共查询到20条相似文献,搜索用时 109 毫秒
1.
2.
常压塔是炼油厂常压装置中的关键装置,由于石油等原料中含有杂质,这些杂质沉积或者携带到后续工序中,加上常压塔长期处于低负荷运行状态,造成常压塔顶出现压力高问题。为解决常压塔顶压力高这一问题,概述了常压塔顶压力高带来的影响,从塔顶冷却效果降低等方面分析了常压塔顶压力高的原因,提出了改善塔顶冷却环境等措施,以期为相关人员提供参考。 相似文献
3.
4.
5.
6.
多元精馏中组分在塔顶、塔底预分配关系的计算机计算 总被引:1,自引:0,他引:1
提出了多组分精馏中塔顶、塔底产品预分配的计算机计算方法。由Chao—seadex汽液平衡模型计算组分相平衡常数,并确定塔顶、塔底温度。由亨斯特别克法计算塔顶、塔底产品量。给出了程序框图及应用实例。 相似文献
7.
简介了聚酯工艺塔顶余热利用现状。通过分析塔顶余热特点,结合低温余热发电技术发展,重点讨论了利用工艺塔顶余热发电的技术方案。结果表明,对于大型聚酯装置工艺塔余热,采用卡琳娜循环发电技术的余热利用效果优于有机朗肯发电技术。 相似文献
8.
文章介绍了焦炭塔顶油气管嘴破坏原因分析与处理。通过对焦炭塔顶油气管嘴破坏原因分析,对其进行处理,不仅可有效防止焦炭塔顶油气管嘴产生裂纹,同时提高了焦化装置的整体安全性,避免了焦化装置在正常运行过程中,装置停车带来的经济损失。 相似文献
9.
10.
针对中原油田石化总厂催化裂化稳定塔塔顶冷却负荷不足等问题,对稳定塔塔顶压力控制方案进行了改造,用干气代替液化气作为热旁路介质,提高了稳定塔塔顶冷却负荷。 相似文献
11.
Mark A. Plummer 《Chemical Engineering Communications》2006,193(10):1321-1331
Quantum and molecular mechanics methods were used to guide the development of a liquid extraction process for the removal of sulfur compounds from gasoline using an aqueous solvent containing n-butylamine (NBA). The calculational results suggest that the extraction mechanism was via forming micelles of NBA around single sulfur compounds. That is, micelles containing 6 to 192 molecules of NBA yielded negative formation energies. With increasing NBA amounts over the same range, total sulfur removal increased in extraction experiments. However, not all sulfur compounds were extracted simultaneously. Extraction selectivities were correlated to calculated formation energies between individual sulfur compounds and a single molecule of NBA. This suggests that extraction selectivity depended on attraction of each sulfur compound out of the gasoline to the NBA micelle wall. To provide sufficient extraction time, the number of extraction stages was investigated. The results predicted that about 10 theoretical stages would be required to achieve equal extractions of all sulfur compound types and 99+% total sulfur removal. 相似文献
12.
Mark A. Plummer 《Chemical Engineering Communications》2013,200(10):1321-1331
Quantum and molecular mechanics methods were used to guide the development of a liquid extraction process for the removal of sulfur compounds from gasoline using an aqueous solvent containing n-butylamine (NBA). The calculational results suggest that the extraction mechanism was via forming micelles of NBA around single sulfur compounds. That is, micelles containing 6 to 192 molecules of NBA yielded negative formation energies. With increasing NBA amounts over the same range, total sulfur removal increased in extraction experiments. However, not all sulfur compounds were extracted simultaneously. Extraction selectivities were correlated to calculated formation energies between individual sulfur compounds and a single molecule of NBA. This suggests that extraction selectivity depended on attraction of each sulfur compound out of the gasoline to the NBA micelle wall. To provide sufficient extraction time, the number of extraction stages was investigated. The results predicted that about 10 theoretical stages would be required to achieve equal extractions of all sulfur compound types and 99+% total sulfur removal. 相似文献
13.
简述了连续重整装置重整反应部分硫中毒的现象,通过分析得出罐区来的精制石脑油所带溶解氧与预加氢反应产生的硫化氢在汽提塔内生成单质硫,是引起硫含量偏高的原因。切断罐区来精制石脑油进汽提塔后,重整进料硫含量恢复正常。 相似文献
14.
为强化污水处理厂尾水的深度脱氮,研究丝瓜络、硫和铁不同质量比和不同水力停留时间(HRT)下丝瓜络耦合硫铁复合填料反硝化滤池的脱氮效率,并对比分析丝瓜络反硝化滤柱和丝瓜络耦合硫铁复合填料反硝化滤柱的脱氮性能。结果表明,120 g丝瓜络∶380 g硫铁复合填料系统(Fe∶S∶水泥=5∶2∶3)脱氮性能最佳,NO3--N去除率稳定,最高可达100%,NO3--N平均去除率约为90.4%,TN平均去除率约为83.1%,系统最佳运行HRT为8 h。丝瓜络耦合硫铁复合填料反硝化滤柱更耐冲击负荷,脱氮性能更好。通过高通量测序结果可知,丝瓜络耦合硫铁复合填料反硝化滤柱中自养反硝化菌增长了219.2%,异养反硝化菌增长了33.0%,添加硫铁复合硫铁填料强化了异养联合自养反硝化作用。可见,丝瓜络耦合硫铁复合填料反硝化滤柱在一定条件下具有高效脱氮能力,适用于城市污水厂尾水的深度脱氮处理。 相似文献
15.
16.
17.
18.
19.
Mahsa Heidari Ali Akbar Safekordi Maryam Ghaedian Amin Shafeghat 《Korean Journal of Chemical Engineering》2013,30(3):700-705
An experimental study was conducted to investigate the extraction of oxidized sulfur compounds from gas oil. Solvents used for this purpose included acetone, acetonitrile, methanol and propanol. The effect of solvent concentration, solvent to gas oil ratio, temperature, time and number of stages was studied. To select the best solvent and conditions for extraction, two criteria were considered: high desulfurization and more hydrocarbon recovery. Results showed that extraction time and temperature have no significant effect. Methanol for low ability of extraction of oxidized sulfur compounds and propanol for low hydrocarbon recovery were excluded from further experiments. After the tests, the optimum conditions for extraction were determined to be 85% acetone, solvent/feed ratio of 1, two stages extraction in ambient temperature and enough time for mixing. In this condition 85% of sulfur compounds of gas oil containing 1,670 ppmw S were separated and 95% of gas oil was recovered. 相似文献
20.
针对金陵石化I重整装置2016年2月出现的脱庚烷塔底物料中非芳含量上升、抽提原料中非芳含量上升、反应总温降下降以及单位产氢量下降等反应苛刻度低的问题进行详细分析,总结出可能引起反应苛刻度低的四个方面条件:I重整进出物料换热器内漏、原料性质、操作条件及催化剂性质,并分别对四个方面的条件进行详细的数据对比分析,最后得出本次I重整装置反应苛刻的低的主要原因为增加了S含量高达(4~6)×10-6的II加氢裂化装置重石掺炼量,致使重整催化剂出现轻微的S中毒,加快了催化剂积碳速率,且因I重整装置扩容改造后未增加催化剂再生能力,再生能力不足直接导致待生催化剂中C含量高达6.66%,从而使重整催化剂金属活性降低,直接降低了催化剂烷烃脱氢环化性能,使I重整反应苛刻度下降,脱庚烷塔底C8+物料及抽提进料中非芳含量明显升高。 相似文献