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1.
Stability improvement of CO2 foam for enhanced oil‐recovery applications using polyelectrolytes and polyelectrolyte complex nanoparticles
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Nishkriya Kalyanaraman Cameron Arnold Aadish Gupta Jyun Syung Tsau Reza Barati Ghahfarokhi 《应用聚合物科学杂志》2017,134(6)
CO2 foam for enhanced oil‐recovery applications has been traditionally used in order to address mobility‐control problems that occur during CO2 flooding. However, the supercritical CO2 foam generated by surfactant has a few shortcomings, such as loss of surfactant to the formation due to adsorption and lack of a stable front in the presence of crude oil. These problems arise because surfactants dynamically leave and enter the foam interface. We discuss the addition of polyelectrolytes and polyelectrolyte complex nanoparticles (PECNP) to the surfactant solution to stabilize the interface using electrostatic forces to generate stronger and longer‐lasting foams. An optimized ratio and pH of the polyelectrolytes was used to generate the nanoparticles. Thereafter we studied the interaction of the polyelectrolyte–surfactant CO2 foam and the polyelectrolyte complex nanoparticle–surfactant CO2 foam with crude oil in a high‐pressure, high‐temperature static view cell. The nanoparticle–surfactant CO2 foam system was found to be more durable in the presence of crude oil. Understanding the rheology of the foam becomes crucial in determining the effect of shear on the viscosity of the foam. A high‐pressure, high‐temperature rheometer setup was used to shear the CO2 foam for the three different systems, and the viscosity was measured with time. It was found that the viscosity of the CO2 foams generated by these new systems of polyelectrolytes was slightly better than the surfactant‐generated CO2 foams. Core‐flood experiments were conducted in the absence and presence of crude oil to understand the foam mobility and the oil recovered. The core‐flood experiments in the presence of crude oil show promising results for the CO2 foams generated by nanoparticle–surfactant and polyelectrolyte–surfactant systems. This paper also reviews the extent of damage, if any, that could be caused by the injection of nanoparticles. It was observed that the PECNP–surfactant system produced 58.33% of the residual oil, while the surfactant system itself produced 47.6% of the residual oil in place. Most importantly, the PECNP system produced 9.1% of the oil left after the core was flooded with the surfactant foam system. This proves that the PECNP system was able to extract more oil from the core when the surfactant foam system was already injected. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 44491. 相似文献
2.
Daniel Hatchell Xiongyu Chen Hugh Daigle Matthew Hartmann John-Richard Ordonez-Varela Christophe Blondeau Keith Johnston 《Journal of surfactants and detergents》2023,26(3):421-435
CO2 enhanced oil recovery and storage could see widespread deployment as decarbonization efforts accelerate to meet climate goals. CO2 is more efficiently distributed underground as a viscous foam than as pure CO2; however, most reported CO2 foams are unstable at harsh reservoir conditions (22 wt% brine, 2200 psi, and 80°C). We hypothesize that silica nanoparticles (NP) grafted with (3-trimethoxysilylpropyl)diethylenetriamine ligands (N3), to improve colloidal stability, and dimethoxydimethylsilane ligands (DM), to improve CO2-phillicity, combined with the cationic surfactant N1-alkyl-N3, N3-dimethylpropane-1,3-diamine (RCADA), will develop viscous, stable CO2 foams at reservoir conditions. We grafted NP with N3 and DM ligands. We verified NP stability at reservoir conditions with measurements of zeta potential, amine titration curves, and NP diameter. We measured NP water contact angles (θw) at the water–air and water–liquid CO2 interfaces. In a high-temperature, high-pressure flow apparatus, we calculated the viscosity of CO2 foams across a beadpack and determined static foam stability with microscope observations. Modified NP were colloidally stable at reservoir conditions for 4 weeks, and had higher θw in liquid CO2 than in air. Addition of at least 0.5 μmol/m2 DM silane (0.5DM) greatly improved foam stability. RCADA-only foam coarsening rates (dDSM3/dt) decreased 16–17× after adding 1 wt/vol% 8N3 + 1.5DM NP, and 5–10× with a 0.1–1 vol/vol% increase in RCADA concentration (with or without NP). 1 vol/vol% RCADA foam exhibited coarsening rates of 900 and 2400 μm3/min with 1 and 0.2 wt/vol% 8N3 + 1.5DM NP, respectively. These results demonstrate impressive foam stabilities at harsh reservoir conditions. 相似文献
3.
