共查询到20条相似文献,搜索用时 93 毫秒
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乙烯是石油化学工业中最重要的基础有机原料之一。通常乙烯采用低温常压存储,因此存储的能耗对乙烯储运的运行成本影响较大。本文通过对低温乙烯存储系统中不同的工艺能耗进行了分析和比较,发现节能技术的应用能回收乙烯冷量,有效的降低乙烯存储的能耗,为低温乙烯存储系统中的节能技术的应用提供参考。 相似文献
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国外乙烯装置扩能改造典型分析 总被引:1,自引:0,他引:1
对国外90年代中期3套乙烯装置扩能改造进行了详细了介绍和典型分析,所选的3套乙烯装置基本符合国内正在进行和将要进行的乙烯改造规模,其经验对;国内现有乙烯装置的第二轮改造具有直接的现实参考价值。在此基础上还提出了国内乙烯装置扩能改造的建议。 相似文献
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S. Srinivasa Reddy 《Polymer Bulletin》1996,36(3):317-323
Summary The effect of [A1]/[Zr] mol ratio and temperature on the cocatalytic effects of tetraisobutyldialuminoxane (TIBDAO) and methylaluminoxane (MAO) for ethylene polymerization using Cp2ZrCl2 catalyst were studied. The decay type kinetic profile was observed for both TIBDAO and MAO cocatalyzed ethylene polymerizations. Catalytic activity and rate of polymerization were found to be low for TIBDAO cocatalyzed ethylene polymerization when compared to MAO cocatalyzed ethylene polymerization. The differences in catalytic activity and rate of polymerization for ethylene polymerization catalyzed by Cp2ZrCl2-TIBDAO and Cp2ZrCl2-MAO were discussed with respect to the structures of MAO and TIBDAO. An active species for Cp2ZrCl2-MAO and Cp2ZrCl2-TIBDAO catalyzed ethylene polymerizations was also discussed. The polyethylene was characterized by intrinsic viscosity measurements. 相似文献
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Four PPG Avanel Series S surfactants (sodium alkyl polyether sulfonates) with varying ethylene oxide content (n = 3, 7, 9, and 15) were used to investigate the influence of the steric length in this type of electrosteric stabilizers on emulsion polymerization. The polymerization studies employing potassium persulfate as an initiator with styrene, methyl methacrylate, and vinyl acetate monomers showed no apparent change in particle size, number of particles, and polymerization rate with the changing steric length of the surfactant. Steric influences were observed in the redox-initiated systems of styrene, butyl acrylate, and methyl methacrylate. Increasing the ethylene oxide unit content from three to nine units decreased the rate of polymerization, the particle size and number in the polystyrene latexes. Polymerizations with the acrylates displayed the same trend except that the polymerization rate reached a minimum value at nine ethylene oxide units and increased when the surfactant containing 15 ethylene oxide units was used. 相似文献
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Nevena Manolova Jan Libiszowski Ryszard Szymanski Stanislaw Penczek 《Polymer International》1995,36(1):23-28
The Polymerization of ethylene oxide catalysed by protonic acids and proceeding via the activated monomer mechanism differs from the polymerizations of substituted epoxides like propylene oxide and epichlorohydrin. The kinetics of ethylene oxide polymerization were investigated and compared with the kinetics of model reactions, namely addition of oligomers of ethylene oxide to ethylene oxide. The mechanism of polymerization involves, besides the addition of monomer to the terminal hydroxyl groups, the addition to the polymer ether groups. This reaction does not take place for substituted oxiranes, most probably because of steric hindrance. 相似文献
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Meera Mahadevan Sangyool Lee Serguei V. Dessiatoun Michael Ohadi Ebrahim Al Hajri Kyu Yong Choi 《化学工程与技术》2016,39(2):293-300
