 25 days). The addition of the negatively charged heat-treated milk protein–carbohydrate mixture containing Maillard reaction products (MRP) to the bulk phase of the emulsion also enhanced the oxidative stability of the KO-in-water emulsion. The addition of MRP to the aqueous phase of phospholipids stabilized emulsion droplets offered more protection to EPA and DHA of the KO emulsions compared to the formation of an additional layer at the interface of the KO emulsion droplet. This suggests that interventions based on addition of antioxidant species to the formulation were more effective for arresting oxidation than increasing the thickness of the droplet interface. The addition of proteins into KO containing emulsion formulations is a promising strategy for protecting omega-3 marine phospholipids against oxidation. 相似文献
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通过正交试验研究复合表面活性剂乳状液稳定性,得出了所研究范围内复合表面活性剂的稳定性方程,并通过MATLAB数学软件求出其最优配方为OP-10为1%,十二烷基硫酸钠0.2%,椰油酰胺基丙基甜菜碱(CAB-35)0.2%,异丙醇0.02%,最后通过实验论证该体系为最优配方。 相似文献
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Cong Zhao Junkui Miao Meiyu Sui Xisheng Liu Yueqin Yu 《Journal of surfactants and detergents》2019,22(3):633-639
Sodium alginate was hydrophobically modified with dodecenyl succinic anhydride in a neutral aqueous solution (pH = 6.8) at room temperature, forming an environmentally friendly amphiphile dodecenyl-modified alginate (DMA). Surface activity of DMA was assessed using surface tension and zeta-potential measurements. Hydrophobic compound-loading capacity as well as oil-in-water emulsion stability of DMA solutions were investigated to study the potential applications of DMA. The critical micelle concentration (CMC) of DMA aqueous solution was found to be 0.70 mg mL−1 with the surface tension being around 33.0 mN m−1. DMA solutions were able to solubilize hydrophobic compounds like Sudan IV and Clofazimine in aqueous medium. 10% peanut oil-in-water emulsions stabilized by 10 mg mL−1 DMA presented good stability during 7 days of storage and the interfacial tension between water and oil was lowered from 23.0 to 9.0 mN m−1. Results showed that DMA was an efficient surfactant and could work as a drug-delivery vehicle or a natural food emulsion stabilizer in the future. 相似文献
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以甲基丙烯酸甲酯,丙烯酸丁酯为单体,用自制的乳化剂合成了全内乳液。配制了性能良好的乳胶漆,讨论了PVC等因素对乳胶漆性能的影响。 相似文献
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采用VAC/BA/AAm三元共聚体系制备乳液型书画装裱粘合剂。对PVA用量、聚合反应温度、引发 剂、pH值、AAm用量等对粘合剂性能的影响进行了研究,确定了最优制备条件。 相似文献
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介绍了司盘-80有关指标与乳化液稳定性的关系,实验结果表明,在一定范围内增加酯化物含量,放 范围,降低水分含量有利于乳化液稳定性的提高,由不同质量油酸生产的司盘-80的酸值,对乳化液稳定性的影响不具有可比性。 相似文献
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F. S. H. Lu B. R. Thomsen G. Hyldig D. M. B. Green-Petersen N. S. Nielsen C. P. Baron C. Jacobsen 《Journal of the American Oil Chemists' Society》2013,90(11):1673-1683
Marine phospholipids (PL) are potential ingredients for food fortification due to its numerous advantages. The main objective of this study was to investigate whether a fermented milk product fortified with a mixture of marine PL and fish oil had better oxidative stability than a fermented milk product fortified with fish oil alone. Fortification of a fermented milk product with marine PL was performed by incorporating 1 % w/w lipids, either in the form of neat oil or in the form of a pre-emulsion. Lipid oxidation was investigated in the neat emulsions and fortified products by the measurements of primary, secondary volatile oxidation products and tocopherol content upon 32 days storage at 2 °C and 28 days storage at 5 °C, respectively. Analyses of particle size distribution, viscosity and microbial growth were also performed. In addition, sensory attributes such as sour, fishy and rancid flavor/odor were evaluated in fortified products by a trained panel. The results obtained showed that incorporation of a mixture of marine PL and fish oil into fermented milk products decreased the oxidative stability and sensory quality of fortified products. The pH-dependent behavior of iron seemed to be the main factor that influenced the lipid oxidation in the marine PL emulsion and fermented milk system. In addition, both oxidative stability and sensory acceptability of fortified products varied depending on the quality of the marine PL used for fortification. 相似文献
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Enzymatic Synthesis of Tyrosol-Based Phenolipids: Characterization and Effect of Alkyl Chain Unsaturation on the Antioxidant Activities in Bulk Oil and Oil-in-Water Emulsion 下载免费PDF全文