Stabilization of CO2‐in‐water emulsions with high internal phase volume using PVAc‐b‐PVP and PVP‐b‐PVAc‐b‐PVP as emulsifying agents
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Li Wen Liwen Wang Shuyi Fang Lei Bao Dongdong Hu Yuan Zong Ling Zhao Tao Liu 《应用聚合物科学杂志》2018,135(23)
Two newly‐designed hydrocarbon surfactants, that is, poly(vinyl acetate)‐block‐poly(1‐vinyl‐2‐pyrrolidone) (PVAc‐b‐PVP) and PVP‐b‐PVAc‐b‐PVP, were synthesized using reversible addition–fragmentation chain transfer polymerization and used to form CO2/water (C/W) emulsions with high internal phase volume and good stability against flocculation and coalescence up to 60 h. Their structures were precisely determined by nuclear magnetic resonance, gel permeation chromatography, thermal gravimetric analysis, and differential scanning calorimetry. Besides low temperature and high CO2 pressure, the surfactant structures were the key factors affecting the formation and stability of high internal phase C/W emulsions, including the polymerization degrees of CO2‐philic block (PVAc) and hydrophilic block (PVP), as well as the number of hydrophilic tail. The surface tension of the surfactant aqueous solution and the apparent viscosity of the C/W emulsions were also measured to characterize the surfactants efficiency and effectiveness. The surfactants with double hydrophilic tails showed stronger emulsifying ability than those with single hydrophilic tail. The great enhancement of the emulsions stability was due to decrease of the interface tension as well as increase of the steric hindrance in the water lamellae, preventing a frequent collision of CO2 droplets and their fast coalescence. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46351. 相似文献
4.
Weiyu Bi Panfeng Zhang Xiangrui Du Wei Lü Shitou Wang Tangying Yang Liping Ma Xiaochun Liu Haifeng Zhao Shaoran Ren 《Journal of surfactants and detergents》2022,25(3):387-398
Natural gas foam can be used for mobility control and channel blocking during natural gas injection for enhanced oil recovery, in which stable foams need to be used at high reservoir temperature, high pressure and high water salinity conditions in field applications. In this study, the performance of methane (CH4) foams stabilized by different types of surfactants was tested using a high pressure and high temperature foam meter for surfactant screening and selection, including anionic surfactant (sodium dodecyl sulfate), non-anionic surfactant (alkyl polyglycoside), zwitterionic surfactant (dodecyl dimethyl betaine) and cationic surfactant (dodecyl trimethyl ammonium chloride), and the results show that CH4-SDS foam has much better performance than that of the other three surfactants. The influences of gas types (CH4, N2, and CO2), surfactant concentration, temperature (up to 110°C), pressure (up to 12.0 MPa), and the presence of polymers as foam stabilizer on foam performance was also evaluated using SDS surfactant. The experimental results show that the stability of CH4 foam is better than that of CO2 foam, while N2 foam is the most stable, and CO2 foam has the largest foam volume, which can be attributed to the strong interactions between CO2 molecules with H2O. The foaming ability and foam stability increase with the increase of the SDS concentration up to 1.0 wt% (0.035 mol/L), but a further increase of the surfactant concentration has a negative effect. The high temperature can greatly reduce the stability of CH4-SDS foam, while the foaming ability and foam stability can be significantly enhanced at high pressure. The addition of a small amount of polyacrylamide as a foam stabilizer can significantly increase the viscosity of the bulk solution and improve the foam stability, and the higher the molecular weight of the polymer, the higher viscosity of the foam liquid film, the better foam performance. 相似文献
5.