The feasibility of using a microtubular reactor for heterogeneous polymerization of ethylene was investigated experimentally. Chemically inert polymer tubing of 800–2300 μm in inner diameter was fabricated and used as a polymerization reactor. Nonporous silica nanoparticles with a diameter of 400 nm were synthesized and used as support for the high‐activity rac‐ethylene(indenyl)2ZrCl2 catalyst with methylaluminoxane as cocatalyst and toluene as diluent. Large‐diameter microtubular reactors were also successfully used to conduct heterogeneous polymerization of ethylene in continuous reaction operations. High initial catalyst activity was obtained and the overall polymerization activity per volume or reactor length was quite high. No particle fragmentation occurred and the polymer particles were covered with small subgrains or nanofibrils with a diameter of 30 nm. 相似文献
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The severe thermodynamic conditions of the high‐pressure ethylene polymerization process hinder ethylene from going to full conversion. One remedy to improve the monomer conversion is to make effective use of difunctional peroxides. Multifunctional peroxides can accelerate the polymerization rate, produce branching, and modify the rheological properties of molten polymers. This article proposes a kinetic model based on a postulated reaction mechanism for ethylene polymerization initiated by difunctional initiators in a high‐pressure tubular reactor. Three peroxides suitable for ethylene polymerization were compared for their effectiveness. Compared to dioctanoyl peroxide, the two difunctional peroxides considered performed much better for the higher temperature regions of the reactor and gave ethylene conversions nearly twice as high for only half of the initial amount of dioctanoyl. They also generated low‐density polyethylene polymer with a broader molecular weight distribution and longer chain branching. These two important polymer characteristics can influence the end‐product rheological properties. Injecting fresh ethylene at different points along the reactor improved the conversion and produced more branched polymer. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
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通过齐聚催化剂和共聚催化剂的有机结合和相互协同,可实现以乙烯为唯一单体的串级催化聚合,合成乙烯与α-烯烃共聚的线性低密度聚乙烯和聚烯烃热塑性弹性体,但开发高选择性、高共聚能力、适合高温聚合的串级聚合催化体系仍极具挑战。本文围绕不同类型的乙烯齐聚/聚合反应,评述了乙烯二聚、三聚、四聚及聚烯烃大单体合成技术及其相应的串级催化聚合的研究进展。迄今,大部分串级催化聚合是在较低的聚合反应温度下进行的,有限的串级催化体系适合高温聚合;乙烯二聚和三聚串级催化聚合可合成短支链较均一的乙烯与α-烯烃共聚物,但在乙烯四聚串级催化聚合中1-辛烯的选择性亟待提高;此外,通过聚烯烃大单体的串级催化聚合,可为具有特殊链拓扑结构的高性能聚烯烃热塑性弹性体的开发开拓新途径。 相似文献
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研究了对丙烯的高速间规活性聚合有效的Cs-对称胺芴二甲基钛络合物-干燥修饰甲基铝氧烷(dMMAO)催化剂体系对乙烯的聚合行为的影响。结果表明:乙烯常压聚合表现出稳定的聚合速率,聚合活性达到282 kg-PE/(mol-Ti·h);利用间歇聚合法进行乙烯聚合的单体转化率均达到99%以上,说明催化体系无失活现象,但得到的聚乙烯在135℃下不溶于GPC溶剂邻二氯苯中;采用先加入定量丙烯单体聚合完全结束后,再加入定量乙烯单体进行聚合的方法合成了sPP-b-PE嵌段共聚物。嵌段共聚合的结果说明乙烯聚合是以活性聚合的方式进行的。利用该催化体系还合成了丙烯-乙烯丙烯双嵌段共聚物(sPP-b-E/P)以及丙烯-乙烯丙烯-丙烯(sPP-b-E/P-b-sPP)三嵌段共聚物。 相似文献
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N. M. Gul'tseva T. M. Ushakova A. M. Aladyshev L. N. Raspopov I. N. Meshkova 《Polymer Bulletin》1992,29(6):639-646
Summary Ethylene and propylene co-polymerization and sequential polymerization with high activity supported titanium catalysts were studied. Specific rate of homopolymerization and copolymerization constants for ethylene and propylene were determined by using the derived values of the solubility constants for monomers in nascent polymers. The reason of the increased rate of co-polymerization upon enriching the monomers mixture with propylene, the effect of activation of ethylene polymerization upon preliminary polymerization of propylene may be in the increasing number of active sites due to enlarged content of amorphous phase in the nascent polymer product. 相似文献