Oxidative stability of lipids is one of the most important parameters affecting their quality. Lipase‐catalyzed lipophilic tyrosyl esters with an equivalent carbon alkyl chain but different degrees of unsaturation (C18:0 to C18:4n3) were prepared, characterized, and used as antioxidants. Free fatty acids and fatty acid ethyl esters (substrate molar ratio tyrosol: acyl donor, 1:10) were used as acyl donors and immobilized lipase from Candida antarctica was the biocatalyst (10 %). The phenolipids were isolated and characterized using ESI–MS, 1H‐NMR, and 13C‐NMR. Peroxide value (PV) and para‐anisidine value (p‐AV) were measured to evaluate their antioxidant activities in bulk oil structured lipid (SL) and in an oil‐in‐water emulsion (SL‐based infant formula). No significant difference was found in yield and reaction time between the two types of acyl donors. However, as the unsaturation of the fatty acids increased the reaction time also increased. In SL, tyrosyl esters exhibited lower antioxidant activity than tyrosol whereas the addition of an alkyl chain enhanced the antioxidant efficiency of tyrosol in infant formula. Tyrosyl oleate was the most efficient antioxidant in the emulsion system followed by tyrosyl stearate and tyrosyl linoleate. These results suggest that the synthesized phenolipids may be used as potential antioxidants in lipid‐based products. 相似文献
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Oxidation and Colloidal Stability of Oil-in-Water Emulsion as Affected by Pigmented Rice Hull Extracts 下载免费PDF全文
Nopparat Cheetangdee Soottawat Benjakul 《Journal of the American Oil Chemists' Society》2016,93(4):519-529
Extracts from the hull of pigmented rice were prepared using a mixture of methanol–water (1:1, 2:1, and 3:1, v/v) for different extraction times (0–180 min). Total phenolic content (TPC) of the extracts increased with increasing concentration of methanol and extraction time (P < 0.05). A positive correlation between TPC and antioxidant activities, i.e., DPPH and ABTS radical scavenging activities and reducing power, was observed. The extracts prepared using methanol–water at the ratio of 3:1 for 180 min at 50 °C, referred as rice hull phenolic extract (RHPE), showed the highest TPC and free radical scavenging abilities and reducing power (P < 0.05). When the effects of RHPE on physicochemical stability of the emulsions stabilized by different emulsifiers, i.e., Tween 20 and bovine serum albumin (BSA), were examined, the collapse of emulsion was retarded when RHPE was applied in BSA‐based emulsions, whereas a negative effect was noticeable in Tween 20‐based counterpart. Lower oxidative degree was found for BSA stabilized emulsions, compared to Tween 20 containing system. RHPE (1–3 %) markedly improved the oxidative stability, particularly for BSA stabilized emulsions. Therefore, RHPE could be employed along with the selected protein to increase physicochemical stability of emulsion. 相似文献
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Khadije Abdolmaleki Mohammad Amin Mohammadifar Zhian Sheikhi Golshan Matinfar Kooshan Nayebzadeh 《Journal of the American Oil Chemists' Society》2019,96(7):795-803
Different emulsions based on six types of vegetable oils (sunflower, canola, sesame, olive, coconut, and palm olein) were studied to investigate the role of the oil phase in the stability and physicochemical characteristics of oil-in-water emulsions prepared with gum tragacanth. The results indicated that the stability, rheological parameters, and size distribution of emulsions were dependent on the oil type. Based on the interfacial tension value, the type of oil did not have a significant effect on the gum tragacanth-emulsifying properties. The formulation based on sunflower and coconut oil led to producing more stable emulsion and a sample containing palm olein resulted in an unstable emulsion. Rheological analysis revealed that the sample based on palm olein showed the lowest consistency coefficient (2.10 ± 0.05 Pas n), elastic modulus (3.90 ± 0.21 Pa), and energy of cohesion (80.87 ± 1.1 J m−3). This study revealed that using oils with lower viscosity and higher density led to the higher stability of the emulsion samples. 相似文献
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Lilon I. Merrill Oscar A. Pike Lynn V. Ogden Michael L. Dunn 《Journal of the American Oil Chemists' Society》2008,85(8):771-776
The oxidative stability of conventional and high-oleic varieties of commercial vegetable oils, with and without added antioxidants,
was evaluated using the oil stability index (OSI). Oil varieties studied were soybean (SOY), partially-hydrogenated soybean
(PHSOY), corn (CORN), sunflower (SUN), canola (CAN), high-oleic canola (HOCAN), very high-oleic canola (VHOCAN), oleic safflower
(SAF) and high-oleic sunflower (HOSUN). One or more commercial antioxidants were added to the four most stable oils at supplier-recommended
levels: rosemary extract (RM; 1,000 ppm), ascorbyl palmitate (AP; 1,000 ppm), tert-butylhydroquinone (TBHQ; 200 ppm), and mixed tocopherols (TOC; 200 ppm). OSI in hours (h) at 110 °C of the conventional oils
were 5.2, 7.6, 8.4, 9.8, 10.9 and 14.3 h for SUN, SOY, CAN, CORN, PHSOY and SAF, respectively. OSI of high-oleic variants
were 12.9, 16.5 and 18.5 h for HOCAN, HOSUN and VHOCAN, respectively. Maximum OSI values for the four most stable oils when
treated with antioxidants, were 40.9, 48.5, 48.8 and 55.7 h for HOCAN, VHOCAN, SAF and HOSUN, respectively. Addition of TBHQ,
alone and in combination with other antioxidants, resulted in the greatest increase in oxidative stability of SAF and other
high-oleic oils evaluated. AP had a positive synergistic effect when used with TBHQ, while RM decreased TBHQ effectiveness. 相似文献
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