In this study, a benign process was used to successfully produce low density foam from poly(arylene ether sulfone) (PAES). Both carbon dioxide (CO2) and water as well as nitrogen and water were used as physical blowing agents in a one‐step batch process. A large amount of blowing agents (up to 7.5%) was able to diffuse into the PAES resin in a 2‐h saturation time. Utilizing water and CO2 as the blowing agents yielded foam with better properties than nitrogen and water because both the water and CO2 are plasticizers for the PAES resin. PAES foam produced from CO2 and water had a large reduction in foam density (~80%) and a cell size of ~50 μm, while maintaining a primarily closed cell structure. The small cell size and closed cell structure enhanced the mechanical properties of the foam when compared with the PAES foam produced from nitrogen and water. The tensile, compressive, and notched izod impact properties of the PAES foams were examined, and the compressive properties were compared to commercially available structural foams. With reduced compression strength of 39 MPa and reduced compression modulus of 913 MPa, the PAES foam is comparable to polyetherimide and poly(vinylchloride) structural foams. POLYM. ENG. SCI., 2009. © 2008 Society of Plastics Engineers 相似文献
6.
Ganesh A. Bathe Mandar S. Bhagat Bhushan L. Chaudhari 《Journal of surfactants and detergents》2018,21(3):409-419
The purpose of this study was to understand and compare the dynamic foam behavior of the surfactant Tween‐20 in air–water and CO2–water systems. The foam height in the CO2–water system was less than that in the air–water system, but the foam stability was better in the CO2–water system. The effect of temperature on axial dye displacement and foam bubble size was studied, where the foam generation ability of the surfactant was directly proportional to the temperature, while the foaminess was inversely proportional. The observed highest foam volume for the air–water system was 3922 ± 181 cm3 and for the CO2–water system 3195 ± 181 cm3 at 5.0 g L–1 of surfactant at air flow rate of 1 liter per minute (LPM) at 52 °C. The half‐life for the air–water and the CO2–water system was 110 and 40 s, respectively, at 5.0 g L–1 of surfactant at the air flow rate of 1 LPM and 28 °C. In wet foam, the liquid holdup range for the air–water system was 0.38–0.52% and for the CO2–water system 0.51–0.72% in the concentration range 1.0–5.0 g L–1 at 1 LPM gas flow rate. 相似文献
7.
Preparation of open‐cell foams from polymer blends by supercritical CO2 and their efficient oil‐absorbing performance
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Yu‐Wei Fang Jin‐Biao Bao Hai‐Kuo Yan Wei Sun Ling Zhao Guo‐Hua Hu 《American Institute of Chemical Engineers》2016,62(12):4182-4185
This letter reports on the hydrophobicity and oleophilicity of open‐cell foams from polymer blends prepared by supercritical CO2. A typical bulk density of the foam is measured to be 0.05 g/cm3. The contact angle of the foam with water is determined to be 139.2°. The foam can selectively absorb the diesel from water with the uptake capacity of 17.0 g/g. The foams are technologically promising for application of oil spill cleanup. © 2016 American Institute of Chemical Engineers AIChE J, 62: 4182–4185, 2016 相似文献
8.
Hongsheng Lu Xueqian Guan Baogang Wang Zhiyu Huang 《Journal of surfactants and detergents》2015,18(5):773-782
By mixing an aqueous solution of tertiary amine, N,N‐dimethylethanolamine (DMEA), with naphthenic acid (RCOOH) derived from heavy oil, a CO2 switchable zwitterionic surfactant (RCOO?DMEAH+) aqueous system was constructed. The CO2 switchability of this zwitterionic surfactant was confirmed by visual inspection, pH measurements, and conductivity tests, i.e., the RCOO?DMEAH+ decomposed into RCOOH, DMEAH+ and HCO3? after bubbling CO2 through but switched back to its original state by subsequent bubbling N2 through at 80 °C to remove the CO2. The interfacial tension tests of heavy oil in DMEA aqueous solutions indicated that the solution containing 0.5 wt% of DMEA and 0.2 wt% of NaCl resulted in the lowest interfacial tension. The O/W emulsion formed when aqueous solutions of DMEA were used to emulsify heavy oil exhibited the best performance when the oil/water volume ratio, DMEA concentration, and NaCl concentration were 65:35, 0.5 and 0.2 wt%, respectively. The feasibility of pipeline transport of the O/W heavy oil emulsion was evaluated. The results illustrated that the demulsification of the O/W emulsion after transport could be easily realized by bubbling CO2 through. Although demulsification efficiency still needs to be improved, the recycling of the aqueous phase after demulsification by removal of CO2 looks promising. 相似文献
9.
Measurements of interfacial tensions for 2-ethyl-hexanol-(propylene oxide)∼4.5-(ethylene oxide)∼8 (2EH-PO4.5-EO8) at the planar water-CO2 interface and the surfactant distribution coefficient are utilized to explain microemulsion and macroemulsion phase behavior from 24 to 60 °C and 6.9 to 27.6 MPa. A CO2 captive bubble technique has been developed to measure the interfacial tension γ at a known surfactant concentration in the aqueous phase, with rapid equilibration at the water-CO2 interface. The surface pressure (γo − γ) decreases modestly with density at constant temperature as CO2 solvates the surfactant tails more effectively, but changes little with temperature at constant density. The area per surfactant at the CO2-water interface determined from the Gibbs adsorption equation decreases from 250 A2/molecule at 24 °C and 6.9 MPa, to 200 A2/molecule at 27.6 MPa. It was approximately twofold larger than that at the water-air interface, given the much smaller γo driving force for surfactant adsorption. For systems with added NaCl, γ decreases with salinity at low CO2 densities as the surfactant partitions from water towards the W-C interface. At high densities, salt drives the surfactant from the W-C interface to CO2 and raises γ. Compared with most hydrocarbon surfactants, this dual tail surfactant is unusually CO2-philic in that it partitions primarily into the CO2 phase versus the water phase at CO2 densities above 0.8 g/ml, and produces γ values below 1 mN/m. With this small γ, a middle phase microemulsion and a C/W microemulsion were formed at low temperatures and high CO2 densities, whereas macroemulsions were formed at other conditions. 相似文献
10.
Open microcellular foams of polyethylene terephthalate (PET)/polycarbonate (PC) blends were prepared by controlling their foaming behavior at the interface between these two polymers. Interface modification was a crucial factor in governing the foaming behavior and cell morphology of the blend foams: annealing at 280°C, i.e., conducting the transesterification reaction, generates a PET‐b‐PC copolymer, which lowers the interfacial tension, increases the affinity between PET and PC, and decreases the crystallinity of the PET domains. When CO2 foaming was performed at the interface modified with the copolymer, an interesting fibril‐like structure was formed. The cell density of the PET/PC blend then increased, and its cell size reduced to the microscale while maintaining a high open‐cell ratio. The effect of heat annealing (transesterification reaction) on CO2‐foaming was studied to reveal the relationship among the interface affinity, crystallinity, and degree of fibrillation. The optimal heat‐annealing procedure generated a fibril‐like structure in the PET/PC blend foams with a high cell density (7 × 1011 cm?3), small cell size (less than 2 μm), and 100% open‐cell ratio. POLYM. ENG. SCI., 55:375–385, 2015. © 2014 Society of Plastics Engineers 相似文献
11.
A Novel Preparation Method for Foamed Silica Ceramics by Sol-Gel Reaction and Mechanical Foaming 总被引:1,自引:0,他引:1
A simple method for obtaining silica foam has been developed by combining sol-gel reaction and mechanical foaming without added organic pore formers, in order to reduce generation of CO2 and harmful gases by decomposition of the organic compounds. The silica foam was prepared by mechanically foaming the silica sol and controlling the viscosity change and gelling. The gelation time of the silica sol can be varied from 10 minutes to 3 hours by changing the pH, temperature and concentration of the surfactant added as a foam stabilizer. The dried silica gel foam was calcined at 600°C then fired at 1000°C to obtain sintered silica foam. The porosity and average pore size of the silica foam was 84% and 140 m, respectively. The bending strength and gas permeability of the sintered silica foam was 2.4 MPa and 9.4 × 10–11 m2, respectively. 相似文献
12.
A resilient, thermosetting foam system with a bio‐based content of 96 wt % (resulting in 81% of C14) was successfully developed. We implemented a pressurized carbon dioxide foaming process that produces polymeric foams from acrylated epoxidized soybean oil (AESO). A study of the cell dynamics of uncured CO2/ AESO foams proved useful to optimize cure conditions. During collapse, the foam's bulk density increased linearly with time, and the cell size and cell density exhibited power‐law degradation rates. Also, low temperature foaming and cure (i.e. high viscosity) are desirable to minimize foam cell degradation. The AESO was cured with a free‐radical initiator (tert‐butyl peroxy‐2‐ethyl hexanoate, Ti ~ 60°C). Cobalt naphtenate was used as an accelerator to promote quick foam cure at lower temperature (40–50°C). The foam's density was controlled by the carbon dioxide pressure inside the reactor and by the vacuum applied during cure. The viscosity increased linearly during polymerization. The viscosity was proportional to the extent of reaction before gelation, and the cured foam's structure showed a dependence on the time of vacuum application. The average cell size increased and the cell density decreased with foam expansion at a low extent of cure; however, the foam expansion became limited and unhomogeneous with advanced reaction. When vacuum was applied at an intermediate viscosity, samples with densities ~ 0.25 g/cm3 were obtained with small (<1 mm) homogeneous cells. The mechanical properties were promising, with a compressive strength of ~ 1 MPa and a compressive modulus of ~ 20 MPa. The new foams are biocompatible. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
13.
Effect of Viscosity on Preparation of Foamed Silica Ceramics by a Rapid Gelation Foaming Method 总被引:3,自引:0,他引:3
An environmentally benign preparation method for silica foam (the rapid gelation foaming method) was developed by combining sol-gel reactions and mechanical foaming without using organic polymers or monomers, in order to generate less CO2 and harmful gases from the decomposition of organic compounds contained in the raw material. The viscosity of the silica sol during foaming affects the porous properties of the silica foam, i.e. the porosity and average pore size decrease with increasing viscosity. The pore structure of the silica foams depend on the viscosity of silica sol, two types of pore structure being formed. An open-pore structure is obtained by foaming low-viscosity sols, while a closed-pore structure is obtained by foaming high-viscosity sols. Since the viscosity of the silica sol affects the stability and foaming ability of the foam, the porous properties of the product can be controlled by controlling the viscosity of the silica during foaming. 相似文献
14.
Pattamas Rattanaudom Bor-Jier Shiau Uthaiporn Suriyapraphadilok Ampira Charoensaeng 《Journal of surfactants and detergents》2019,22(5):1247-1263
A primary concern of surfactant-assisted foams in enhanced oil recovery (EOR) is the stability of the foams. In recent studies, foam stability has been successfully improved by the use of nanoparticles (NP). The adhesion energy of the NP is larger than the adsorbed surfactant molecules at the air–water interface, leading to a steric barrier to mitigate foam-film ruptures and liquid-foam coalescence. In this study, the partially hydrophobic SiO2 nanoparticles (SiO2-NP) were introduced to anionic mixed-surfactant systems to investigate their potential for improving the foamability and stability. An appropriate ratio of internal olefin sulfonate (C15-18 IOS) and sodium polyethylene glycol monohexadecyl ether sulfate (C32H66Na2O5S) was selected to avoid the formation of undesirable effects such as precipitation and phase separation under high-salt conditions. The effects of the NP-stabilized foams were investigated through a static foam column experiment. The surface tension, zeta potential, bubble size, and bubble size distribution were observed. The stability of the static foam in a column test was evaluated by co-injecting the NP-surfactant mixture with air gas. The results indicate that the foam stability depends on the dispersion of NP in the bulk phase and at the water–air interface. A correlation was observed in the NP-stabilized foam that stability increased with increasing negative zeta potential values (−54.2 mv). This result also corresponds to the smallest bubble size (214 μm in diameter) and uniform size distribution pattern. The findings from this study provide insights into the viability of creating NP-surfactant interactions in surfactant-stabilized foams for oil field applications. 相似文献
15.
Anish Kumar Bhaskar Patham Smita Mohanty Sanjay Kumar Nayak 《Polymer International》2020,69(4):373-386
We investigate the production and characterization of foams prepared from polypropylene (PP) as well as PP–silica nanocomposites containing different loadings of nano‐silica. This study was carried out to investigate the mechanisms underlying the production of foams with a regular cell structure through the use of nano‐scale fillers. Foaming was carried out in batch mode using an autoclave with CO2 as the physical blowing agent; high pressures of the order of 14 MPa were achieved through a combination of active pressurization and the use of high foaming temperatures. The resulting PP nanocomposite foams were characterized in detail to quantify the effect of the nano‐silica loading on the foam density and mechanical, morphological and thermal properties. The addition of nano‐silica in PP resulted in the improvement of foam quality – as assessed from the well‐defined and regular cell structures with absence of cell coalescence – as well as an increase in expansion ratio and decrease in foam density. Careful analyses of trends in cell size, cell density and expansion ratio of the foams were correlated with measurements of melt rheology and nano‐filler morphology of the unfoamed specimens in order to identify subtle details regarding the role of silica nanoparticles in improving foam quality. © 2019 Society of Chemical Industry 相似文献
16.
Hailey Poole Philip G. Jessop Cosima Stubenrauch 《Journal of surfactants and detergents》2022,25(4):467-475
The present study is about the foaming and defoaming properties of the CO2-switchable surfactant N,N-dimethyltetradecylamine (C14DMA) and its advantages compared with the non-switchable counterpart tetradecyltrimethylammonium bromide (C14TAB). In the absence of CO2, C14DMA is a water insoluble organic molecule without any surface activity thus being unable to stabilize foams. In the presence of CO2, the head group becomes protonated which transforms the water insoluble molecule into a cationic surfactant. Comparing the surface properties and foamability of C14DMA and C14TAB one finds a very similar behavior. However, the foam stabilities differ depending on the gas. Foaming the two-surfactant solutions with CO2 leads to very unstable foams in both cases. However, foaming the two surfactant solutions with N2 reveals the switchability of C14DMA: while the volume of foams stabilized with C14TAB hardly changes over 1600 s, the volume of foams stabilized with C14DMA decreases significantly in the same period of time. This difference is due to the fact that the surface activity, that is, the amphiphilic nature, of C14DMA is continuously switching off since CO2 is displaced by N2 thus deprotonating and deactivating the surfactant. 相似文献
17.
Influence of Hydrocarbon Chain Branching on Foam Properties of Olefin Sulfonate with FoamScan
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Yong Wang Xiaochen Liu Yawen Zhou Jinping Niu 《Journal of surfactants and detergents》2016,19(6):1215-1221
The influence of surfactant structure on foam properties of internal olefin sulfonate (IOS) and alpha olefin sulfonate (AOS) in aqueous solutions was estimated from measurements of the foamability, foam stability, and foam morphology, as obtained from conductivity and image analyses techniques. It was found that the foamability and foam stability of C16–18 AOS are higher compared to that of C16–18 IOS, indicating that hydrocarbon chain branching decreases the foamability and foam stability. The foamability and foam stability are enhanced with increasing surfactant concentration, which increases the adsorbed quantity of surfactant molecules at the air–water interface. The influence of hydrocarbon chain branching on foam morphology was also investigated. It was found that foam cells produced by branched chain C16–18 IOS are larger than the foam cells generated by straight chain C16–18 AOS. 相似文献
18.
Nurudeen Yekeen Ahmad Kamal Idris Muhammad A. Manan Ali Mohamed Samin Abdul Rahim Risal Tan Xin Kun 《中国化学工程学报》2017,25(3):347-357
Influence of silicon oxide(SiO_2) and aluminum oxide(Al_2O_3) nanoparticles on the stability of nanoparticles and sodium dodecyl sulfate(SDS) mixed solution foams was studied at bulk and bubble-scale. Foam apparent viscosity was also determined in Hele-Shaw cell In order to investigate the foam performance at static and dynamic conditions. Results show that the maximum adsorption of surfactant on the nanoparticles occurs at 3 wt% surfactant concentration. Foam stability increases while the foamability decreases with the increasing nanoparticle concentration. However, optimum nanoparticle concentration corresponding to maximum foam stability was obtained at 1.0 wt% nanoparticle concentration for the hydrophilic SiO_2/SDS and Al_2O_3/SDS foams. Foam performance was enhanced with increasing nanoparticles hydrophobicity. Air-foams were generally more stable than CO_2 foams.Foam apparent viscosity increased in the presence of nanoparticles from 20.34 mPa·s to 84.84 mPa·s while the film thickness increased from 27.5 μm to 136 μm. This study suggests that the static and dynamic stability of conventional foams could be improved with addition of appropriate concentration of nanoparticles into the surfactant solution. The nanoparticles improve foam stability by their adsorption and aggregation at the foam lamellae to increase film thickness and dilational viscoelasticity. This prevents liquid drainage and film thinning and improves foam stability both at the bulk and bubble scale. 相似文献
19.
Microcellular polymeric foam structures have been generated using a pressure‐induced phase separation in concentrated mixtures of supercritical CO2 and styrene‐co‐acrylonitrile (SAN). The process typically generates a microcellular core structure encased by a non‐porous skin. Pore growth occurs through two mechanisms: diffusion of CO2 from polymer‐rich regions into the pores and also through CO2 gas expansion. The effects of saturation pressure, temperature and swelling time on the cell size, cell density and bulk density of the porous materials have been studied. Higher CO2 pressures (hence, higher fluid density) provided more CO2 molecules for foaming, generated lower interfacial tension and viscosity in the polymer matrix, and thus produced lower cell size but higher cell densities. This trend was similar to what was observed in swelling time series. While the average cell size increased with increasing temperature, the cell density decreased. The trend of bulk density was similar to that of cell size. © 2000 Society of Chemical Industry 相似文献
20.
I. Blute M. Jansson S. G. Oh D. O. Shah 《Journal of the American Oil Chemists' Society》1994,71(1):41-46
The effect of tetraalkylammonium ions on the destabilization of foam has been studied by measuring the half-life of foam (τ1/2), area/molecule at the air/water interface, surface viscosity and critical micelle concentration (CMC) of sodium dodecyl
sulfate (SDS). The area/molecule of SDS in organic salt solutions, calculated from the Gibbs isotherm, increases as the size
of organic ion increases, and surface viscosity of the film decreases with the size of organic ions. The interaction of tetraalkylammonium
ions with SDS decreases the CMC of the solution, and hence the concentration of SDS monomers decreases. The CMC of SDS decreases
with the increase in the size and concentration of organic ions. The decrease in the CMC, increase in the area/molecule of
SDS at the air/water interface and the decrease in surface viscosity by tetraalkylammonium ions all work to decrease the foam
stability. The results indicate that the change in intermolecular distance between surfactant molecules in the adsorbed film
by organic ions can significantly influence the surface viscosity and foam stability. The foam destabilizing efficiency of
tetra-alkylammonium ions was superior or equivalent to that of tributyl phosphate and 2-ethyl hexanol, which are used in many
antifoaming formulations. 相似文献